1. bookTom 69 (2022): Zeszyt 1 (June 2022)
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Petroleum source rock characteristics of the Mesozoic units, Mekelle Basin, northern Ethiopia

Data publikacji: 04 Sep 2023
Tom & Zeszyt: Tom 69 (2022) - Zeszyt 1 (June 2022)
Zakres stron: 1 - 13
Otrzymano: 11 Mar 2022
Przyjęty: 28 Mar 2022
Informacje o czasopiśmie
License
Format
Czasopismo
eISSN
1854-7400
Pierwsze wydanie
30 Mar 2016
Częstotliwość wydawania
4 razy w roku
Języki
Angielski
Introduction

Petroleum is considered as one of the geologic resources of Ethiopia and potential oil and gas occurrences are expected from the Ogaden, Blue Nile, Mekelle, Gambela and Southern Rift Basins [1]. Paleozoic shale units served as sources of hydrocarbon that fed sandstone and carbonate reservoirs and led to the formation of a significant amount of the world’s oil and gas resource [2] [3]. Large reserves of oil and gas were discovered within the Permian sandstone and carbonate reservoirs sourced mainly by Silurian shales throughout the Middle East (e.g., Iran, Iraq and Arabia) [4]. The Permian Calub Sandstone and Bokh Shale are also good reservoirs and source rocks respectively in the Ogaden Basin, Ethiopia [5, 6]. The middle to upper Jurassic formations which comprised limestone, dolostone, marl, shale and sandstone are also known to have the potential for petroleum occurrences [512]. The Ogaden Basin was intensively investigated and has become the focus of oil companies to look for petroleum due to potential discoveries of gas fields at Shilabo, Calub and Hilala [5]. And, the Blue Nile Basin was the second target and studied in terms of petroleum system [9, 13], whereas the petroleum potential of Mekelle Basin has not been studied except the discovery of oil shale deposits within the Paleozoic glacial sediments [14]. However, the presence of possible potential source rocks within the Mesozoic units was reported by different workers even if detailed evaluation of quality, quantity and maturity of the organic matters have not been carried out. These units include the Agula Shale and Antalo Limestone with brown to black micritic limestone, beds of mudstone, brown shale and greenish-black limestone interbeds [1516]. The Mekelle Basin requires a detailed evaluation of hydrocarbon prospectivity [1]. Therefore, this study is aimed at evaluating the petroleum source rock potential of these limestone and shale units including the Adigrat Sandstone.

Geological setting

The evolution of the Mekelle Basin is thought to have a close relationship with the East Africa Mesozoic rift basins, developed following the breakup of Gondwana [17]. Subduction along the Tethyan margin was considered to be the cause for the development of tensional stress in the Gondwana plate and its eventual breakup (Figure 1a) [18]. The breakup process was also triggered by the Permo – Triassic mantle plume, situated beneath the Karoo province, South Africa, that thermally weakened the lithosphere and contributed to the intracontinental rifting, widespread crustal extension and subsidence [18, 19]. These processes led to the development of the Permo – Triassic rift systems in the eastern part of Africa and created northwest-southeast trending aulacogen-like basins, reaching up to western and central Ethiopia [17, 2022] (Figure 1b).

Figure 1:

(a) Map showing Gondwana breakup (after [18]); (b) Mesozoic rift basins of the Horn of Africa including Ethiopia (after [21]).

The sedimentation began in the late Paleozoic within these fault-controlled depositional environments [17, 19, 20, 2328]. These rift-controlled sedimentary basins, in Ethiopia, include the Ogaden, Blue Nile and Mekelle Basins. The Mekelle Basin has also been considered as an intracontinental sag basin, formed due to cooling and thickening of a juvenile sub-continental lithospheric mantle and subsequent subsidence [29].

Some previous studies documented the petroleum potential of the Ogaden Basin [5, 6, 3033]. [9, 13] investigated the hydrocarbon potential in the Blue Nile Basin. The Mekelle and Omo basins were investigated by [14, 34] respectively. The Mekelle Basin covers 8000 km2 and comprises over 2000 meters thick Paleozoic to Mesozoic sedimentary successions [35] (Figure 2) which are considered to have geologically good properties to look for hydrocarbon [16].

Figure 2:

Geological map of the Mekelle Basin with sampling locations (after [42]). The inset map is a simplified geological map of Ethiopia (after [43]).

