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Detalles de la revista
Formato
Revista
eISSN
2719-9509
Publicado por primera vez
01 Jan 1992
Periodo de publicación
4 veces al año
Idiomas
Inglés

Buscar

Volumen 23 (2009): Edición 4 (May 2009)

Detalles de la revista
Formato
Revista
eISSN
2719-9509
Publicado por primera vez
01 Jan 1992
Periodo de publicación
4 veces al año
Idiomas
Inglés

Buscar

3 Artículos
Acceso abierto

Determination of “Hoffmann Analytes” in Cigarette Mainstream Smoke. The Coresta 2006 Joint Experiment

Publicado en línea: 30 Dec 2014
Páginas: 161 - 202

Resumen

Abstract

Regulatory authorities are currently discussing the measurement of and imposition of ceilings on certain smoke analytes, the so called ‘Hoffmann analytes’. However, as a pre-requisite, the measurement methods and the tolerances around the measurements first need to be established.

In 1999, the Cooperation Centre for Scientific Research Relative to Tobacco (CORESTA) set up a Task Force ‘Special Analytes’ to deal with analytical methodology for measuring ‘Hoffmann analytes’ under International Standard (ISO) smoking and to work towards the standardisation of methods. This paper describes the output and conclusions from a 2005-2006 joint experiment made within the Task Force representing laboratories currently able to analyse these compounds. Data were obtained on most ‘Hoffmann analytes’ from reference cigarettes (2R4F and 1R5F), collecting data according to the existing methods used by the nineteen participating laboratories, in order to describe the within and among laboratory variability and to see which methods could most benefit from more rigorous standardisation work.

In some cases, the applied statistical analysis found that methods could not well differentiate the 1R5F and 2R4F cigarettes of differing ‘tar’ yield. This was explained, in part, by the broad range of methods used by the participating laboratories but also indicated that there were significant inadequacies in the choice of some methods or weaknesses in their application.

Results indicate that ‘Hoffmann analyte’ data are generally more variable both within and among laboratories than nicotine free dry particulate matter (NFDPM); nicotine and carbon monoxide due to their lower smoke yields. Accordingly, tolerances around methods adopted for regulatory purposes will need to be proportionately higher.

Methods for benzo[a]pyrene (B[a]P) and tobacco-specific nitrosamines (TSNAs), already taken to CORESTA recommended methods or ISO standardised methods through the efforts of this Task Force, give some of the most reproducible results, showing the value of this process. However, these data strongly suggest that even these analytes have much higher among-laboratory variability than for NFDPM, nicotine and CO and, based on the only two available one point in time studies, may need tolerances in the range of 35-45% for B[a]P and 26-55% for TSNAs, if they are to be measured for regulatory purposes.

The collected data is useful to participating laboratories for internal method validation and laboratory accreditation, and data comparisons with others allow laboratories to identify strengths and weaknesses in their current methods.

However, much work still needs to be carried out to take most of the methods towards standardisation. Although some fundamental differences or areas of concern around the methodology are discussed herein, they are not comprehensive and there may be others that need to be addressed before methods can be considered ready to take to a Recommended Method and/or to an ISO Standard. These methodological issues are being addressed in further CORESTA work within this Task Force. Smoke analytes with the highest variability found in this study and those analytes that are currently of highest regulatory interest are being prioritised and after further joint experiments, the results are intended to be published.

Acceso abierto

Investigation of Tobacco Pyrolysis Gases and Puff-by-puff Resolved Cigarette Smoke by Single Photon Ionisation (SPI) - Time-of-flight Mass Spectrometry (TOFMS)

Publicado en línea: 30 Dec 2014
Páginas: 203 - 226

Resumen

Abstract

The work presented deals with the application of Single Photon Ionisation- Time-of-Flight Mass Spectrometry (SPI-TOFMS) for the investigation of tobacco smoke. SPI-TOFMS is a modern analytical technique, which enables the simultaneous analysis of a large number of organic species in complex gas mixtures in real time. The paper is a summary of a PhD thesis (1) and seven research articles, which were recently published in various scientific journals (2-8). Consequently, more detailed information on particular aspects can be found in there.

The experimental part covers two different approaches, and therefore, it is divided into two sub-sections. In the first one, the SPI-TOFMS is coupled to a pyrolysis furnace. The objective is to examine the thermal behaviour of tobacco under various controlled conditions. In so doing, three tobacco types (Virginia, Oriental, and Burley) were pyrolysed in two reaction gas compositions (nitrogen and synthetic air) and seven different furnace temperatures (400 °C, 500 °C, 600 °C, 700 °C, 800 °C, 900 °C, and 1000 °C). Results can help to unravel the complex formation and decomposition reactions taking place when tobacco is heated. In the second part the SPI-TOFMS is connected to a cigarette smoking machine in order to investigate the behaviour of cigarette smoke constituents on a puff-by-puff basis. The work incorporates the comparison of whole smoke and gas phase of cigarette smoke, a puff-resolved quantification of several hazardous smoke constituents, and the overall chemical characterisation of the individual smoking puffs. In addition, a critical consideration of the prevailing smoking procedure is given when applied to single puff analysis. A further study examines the influence of five different cigarette lighting devices (gas lighter, electric lighter, candle, match, and burning zone of another cigarette) on the chemical composition of the first puff.

