Volume 38 (2011): Issue 4 (December 2011)

The traditional radiocarbon method widely used in archaeology and geology for chronological purposes can also be used in environmental studies. Combustion of fossil fuels like coal, natural gas, petroleum, etc., in industrial and/or heavily urbanized areas, has increased the concentration of carbon dioxide in the atmosphere. The addition of fossil carbon caused changes of carbon isotopic composition, in particular, a definite decrease of 14C concentration in atmospheric CO2 and other carbon reservoirs (ocean and terrestrial biosphere), known as the Suess effect. Tree rings, leaves, as well as other annual growing plants reflected the changes of radiocarbon concentration in the atmosphere due to processes of photosynthesis and assimilation of carbon from the air. By measuring radiocarbon concentration directly in atmospheric CO2 samples and/or biospheric material growing in industrial and/or highly urbanized areas where high emission of dead carbon is expected, it is possible to estimate the total emission of dead CO2. Based on equations of mass balance for CO2 concentration, stable isotopic composition of carbon and radiocarbon concentration it is possible to calculate CO2 con-centration associated with fossil fuel emission into the atmosphere. The procedure use differences between the radiocarbon concentration and stable isotope composition of carbon observed in clean areas and industrial or/and highly urbanized areas.

This study focuses on the analysis of the structural and textural features of the colluvial (deluvial) deposits in the Suwałki Lake District (NE Poland) and their absolute age. The colluvium has a thickness of up to 150 cm. The dates of the peat under colluvium or lowermost fossil humus-rich horizons point to the ages from 5405±80 BP to 480 BP. Deposition of material at the footslope is a result of a denudation triggered by human action (surface water erosion and tillage erosion) and usually corresponds with the settlement stages. The 14C dating of deposited sediment sometimes indicated to older dates of colluvium then the archaeological evidence available for examined sites. Locally, the overlying fossil humic horizon was older then the lowermost one. The textural features of the colluvial deposits such as: the content of fine fraction, weak sorting and relationship between the mean grain-size (Mz) and the sorting index (σ1) were used to recognize sediment redeposited from the upper part of the slope. Basing on the mineral composition and electrical conductivity of fossil humus horizon it is possible to say whether the soil was degraded or aggraded. These features of the humus-rich horizons occurring between colluvial sediments can be used to explain discrepancy between the radiocarbon dating and archaeological evidence.

The present study focuses on investigations carried out in the Late Vistulian succession of the Warta River deposits (central Poland) in which a horizon of subfossil trees was excavated. Prelim-inary conclusions on time record and past environmental conditions of a forest existence determined from radiocarbon dating, pollen analyses and geological evidence appear promising with view of tree-ring chronologies.

Due to the construction of a new North-South subway in Cologne, Roman time harbour sediments were exposed and were sampled for luminescence dating. A very good independent age control was given by the precise knowledge of the chronology of Roman activity and by radiocarbon ages of charcoal samples. Hence, different methodological approaches within luminescence dating were applied for Holocene heterogeneously bleached fluvial samples and were compared to the known ages. For one sample, optically stimulated luminescence (OSL) dating was applied to coarse-grained quartz using a single aliquot regenerative-dose (SAR) protocol. After De-measurements, different statistical approaches were tested (i.e. arithmetic mean, median, minimum age model, finite mixture model, leading edge method and the Fuchs and Lang approach). It is demonstrated that the Fuchs and Lang approach along with the leading edge method yielded the best matching OSL ages with respect to the known ages.

For the other sample which showed feldspar contamination within the quartz signal, the post-IR blue stimulated luminescence (double SAR protocol) was measured in three different ways to calculate the Devalue: with continuous wave (CW) stimulation with an IR-bleach at 50°C and at 225°C for 100 s prior to the OSL, and pulsed OSL (POSL). It was demonstrated that the IR-stimulation at 225°C has very good potential to remove the feldspar signal contribution as well as pulsed OSL, but the former might deplete parts of the quartz OSL signal.