The Paleozoic units comprise about 300 meters thick of glacial origin clastic rocks [36] which were, first, described and subdivided into glacial sandstone (Enticho Sandstone) and tillite facies (Edaga Arbi Tillite) [37]. The Edaga Arbi Tillite was later named Edaga Arbi Glacial which comprises tillite, siltstone and shale facies [35]. Enticho Sandstone was also subdivided into two members; Lower Enticho Sandstone and Upper Enticho Sandstone [38]. Detailed facies analysis revealed that the late Paleozoic sediments (Upper Enticho Sandstone and Edaga Arbi Glacial) were formed due to a wide range of glaciogenic processes and depositional environments including sub- aquatic environments with two major glacier advance-retreat cycles [39]. Oil shale deposit was discovered, sandwiched between the Enticho Sandstone and Edaga Arbi glacials and, in some places, underlying the Adigrat Sandstone which has an average mineable bed-thickness of 55 meters, covering an area of 30 km2 with an estimated reserve of 4 billion tonnes [14]. The Triassic to middle Jurassic unit (Adigrat Sandstone) is about 300–650 meters thick and is considered to have a very good reservoir potential for petroleum [15, 16, 35]. The unit comprises fine-grained to coarsegrained sandstones and interbeds of siltstone and clay which were deposited in continental and shallow marine environments during the Triassic-middle Jurassic [35, 36].

The middle to upper Jurassic unit is carbonate (Antalo Limestone) with about 740 meters thick dominated mainly by yellow, white to black limestone with significant interbeds of marl, lenses of chert and cross-bedded sandstone [1517, 35]. The brown shale and black limestone interbeds of the Antalo Limestone could serve as very good potential source rocks [16]. The unit has some reservoir potential [40]. The unit is also considered as a marine shelf carbonate facies, equivalent to the Mesozoic carbonate units of the Middle East Arabian Basins having potential for oil and gas occurrences [41]. In the Ogaden Basin, the marl and shale layers of Uarandab Formation are potential source rocks, with Type II kerogen, having petroleum potential that ranges from 2 kg/ton to 20 kg HC/ton of rock [5]. The black shales and mudstones of the Upper Hamanlei of the Blue Nile Basin, are also matured source rocks for oil generation, with TOC up to 7 wt.% and hydrogen index (HI) between 465 mgHC/g and 660 mgHC/g [9]. The Agula Shale is characterized by gray to black shale, marl and clay subunits with inter-laminae of black limestone, gypsum and dolomite, and has 60 to 250 meters thickness that was deposited in lagoons under semiarid conditions [15] [35]. The Amba Aradam Sandstone is upper Jurassic-lower Cretaceous in age [15, 17] which conformably overlies the Agula Shale. It is 60–200 meters thick and comprises medium to coarse-grained white to pink color sandstone facies (at the northern part of the basin) and white sandstone and conglomerate facies with some clayey beds (at the southern part of the basin) [35]. It has been confirmed, from the present study, that a highly conglomeratic sandstone composed of very coarse pebble size and well rounded quartz grains is exposed in the southern part of the basin whereas in the northwestern part of the basin, it is very fine-grained with yellow, pink to reddish colors. This unit was deposited in fluvial-lacustrine depositional environments and is assumed to be a very good reservoir rock in the basin [16, 35].

Materials and methods

A total of fifteen samples made up of five black limestones and ten shales were collected from four outcrop locations for organic geochemical analyses. The samples were collected from the Adigrat Sandstone (one sample), Antalo Limestone (twelve samples) and Agula Shale (two samples). The petroleum potential of the samples was assessed from the Total Organic Carbon (TOC) and Rock-Eval pyrolysis. All laboratory procedures were carried out following the Norwegian Industry Guide to Organic Geochemical Analyses, fouth edition [44], at the Applied Petroleum Technology Ltd, (ALS Oil & Gas), UK. About 100 mg of sample was pulverized and diluted hydrochloric acid (HCl) was added to the pulverized rock samples to remove carbonate. The samples were then introduced into the Leco combustion oven, and the organic matter was directly converted to carbon dioxide through combustion. The amount of carbon in the samples was measured, as carbon dioxide, by an infrared (IR) detector. A Leco SC-632 carbon analyzer was used to measure the TOC and the amount of carbon was obtained and expressed in weight percent (wt.%). Rock-Eval pyrolysis was carried out using the Rock-Eval 6 instrument. Jet-Rock 1 was run and checked against the acceptable range given in [44]. Different hydrocarbon components (S1, S2 and S3) were volatilized and determined, with the help of a Flame Ionization Detector (FID). The samples were placed in the oven and heated to a temperature of 300 °C for 3 minutes, and Sχ values were detected. The oven temperature was again increased to 650 °C, at a programmed rate of 25°C/minute to detect S2 and S3values. Then, the pyrolysis products; S1, S2 and S3 peaks were normalized to the weight of the sample (mg HC/g sample). Tmax values were also determined with the S2 peaks.