Acceso abierto

Book Review: The Chemical Components of Tobacco and Tobacco Smoke

Publicado en línea: 30 Dec 2014
Páginas: 227 - 230

Resumen

Abstract

This book is highly recommended as an indispensable reference source for tobacco and smoke chemists as well as other scientists involved in the study of tobacco and its products. The compilation of proper chemical names, common names, Chemical Abstract Service numbers (CAS No.), and structures is alone worth the purchase price.

3 Artículos
Acceso abierto

Determination of “Hoffmann Analytes” in Cigarette Mainstream Smoke. The Coresta 2006 Joint Experiment

Publicado en línea: 30 Dec 2014
Páginas: 161 - 202

Resumen

Abstract

Regulatory authorities are currently discussing the measurement of and imposition of ceilings on certain smoke analytes, the so called ‘Hoffmann analytes’. However, as a pre-requisite, the measurement methods and the tolerances around the measurements first need to be established.

In 1999, the Cooperation Centre for Scientific Research Relative to Tobacco (CORESTA) set up a Task Force ‘Special Analytes’ to deal with analytical methodology for measuring ‘Hoffmann analytes’ under International Standard (ISO) smoking and to work towards the standardisation of methods. This paper describes the output and conclusions from a 2005-2006 joint experiment made within the Task Force representing laboratories currently able to analyse these compounds. Data were obtained on most ‘Hoffmann analytes’ from reference cigarettes (2R4F and 1R5F), collecting data according to the existing methods used by the nineteen participating laboratories, in order to describe the within and among laboratory variability and to see which methods could most benefit from more rigorous standardisation work.

In some cases, the applied statistical analysis found that methods could not well differentiate the 1R5F and 2R4F cigarettes of differing ‘tar’ yield. This was explained, in part, by the broad range of methods used by the participating laboratories but also indicated that there were significant inadequacies in the choice of some methods or weaknesses in their application.

Results indicate that ‘Hoffmann analyte’ data are generally more variable both within and among laboratories than nicotine free dry particulate matter (NFDPM); nicotine and carbon monoxide due to their lower smoke yields. Accordingly, tolerances around methods adopted for regulatory purposes will need to be proportionately higher.

Methods for benzo[a]pyrene (B[a]P) and tobacco-specific nitrosamines (TSNAs), already taken to CORESTA recommended methods or ISO standardised methods through the efforts of this Task Force, give some of the most reproducible results, showing the value of this process. However, these data strongly suggest that even these analytes have much higher among-laboratory variability than for NFDPM, nicotine and CO and, based on the only two available one point in time studies, may need tolerances in the range of 35-45% for B[a]P and 26-55% for TSNAs, if they are to be measured for regulatory purposes.

The collected data is useful to participating laboratories for internal method validation and laboratory accreditation, and data comparisons with others allow laboratories to identify strengths and weaknesses in their current methods.

However, much work still needs to be carried out to take most of the methods towards standardisation. Although some fundamental differences or areas of concern around the methodology are discussed herein, they are not comprehensive and there may be others that need to be addressed before methods can be considered ready to take to a Recommended Method and/or to an ISO Standard. These methodological issues are being addressed in further CORESTA work within this Task Force. Smoke analytes with the highest variability found in this study and those analytes that are currently of highest regulatory interest are being prioritised and after further joint experiments, the results are intended to be published.

Acceso abierto

Investigation of Tobacco Pyrolysis Gases and Puff-by-puff Resolved Cigarette Smoke by Single Photon Ionisation (SPI) - Time-of-flight Mass Spectrometry (TOFMS)

Publicado en línea: 30 Dec 2014
Páginas: 203 - 226

Resumen

Abstract

The work presented deals with the application of Single Photon Ionisation- Time-of-Flight Mass Spectrometry (SPI-TOFMS) for the investigation of tobacco smoke. SPI-TOFMS is a modern analytical technique, which enables the simultaneous analysis of a large number of organic species in complex gas mixtures in real time. The paper is a summary of a PhD thesis (1) and seven research articles, which were recently published in various scientific journals (2-8). Consequently, more detailed information on particular aspects can be found in there.

The experimental part covers two different approaches, and therefore, it is divided into two sub-sections. In the first one, the SPI-TOFMS is coupled to a pyrolysis furnace. The objective is to examine the thermal behaviour of tobacco under various controlled conditions. In so doing, three tobacco types (Virginia, Oriental, and Burley) were pyrolysed in two reaction gas compositions (nitrogen and synthetic air) and seven different furnace temperatures (400 °C, 500 °C, 600 °C, 700 °C, 800 °C, 900 °C, and 1000 °C). Results can help to unravel the complex formation and decomposition reactions taking place when tobacco is heated. In the second part the SPI-TOFMS is connected to a cigarette smoking machine in order to investigate the behaviour of cigarette smoke constituents on a puff-by-puff basis. The work incorporates the comparison of whole smoke and gas phase of cigarette smoke, a puff-resolved quantification of several hazardous smoke constituents, and the overall chemical characterisation of the individual smoking puffs. In addition, a critical consideration of the prevailing smoking procedure is given when applied to single puff analysis. A further study examines the influence of five different cigarette lighting devices (gas lighter, electric lighter, candle, match, and burning zone of another cigarette) on the chemical composition of the first puff.

Acceso abierto

Book Review: The Chemical Components of Tobacco and Tobacco Smoke

Publicado en línea: 30 Dec 2014
Páginas: 227 - 230

Resumen

Abstract

This book is highly recommended as an indispensable reference source for tobacco and smoke chemists as well as other scientists involved in the study of tobacco and its products. The compilation of proper chemical names, common names, Chemical Abstract Service numbers (CAS No.), and structures is alone worth the purchase price.

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