The history of the interlaboratory comparison of TL dating results in Poland started in the 1980s. At that time the Lublin, Warsaw and Silesian laboratories made the first attempts at TL dating of the same loess samples from the Odonów profile. However, the cooperation ceased for many years due to great differences in the obtained TL age estimates. The next interlaboratory comparisons were made in the years 2000–2009 for the loess samples from several Polish (Dybawka, Tarnawce, Dankowice, Biały Kościół) and Ukrainian (Boyanychi, Halych, Velykyj Hlybochok, Yezupil) profiles. Most of the compared dates, obtained for the loess deposits from the Upper Pleistocene and younger part of the Middle Pleistocene, were consistent. This encouraged us to undertake the Gdańsk-Lublin interlaboratory cooperation in dating of 200-700 ka old loess deposits. Nine samples were taken from the Ukrainian profile Mamalyha 2 in 2009 for this purpose. The TL dating results indicate that comparable dates are obtained in two laboratories for loess deposits younger than 300 ka BP. The TL signal obtained in the Gdańsk laboratory for the samples older than 300 ka BP was saturated so such samples should not be dated by the multi-aliquot regeneration method. The results obtained in the Lublin laboratory for these deposits (489–682 ka) confirm that it is possible to date loess deposits older than 500 ka. It probably results from the use of total-bleach method with preheating at 160°C for the equivalent dose determination.

The thermoluminescence (TL) dating method has a significant measurement error margin reaching almost 10%. Due to this fact it could be considered as little effective in case of such sites from the Roman period as burial grounds with many artefacts useful for archaeological dating. However, for many settlements from this period, where pottery is the only kind of artefacts, the TL method can give notable results. The main purpose of the study was to make an attempt at TL dating of pottery and clay daub samples from the Nieszawa Kolonia and Kręcieszki sites and to compare the obtained dates with the results of archaeological dating of selected features from the Przeworsk Culture settlements. In the Kręcieszki site the fragments of burnt clay daub were dated by the TL method for the first time in the Lublin laboratory. It turned out that clay daub is an equally good dating material as pottery. It can be found that the TL dating of pottery from Nieszawa Kolonia confirms two stages of settlement. The first settlement stage is related to the phases B2-B2/C1-C1a of the Roman period, i.e. from the beginning of the 2nd to the beginning of the 3rd century. The second group of TL dates corresponds to the phases C2D that is to the second stage of settlement, from the second half of the 3rd century to the half of the 5th century AD. The results of TL dating of pottery and clay daub in the Kręcieszki site are rather similar and correspond to the phase B1/B2 of the period of Roman influence, determined from pottery style, but can also indicate the phase B2/C1.

Recent work on infrared stimulated luminescence (IRSL) dating has focussed on finding and testing signals which show less or negligible fading. IRSL signals measured at elevated temperature following IR stimulation at 50°C (post-IR IRSL) have been shown to be much more stable than the low temperature IRSL signal and seem to have considerable potential for dating. For Early Pleistocene samples of both European and Chinese loess natural post-IR IRSL signals lying in the saturation region of the laboratory dose response curve have been observed; this suggests that there is no significant fading in nature. As a contribution to the further testing of post-IR IRSL dating, we have used 18 samples from two Japanese loess profiles for which quartz OSL and tephra ages up to 600 ka provide age control. After a preheat of 320°C (60 s), the polymineral fine grains (4–11 μm) were bleached with IR at 50°C (200 s) and the IRSL was subsequently measured at 290°C for 200 s. In general, the fading uncorrected post-IR IRSL ages agree with both the quartz OSL and the tephra ages. We conclude that the post-IR IRSL signal from these samples does not fade significantly and allows precise and accurate age determinations on these sediments.

A new measurement protocol has been tested on K-feldspars from Whanganui Inlet and Parengarenga Harbour, New Zealand. A Single Aliquot Regenerative (SAR) dose protocol, using two successive infrared (IR) stimulations (post-IR IR SAR protocol) is setup for these young (<1000 years) coastal sediments. Significant anomalous fading (g2days=7 %/decade) is observed using the conventional IR signal measured at 50°C. In contrast, the fading rate of the IR signal measured at elevated temperature (150°C) after the IR stimulation at 50°C (a post-IR IR signal) is not significant (g2days≤ 1 %/decade). Surprisingly low residual infrared stimulated luminescence (IRSL) signals were observed for a surface sample, suggesting that accurate ages as young as ∼50 years can be obtained for these recent deposits. IRSL ages ranging between 48±6 years and 1050±50 years are obtained from six samples, indicating that sediment accumulation has occurred at the two sites during the last millennia, despite a falling trend in relative sea-level in Whanganui Inlet and a stable relative sea-level at Parengarenga Harbour.