Results and discussion
Field data

The investigated outcrop locations are Giba River, Mesobo, Enadayesus and Chelekot sections (Figure 3) where the studied layers from the Adigrat Sandstone, Antalo Limestone and Agula Shale represent black limestone and shale (Table 1). About 70 meters thick black limestone with the associated shale layer was logged from the Mesobo section which is found approximately 5 km north of the Mekelle town (Figure 4a). The shale layers are gray to black, with variable thicknesses ranging from 10 cm to 3 m (Figure 4b). At the vicinity of Mekelle town, thickly bedded black fine-grained limestone (30 cm to 1.3 m in thickness) associated with cyclic layers of black to gray shale, was identified along a stream-cut which represents about 16 meters thick part of the Antalo Limestone (Figure 4c). The shale beds are relatively consolidated, slightly greenish to gray, with well-developed, very thin laminations. Fissility is observed within the loose to semiconsolidated layers, whereas the consolidated layers are characterized by conchoidal fractures. At the bottom of this outcrop, there is a very thick loose to highly consolidated black shale, with thickness ranging from 40 cm to 4 m (Figure 4d). Around Giba River which is located about 25 km northwest of Mekelle town, gray-black shale layers with thickness ranging from 5 cm to 10 cm were also identified from the upper part of Adigrat Sandstone (Figures 5a, b). Gray-black shale layers also represent a significant part of the Agula Shale (Figure 5c).

Figure 3:

Lithologic logs showing the locations of samples collected for source rock characterization.

Figure 4:

Outcrop photographs showing black shale layers and limestone beds within the Antalo Limestone at the central part of the Mekelle Basin. (a) thickly bedded black fine-grained limestone (Mesobo section, sample MS-1); (b) black shale within black micritic limestone beds (sample MS-7); (c) 16 m thick stream-side cliff exposure comprising limestone and shale beds (samples EY-2 to EY-5) around Mekelle town (Endayesus section); (d) Black shale along stream at the bottom of Endayesus section (sample EY-1).

Figure 5:

Outcrop photographs showing black shale layers within the Adigrat Sandstone and Agula Shale, at the central part of the Mekelle Basin. (a) lower part of Antalo Limestone conformably overlies the upper part of Adigrat Sandstone at Giba River section; (b) about 5–10 cm thick oil shale beds (sample GV-1) from the upper part of Adigrat Sandstone; (c) Some part of the Agula Shale at Chelekot section (samples; CH-1, CH-2).

Outcrop samples collected for organic geochemical analyses.

Sample no.Sampling locationSample typeFormation
CH-113°25’36’’, 39°23’39’’, 1912 m asl.limestoneAgula Shale
CH-2shaleAntalo Limestone
EY-113°29’26’’, 39°29’07’’, 2113 m asl.shale 
EY-2shale
EY-3shale
EY-4limestone
EY-5shale
MS-113°33’23’’, 39°30’36’’, 2094 m asl.limestone 
MS-2shale
MS-3shale
MS-4limestone
MS-5limestone
MS-6shale
MS-7shale
GV-113°37’55’’, 39°24’51’’, 1818 m asl.shaleAdigrat Sandstone
Organic geochemistry

The results of measured and calculated source rock parameters for fifteen (15) limestone and shale samples are shown in Table 2. Two shale samples of the Mesobo section (MS-2 and MS-7), have 0.50 wt.% and 0.92 wt.% TOC values respectively, whereas the remaining five samples (MS-1, MS-3, MS-4, MS-5, MS-6), have TOC between 0.10–0.41 wt.%. From the Endayesus section, only one shale sample (EY-2), has 0.77 wt.% TOC while the remaining four samples have TOC values ranging from 0.2 to 0.25 wt.%. A shale sample from the underlying Adigrat Sandstone, in the Giba River section, recorded 0.42 wt.% TOC. In the Chelekot section, two samples from the overlying Agula Shale have 0.18 wt. % and 0.40 wt. % of TOC respectively. Only three samples (EY-2, MS-2 and MS-7) have TOC values above the 0.5% threshold [45]. The S3 values which represent CO2 content within the kerogen are relatively high compared to the S1 and S2 values (Table 2).

