Characterization of solvents containing CyMe4-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons
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Dec 30, 2015
About this article
Published Online: Dec 30, 2015
Page range: 885 - 891
Received: Aug 16, 2015
Accepted: Aug 26, 2015
DOI: https://doi.org/10.1515/nuka-2015-0123
Keywords
© by Jan John
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.
Radiation stability of CyMe4-BTPhen was examined in systems with three selected cyclohexanone-based diluents. Accelerated electrons were used as a source of ionizing radiation. The CyMe4-BTPhen radiation degradation identification and characterization of the degradation products were performed by high performance liquid chromatography (HPLC) and mass spectrometry (MS) analyses. Residual concentrations of tested ligand were determined. Moreover, extraction properties of the solvents irradiated at two different doses were compared with the extraction properties of non-irradiated solvents to estimate the influence of the presence of degradation products in the organic phase.