It has been suggested that the standardised growth curve (SGC) method can be used to de-terminate De accurately and reduce the measurement time. However, different opinions regarding the applicability of the SGC method exist. In this paper, we report the construction of quartz OSL SGC for 35 aeolian samples from different parts of the Horqin dunefield in northeastern China, and then test their applicability for De determination. Our results suggest that: 1) up to a regeneration dose of 80 Gy, the SGC of the Horqin dunefield can be fitted using the exponential plus linear equation, with the r2 value of 0.97, and all the regeneration dose points closely stick to the fitting line, implying that all samples share a very similar dose-response curve; 2) for samples with Des ranging from 1 to 50 Gy, the ratios of SAR De to SGC De fall within the range of 0.9–1.1, and the average ratio of SAR De to SGC De is 1.01±0.01, close to unity. Therefore, the construction of SGC is correct, and the SGC is an effective procedure for accurate De determination for samples from the study area.

The deposits of the Toruń Basin are dominated by a few-metre thick sand series which fill up buried valley-like depressions. In many cases they underlie the Weichselian till which builds up the ice marginal streamway (pradolina) terraces or they are exposed at the basin slopes. As the results of the geological and sedimentological studies, as well as of the dating of the deposits at the sites in the Toruń Basin indicate, the deposits include two fluvial series accumulated before the advancement of the Leszno Phase ice sheet, i.e. in Middle Weichselian and at the beginning of Late Weichselian. The oldest fluvial series connected with the Saalian Glaciation was found at the mouth section of the Drwęca Valley. The fluvial system of the Toruń Basin during Middle Weichselian and at the beginning of Late Weichselian developed in two phases of the sand-bed braided river. During the first one the river channel were dominated by large mid-riverbed sandbars, while during the second phase the water flow was smaller and, as a result, low transverse sandbars and two-dimensional dunes developed. Other active river channel also showed low-energy flows, more intensive meandering than in the case of the braided rivers, as well as sandy side-bars. Analysis of the rounding and frosting of the quartz grains indicate that the studied series of the Weichselian sandy deposits represent alluvia of a river which were fed from two diverse sources. The first one might have represented the alluvia of a warm river which transformed its load, while the other one might have mainly carried the underlying Quaternary deposits.

Difficulties in evaluating accurate equivalent doses for Late Quaternary sediments from the south coasts of Greece arose in the course of SAR measurements. Large scatter among apparent equivalent doses perplexed the evaluation of accurate mean estimates in circumstances where very large doses were involved. Besides, dose recovery experiments revealed that when intersection of the natural signal occurs onto the saturating segment of the growth curve, a distinct relationship between De and growth curve shape occurs. At very low slope angles, SAR tends to overestimate the recovered dose. The mechanism which controls the spread in equivalent dose estimation is investigated.

In the OSL dating of sediment, the scatter in equivalent dose (D e) between grains is almost always larger than would be expected due to counting statistics alone. Some scatter may be caused by insufficient (partial) bleaching of some of the grains prior to deposition. In order to date partially bleached sediment, it is essential to estimate the amount of scatter caused by other processes (e.g. grain-to-grain variability in the natural dose rate). Measurements of such scatter are performed at the single-grain level; by contrast, most OSL dating is performed on multi-grain subsamples, for which grain-to-grain scatter is reduced through averaging.

Here we provide a model for estimating the expected scatter (i.e. excluding that caused by partial bleaching) for multi-grain aliquots. The model requires as input the single-grain sensitivity distribution, the number of grains in the sub-samples, and the expected scatter at the single-grain level, all of which can be estimated to an adequate degree. The model compares well with measured values of scatter in D e, determined using aliquots of various sizes, and can be used to help produce a minimum-age D e from multi-grain subsamples that is consistent with single-grain data.

Using a set of modern/young (0 to about 200 years old) dust samples collected from the Chinese Loess Plateau the bleachability of IRSL measured at 50°C (IR50) and post-IR50 elevated temperature IRSL (measured at 225°C and at 290°C) is investigated by measuring the apparent (residual) doses recorded by these signals. Doses recorded by quartz OSL are used as a reference. Allowing for differences in dose rates it seems that both IRSL and post-IR IRSL signals yield residual doses that are significantly larger than the doses measured in quartz. These residual doses can be largely explained by thermal transfer caused by preheating. Nevertheless, we advise against the use of a low temperature preheat (<200°C) with IR50 to date loess samples because, as has been reported before, the signal appears to be thermally unstable. In general, we conclude that it may not be advisable to apply post-IR IRSL dating to Chinese loess samples where residuals of up to ∼20 Gy are a significant fraction of the total dose. However, these residuals quickly become unimportant when dating older samples, and this is the age range in which post-IR IRSL dating is likely to be most useful.