Rock-Eval pyrolysis data of the analyzed samples.

Sample no.Sample typeTOC (wt.%)S1S2S3TmaxHIOIPIPP
CH-1limestone0.180.000.000.17327094--0.00
CH-2shale0.400.010.000.255240621.000.01
EY-1shale0.250.000.000.264980106--0.00
EY-2shale0.770.010.010.204851.3260.500.02
EY-3shale0.200.000.010.9849554880.000.01
EY-4limestone0.210.020.070.64475343090.220.09
EY-5shale0.230.000.000.264960111--0.00
MS-1limestone0.110.000.000.30--0275--0.00
MS-2shale0.500.000.020.394934780.000.02
MS-3shale0.410.000.010.515052.441250.000.01
MS-4limestone0.100.000.000.284840294--0.00
MS-5limestone0.220.000.000.264840119--0.00
MS-6shale0.200.000.000.394910194--0.00
MS-7shale0.920.020.021.1051921190.500.04
GV-1shale0.420.000.000.35527083--0.00
Organic matter richness

The most critical parameters such as; TOC and Rock-Eval S1 and S2 values for most of the studied samples are below the standard for any form of hydrocarbon generation, which are unlikely to be considered as petroleum source rocks. The total organic content (TOC) below 0.5 wt. % and S2 values below 2.5 mg HC/g are generally considered as poor source rocks [4649]. Twelve of the studied samples have TOC between 0.11–0.42 wt.% which is in the range of poor quality whereas three of the shale samples with 0.5–0.92 wt.% indicate fair organic matter richness. However, S2 values are too low with very high pyrolysis Tmax. The type of kerogen and its source organic matter has been determined from a cross plot of hydrogen index (HI) and oxygen index (OI) (Figure 6a) by which Type IV kerogen with a high amount of organic carbon dioxide was identified for all of the analyzed limestone and shale samples. Type IV kerogen is derived from highly oxidized or reworked material of any origin [48, 50, 51]. The TOC and pyrolysis yield (S2) cross-plot also show very poor quality organic matter [47, 50] (Figure 6b).

Figure 6:

(a) Oxygen index (OI) and hydrogen index (HI) cross plot for the recognition of kerogen types (after [57]); (b) Kerogen type based on TOC versus pyrolysis yield (S2) cross-plot, showing very poor quality organic matter for hydrocarbon generation (after [47]).

Organic matter maturity

The thermal maturity of the analyzed shale and limestone samples was determined from the Rock-Eval Tmax which is the temperature at which the S2 peak occurs during pyrolysis and can be correlated with the type of organic matter (kerogen) [46, 5255]. The different levels of thermal maturity of the organic matters which are determined from Tmax could qualitatively and quantitatively be expressed as immature (<435 0C), early mature (435–445 0C), peak mature (445– 450 0C), late mature (450–470 0C) and postmature (>470 0C) [48]. Therefore, thermal maturity together with the other source rock parameters such as the total organic carbon (TOC) is significant to determine the quality of a given source rock [56]. The measured Tmax value for one sample is 327 0C which max shows an immature stage and nine samples have Tmax that ranges 475–498 0C and four samples are in between 505–527 0C indicating post mature stage. The level of thermal maturity could also graphically be determined from T and hydrogen index cross max plot (Figure 7a). Hence, the maturity level of the organic matter in all of the analyzed samples indicates a post-mature stage.

Figure 7:

(a) Rock-Eval Tmax versus hydrogen index (HI) plot showing the thermal maturity level of the organic matter (after [57]); (b) TOC versus (S1+ S2) cross-plot, indicating poor hydrocarbon generating potential (after [47]).

