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Characterization of magnetic biochar amended with silicon dioxide prepared at high temperature calcination

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10 paź 2016

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Fig. 1

XRD patterns of (a) KGB, (b) MB, (c) MBC, (d) MBS and (e) MBSC.
XRD patterns of (a) KGB, (b) MB, (c) MBC, (d) MBS and (e) MBSC.

Fig. 2

FT-IR spectra of (a) KGB, (b) MB, (c) MBC, (d) MBS and (e) MBSC.
FT-IR spectra of (a) KGB, (b) MB, (c) MBC, (d) MBS and (e) MBSC.

Fig. 3

SEM images of (a) KGB, (b) MB, (c) MBC, (d) MBS and (e) MBSC.
SEM images of (a) KGB, (b) MB, (c) MBC, (d) MBS and (e) MBSC.

Fig. 4

Saturation magnetization of MB, MBC, MBS and MBSC samples under the applied magnetic field (−20000 Oe to 20000 Oe).
Saturation magnetization of MB, MBC, MBS and MBSC samples under the applied magnetic field (−20000 Oe to 20000 Oe).

Fig. 5

Thermogravimetric analyses (TGA) of MB, MBC, MBS and MBSC samples.
Thermogravimetric analyses (TGA) of MB, MBC, MBS and MBSC samples.

BET surface area, total pore volume and mean pore diameter of the samples_

SampleSA [m2·g−1]Total pore volume Vp[m3·g−1]Mean pore diameter [nm]
KGB35.340.0056.5
MB45.830.0242.1
MBC336.790.0212.5
MBS45.370.0242.1
MBSC125.170.0082.7

Elemental compositions of the samples (KGB, MB, MBC, MBS and MBSC) conducted by EDX analyses_

KGBMBMBCMBSMBSC
Elementwt.%at.%wt.%at.%wt.%at.%wt.%at.%wt.%at.%
C75.0781.7434.7452.3875.2887.0927.6943.7279.1589.36
N04.160.38802.8103.6305.2705.2302.6203.5503.6703.55
O14.8112.1028.1131.8204.2503.7032.2038.1804.2603.61
Na00.0000.0000.5700.4500.0000.0000.6800.5600.0600.03
Mg00.1400.0800.4000.3000.0400.0200.4400.3500.0800.04
Al00.0200.0100.3000.2000.0400.0200.3300.2300.0400.02
Si01.4600.6800.6400.4200.5400.2703.0802.0801.0400.50
P00.0700.0300.1700.1000.0100.0100.1400.0900.0300.01
S00.5300.2100.3800.2100.1200.0500.2700.1600.0800.03
Cl00.5200.1900.6500.3300.0600.0200.1600.0900.0500.02
K03.0001.0000.1300.0600.0600.0200.0900.0400.0500.02
Ca00.2300.0700.1300.0600.0700.0300.0000.0000.0500.02
Fe00.0000.0030.9810.0514.2403.5432.3110.9711.4502.78
MatrixCorrect.ZAFCorrect.ZAFCorrect.ZAFCorrect.ZAFCorrect.ZAF