<abstract xmlns="http://www.w3.org/1999/xhtml"> Radiation stability of CyMe4-BTPhen was examined in systems with three selected cyclohexanone-based diluents. Accelerated electrons were used as a source of ionizing radiation. The CyMe4-BTPhen radiation degradation identification and characterization of the degradation products were performed by high performance liquid chromatography (HPLC) and mass spectrometry (MS) analyses. Residual concentrations of tested ligand were determined. Moreover, extraction properties of the solvents irradiated at two different doses were compared with the extraction properties of non-irradiated solvents to estimate the influence of the presence of degradation products in the organic phase.</abstract>

Radiation stability of CyMe4-BTPhen was examined in systems with three selected cyclohexanone-based diluents. Accelerated electrons were used as a source of ionizing radiation. The CyMe4-BTPhen radiation degradation identification and characterization of the degradation products were performed by high performance liquid chromatography (HPLC) and mass spectrometry (MS) analyses. Residual concentrations of tested ligand were determined. Moreover, extraction properties of the solvents irradiated at two different doses were compared with the extraction properties of non-irradiated solvents to estimate the influence of the presence of degradation products in the organic phase.

Characterization of solvents containing CyMe4-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons

Department of Nuclear Chemistry, Czech Technical University in Prague, Břehová 7, 11519 Prague 1, Czech Republic

Department of Nuclear Chemistry, Czech Technical University in Prague, Břehová 7, 11519 Prague 1, Czech Republic,

Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Hlavni 1001, 25068 Husinec-Rež, Czech Republic

Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Hlavni 1001, 25068 Husinec-Rež, Czech Republic,

Nukleonika

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Characterization of solvents containing CyMe-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons

Radiation stability of CyMe4-BTPhen was examined in systems with three selected cyclohexanone-based diluents. Accelerated electrons were used as a source of...

Characterization of solvents containing CyMe₄-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons

Published Online: Dec 30, 2015

Page range: 885 - 891

Received: Aug 16, 2015

Accepted: Aug 26, 2015

DOI: https://doi.org/10.1515/nuka-2015-0123

Keywords
accelerated electrons, CyMe4-BTPhen, irradiation, radiation stability, solvent extraction

© by Jan John

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Characterization of solvents containing CyMe4-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons

Published Online: Dec 30, 2015

Page range: 885 - 891

Received: Aug 16, 2015

Accepted: Aug 26, 2015

DOI: https://doi.org/10.1515/nuka-2015-0123

Keywordsaccelerated electrons, CyMe4-BTPhen, irradiation, radiation stability, solvent extraction

© by Jan John

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Characterization of solvents containing CyMe₄-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons

Keywords
accelerated electrons, CyMe4-BTPhen, irradiation, radiation stability, solvent extraction