Hydrocarbon generating potential

The hydrocarbon generating potential of source rocks is indicated with the sum of Rock-eval S1 and S2 values, which could be expressed qualitatively and quantitatively as; poor (0–3 mgHC/g), fair (3–6 mgHC/g), good (6–12 mgHC/g), very good (12–24 mgHC/g) and excellent (>24 mgHC/g) [4648]. The S1 values for most of the samples are 0.00 mgHC/g, with some samples having 0.01–0.02 mgHC/g values. S2 values for nine (9) of the studied samples are 0.00 mgHC/g, whereas the remaining six (6) samples range from 0.01 to 0.07 mgHC/g. Therefore, both the S1 and S2 values indicate that the studied samples have a very low potential for any form of hydrocarbon generation. Cross plot of S1 + S2 vs TOC shows that the samples have poor oil generating potential (Figure 7b).

Conclusions

Field evidence showed that the studied units comprised black shale and black limestone beds which seem having adequate organic matter. However, the organic geochemical analyses revealed low organic content of the analyzed samples, indicating that the black color of the samples is not a diagnostic feature of organic richness which could most probably be due to iron oxide impurities. The TOC values of a few samples indicate fair organic matter richness whereas about 80% of the samples have poor organic matter quality. The cross-plots of oxygen and hydrogen indices as well as S2 versus TOC indicate Type IV and dray gas-prone kerogen. The Tmax versus hydrogen index crossplot shows that the organic matter is in a late catagenesis stage and thermally over-mature. Therefore, the source rock parameters indicate poor petroleum generating potential. However, since some outcrop samples of the Antalo Limestone have shown fair organic richness, further study is required, especially from core samples, to assure the source rock potential of this unit.

Figure 1

(a) Map showing Gondwana breakup (after [18]); (b) Mesozoic rift basins of the Horn of Africa including Ethiopia (after [21]).
(a) Map showing Gondwana breakup (after [18]); (b) Mesozoic rift basins of the Horn of Africa including Ethiopia (after [21]).

Figure 2

Geological map of the Mekelle Basin with sampling locations (after [42]). The inset map is a simplified geological map of Ethiopia (after [43]).
Geological map of the Mekelle Basin with sampling locations (after [42]). The inset map is a simplified geological map of Ethiopia (after [43]).

Figure 3

Lithologic logs showing the locations of samples collected for source rock characterization.
Lithologic logs showing the locations of samples collected for source rock characterization.

Figure 4

Outcrop photographs showing black shale layers and limestone beds within the Antalo Limestone at the central part of the Mekelle Basin. (a) thickly bedded black fine-grained limestone (Mesobo section, sample MS-1); (b) black shale within black micritic limestone beds (sample MS-7); (c) 16 m thick stream-side cliff exposure comprising limestone and shale beds (samples EY-2 to EY-5) around Mekelle town (Endayesus section); (d) Black shale along stream at the bottom of Endayesus section (sample EY-1).
Outcrop photographs showing black shale layers and limestone beds within the Antalo Limestone at the central part of the Mekelle Basin. (a) thickly bedded black fine-grained limestone (Mesobo section, sample MS-1); (b) black shale within black micritic limestone beds (sample MS-7); (c) 16 m thick stream-side cliff exposure comprising limestone and shale beds (samples EY-2 to EY-5) around Mekelle town (Endayesus section); (d) Black shale along stream at the bottom of Endayesus section (sample EY-1).

Figure 5

Outcrop photographs showing black shale layers within the Adigrat Sandstone and Agula Shale, at the central part of the Mekelle Basin. (a) lower part of Antalo Limestone conformably overlies the upper part of Adigrat Sandstone at Giba River section; (b) about 5–10 cm thick oil shale beds (sample GV-1) from the upper part of Adigrat Sandstone; (c) Some part of the Agula Shale at Chelekot section (samples; CH-1, CH-2).
Outcrop photographs showing black shale layers within the Adigrat Sandstone and Agula Shale, at the central part of the Mekelle Basin. (a) lower part of Antalo Limestone conformably overlies the upper part of Adigrat Sandstone at Giba River section; (b) about 5–10 cm thick oil shale beds (sample GV-1) from the upper part of Adigrat Sandstone; (c) Some part of the Agula Shale at Chelekot section (samples; CH-1, CH-2).

Figure 6

(a) Oxygen index (OI) and hydrogen index (HI) cross plot for the recognition of kerogen types (after [57]); (b) Kerogen type based on TOC versus pyrolysis yield (S2) cross-plot, showing very poor quality organic matter for hydrocarbon generation (after [47]).
(a) Oxygen index (OI) and hydrogen index (HI) cross plot for the recognition of kerogen types (after [57]); (b) Kerogen type based on TOC versus pyrolysis yield (S2) cross-plot, showing very poor quality organic matter for hydrocarbon generation (after [47]).

Figure 7

(a) Rock-Eval Tmax versus hydrogen index (HI) plot showing the thermal maturity level of the organic matter (after [57]); (b) TOC versus (S1 + S2) cross-plot, indicating poor hydrocarbon generating potential (after [47]).
(a) Rock-Eval Tmax versus hydrogen index (HI) plot showing the thermal maturity level of the organic matter (after [57]); (b) TOC versus (S1 + S2) cross-plot, indicating poor hydrocarbon generating potential (after [47]).

Rock-Eval pyrolysis data of the analyzed samples.

Sample no. Sample type TOC (wt.%) S1 S2 S3 Tmax HI OI PI PP
CH-1 limestone 0.18 0.00 0.00 0.17 327 0 94 -- 0.00
CH-2 shale 0.40 0.01 0.00 0.25 524 0 62 1.00 0.01
EY-1 shale 0.25 0.00 0.00 0.26 498 0 106 -- 0.00
EY-2 shale 0.77 0.01 0.01 0.20 485 1.3 26 0.50 0.02
EY-3 shale 0.20 0.00 0.01 0.98 495 5 488 0.00 0.01
EY-4 limestone 0.21 0.02 0.07 0.64 475 34 309 0.22 0.09
EY-5 shale 0.23 0.00 0.00 0.26 496 0 111 -- 0.00
MS-1 limestone 0.11 0.00 0.00 0.30 -- 0 275 -- 0.00
MS-2 shale 0.50 0.00 0.02 0.39 493 4 78 0.00 0.02
MS-3 shale 0.41 0.00 0.01 0.51 505 2.44 125 0.00 0.01
MS-4 limestone 0.10 0.00 0.00 0.28 484 0 294 -- 0.00
MS-5 limestone 0.22 0.00 0.00 0.26 484 0 119 -- 0.00
MS-6 shale 0.20 0.00 0.00 0.39 491 0 194 -- 0.00
MS-7 shale 0.92 0.02 0.02 1.10 519 2 119 0.50 0.04
GV-1 shale 0.42 0.00 0.00 0.35 527 0 83 -- 0.00

Outcrop samples collected for organic geochemical analyses.

Sample no. Sampling location Sample type Formation
CH-1 13°25’36’’, 39°23’39’’, 1912 m asl. limestone Agula Shale
CH-2 shale Antalo Limestone
EY-1 13°29’26’’, 39°29’07’’, 2113 m asl. shale  
EY-2 shale
EY-3 shale
EY-4 limestone
EY-5 shale
MS-1 13°33’23’’, 39°30’36’’, 2094 m asl. limestone  
MS-2 shale
MS-3 shale
MS-4 limestone
MS-5 limestone
MS-6 shale
MS-7 shale
GV-1 13°37’55’’, 39°24’51’’, 1818 m asl. shale Adigrat Sandstone

World Bank (2016): Ethiopia Oil and Gas Sector Development: Support for Review and Update of Policy and Regulatory Framework. Final Report. The World Bank, 72 p. World Bank ( 2016 ): Ethiopia Oil and Gas Sector Development: Support for Review and Update of Policy and Regulatory Framework . Final Report . The World Bank , 72 p. Search in Google Scholar

Ehrenberg, S.N., Nadeau, P.H. (2005): Sandstone vs. Carbonate petroleum reservoirs: A global perspective on porosity-depth and porosity-permeability relationships. American Association of Petroleum Geologists Bulletin, 89(4), pp. 435–445. Ehrenberg S.N. Nadeau P.H. ( 2005 ): Sandstone vs. Carbonate petroleum reservoirs: A global perspective on porosity-depth and porosity-permeability relationships . American Association of Petroleum Geologists Bulletin , 89 ( 4 ), pp. 435 445 . Search in Google Scholar

Ahr, W.M. (2008): Geology of Carbonate Reservoirs: The Identification, Description, and Characterization of Hydrocarbon Reservoirs in Carbonate Rocks. John Wiley and Sons: New Jersey, 277 p. Ahr W.M. ( 2008 ): Geology of Carbonate Reservoirs: The Identification, Description, and Characterization of Hydrocarbon Reservoirs in Carbonate Rocks . John Wiley and Sons : New Jersey , 277 p. Search in Google Scholar

Edgell, H.S. (1977): The Permian system as an oil and gas reservoir in Iran, Iraq and Arabia. Proc. Second Iranian Geological Symposium, pp. 161–201. Edgell H.S. ( 1977 ): The Permian system as an oil and gas reservoir in Iran, Iraq and Arabia . Proc. Second Iranian Geological Symposium , pp. 161 201 . Search in Google Scholar

Hunegnaw, A. Sage, L., Gonnard, R. (1998): Hydrocarbon Potential of the Intracratonic Ogaden Basin, SE Ethiopia. Journal of Petroleum Geology, 21, pp. 401–425. Hunegnaw A Sage L. Gonnard R . ( 1998 ): Hydrocarbon Potential of the Intracratonic Ogaden Basin, SE Ethiopia . Journal of Petroleum Geology , 21 , pp. 401 425 . Search in Google Scholar

Tsegaye, S.G. Nton, M.E. Boboye, O.A., Ahmed, W. (2018): Geochemical Characteristics and Hydrocarbon Generation Modelling of Early Triassic to Late Cretaceous Formations within Ogaden Basin, Ethiopia. Journal of Petroleum Science and Technology, 8(4), pp. 58–75. Tsegaye S.G. Nton M.E. Boboye O.A. Ahmed W . ( 2018 ): Geochemical Characteristics and Hydrocarbon Generation Modelling of Early Triassic to Late Cretaceous Formations within Ogaden Basin, Ethiopia . Journal of Petroleum Science and Technology , 8 ( 4 ), pp. 58 75 . Search in Google Scholar

Carrigan, W.J. Cole, G.A. Colling, E.L., Jones, P.J. (1995): Geochemistry of the Upper Jurassic Tuwaiq Mountain and Hanifa Formation Petroleum Source Rocks of Eastern Saudi Arabia. In: Petroleum Source Rocks, Katz, B.J. (eds.). Springer-Verlag: Berlin, pp. 67–87. Carrigan W.J. Cole G.A. Colling E.L. Jones P.J. ( 1995 ): Geochemistry of the Upper Jurassic Tuwaiq Mountain and Hanifa Formation Petroleum Source Rocks of Eastern Saudi Arabia . In: Petroleum Source Rocks , Katz B.J. (eds.). Springer-Verlag : Berlin , pp. 67 87 . Search in Google Scholar

Csato, I., Habib, A., Kiss, K., Koncz, I. (2001): Play concepts of oil exploration in Yemen: MOL’s experience in 1996-2000. Oil and Gas Journal, 99(23), pp. 68–74. Csato I. Habib A. Kiss K. Koncz I . ( 2001 ): Play concepts of oil exploration in Yemen: MOL’s experience in 1996-2000 . Oil and Gas Journal , 99 ( 23 ), pp. 68 74 . Search in Google Scholar

Wolela, A. (2007): Source Rock Potential of the Blue Nile (Abay) Basin, Ethiopia. Journal of Petroleum Geology, 30(4), pp. 389–402. Wolela A . ( 2007 ): Source Rock Potential of the Blue Nile (Abay) Basin, Ethiopia . Journal of Petroleum Geology , 30 ( 4 ), pp. 389 402 . Search in Google Scholar

Hakimi, M.H. Abdullah, W.H., Shalaby, M.R. (2010): Organic geochemistry and thermal maturity of the Madbi Formation, East Shabowah Oil fields, Masila Basin, Yemen. Bulletin of the Geological Society of Malaysia, 56, pp. 41–48. Hakimi M.H. Abdullah W.H. Shalaby M.R. ( 2010 ): Organic geochemistry and thermal maturity of the Madbi Formation, East Shabowah Oil fields, Masila Basin, Yemen . Bulletin of the Geological Society of Malaysia , 56 , pp. 41 48 . Search in Google Scholar

Hakimi, M.H., Abdullah, W.H. (2014): Thermal maturity history and petroleum generation modeling for the Upper Jurassic Madbi source rocks in the Marib-Shabowah Basin, western Yemen. Marine and Petroleum Geology, 59, pp. 202–216. Hakimi M.H. Abdullah W.H. ( 2014 ): Thermal maturity history and petroleum generation modeling for the Upper Jurassic Madbi source rocks in the Marib-Shabowah Basin, western Yemen . Marine and Petroleum Geology , 59 , pp. 202 216 . Search in Google Scholar

Hakimi, M.H., Abdullah, W.H., Shalaby, M.R. (2012): Madbi-Biyadh/Qishn (!) petroleum system in the onshore Masila Basin of the Eastern Yemen. Marine and Petroleum Geology, 35, pp. 116–127. Hakimi M.H. Abdullah W.H. Shalaby M.R. ( 2012 ): Madbi-Biyadh/Qishn (!) petroleum system in the onshore Masila Basin of the Eastern Yemen . Marine and Petroleum Geology , 35 , pp. 116 127 . Search in Google Scholar

Mammo, T. (2010): Delineation of sub-basalt sedimentary basins in hydrocarbon exploration in North Ethiopia. Marine and Petroleum Geology, 27, pp. 895–908. Mammo T . ( 2010 ): Delineation of sub-basalt sedimentary basins in hydrocarbon exploration in North Ethiopia . Marine and Petroleum Geology , 27 , pp. 895 908 . Search in Google Scholar

Yihdego, Y., Salem, H.S., Kafui, B.G., Veljkovic, Z. (2018): Economic geology value of oil shale deposits: Ethiopia (Tigray) and Jordan. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 40(17), pp. 2079–2096. Yihdego Y. Salem H.S. Kafui B.G. Veljkovic Z . ( 2018 ): Economic geology value of oil shale deposits: Ethiopia (Tigray) and Jordan . Energy Sources, Part A: Recovery, Utilization and Environmental Effects , 40 ( 17 ), pp. 2079 2096 . Search in Google Scholar

Bosellini, A., Russo, A., Fantozzi, P.L., Assefa, G., Solomon, T. (1997): The Mesozoic Succession of the Mekele Outlier (Tigre Province, Ethiopia). Memorie diScienze Geologiche, 49, pp. 95–116. Bosellini A. Russo A. Fantozzi P.L. Assefa G. Solomon T . ( 1997 ): The Mesozoic Succession of the Mekele Outlier (Tigre Province, Ethiopia) . Memorie diScienze Geologiche , 49 , pp. 95 116 . Search in Google Scholar

EMoM. (2011): Petroleum Exploration in Ethiopia: Information and Opportunities. Unpublished Report, Ethiopian Ministry of Mines, Addis Ababa, pp. 1–20. EMoM . ( 2011 ): Petroleum Exploration in Ethiopia: Information and Opportunities . Unpublished Report , Ethiopian Ministry of Mines , Addis Ababa , pp. 1 20 . Search in Google Scholar

Kazmin, V. (1975): Explanation of the geological map of Ethiopia. Geological Survey of Ethiopia. Bulletin, 1, pp. 1–14. Kazmin V . ( 1975 ): Explanation of the geological map of Ethiopia. Geological Survey of Ethiopia . Bulletin , 1 , pp. 1 14 . Search in Google Scholar

Storey, B.C. (1993): Tectonic Controls on Gondwana break-up Models: Evidence from the Proto-Pacific Margin of Antarctica and the Southern Andes. Second ISAG, pp. 551–554. Storey B.C. ( 1993 ): Tectonic Controls on Gondwana break-up Models: Evidence from the Proto-Pacific Margin of Antarctica and the Southern Andes . Second ISAG , pp. 551 554 . Search in Google Scholar

Worku, T., Astin, T.R. (1992): The Karoo to Recent Rifting in the Western Branch of the East-African Rift System: A Bibliographical Synthesis. Musée Royal de l’Afrique Centrale, 83, pp. 63–82. Worku T. Astin T.R. ( 1992 ): The Karoo to Recent Rifting in the Western Branch of the East-African Rift System: A Bibliographical Synthesis . Musée Royal de l’Afrique Centrale , 83 , pp. 63 82 . Search in Google Scholar

Binks, R.M., Fairhead, J.D. (1992): A plate tectonic setting for Mesozoic rifts of West and Central Africa. In: Geodynamics of Rifting, Volume II. Case History Studies on Rifts: North and South America and Africa, Ziegler, P.A. (eds.). Tectonophysics, 213, pp. 141–151. Binks R.M. Fairhead J.D. ( 1992 ): A plate tectonic setting for Mesozoic rifts of West and Central Africa . In: Geodynamics of Rifting, Volume II. Case History Studies on Rifts: North and South America and Africa , Ziegler P.A. (eds.). Tectonophysics , 213 , pp. 141 151 . Search in Google Scholar

Gani, N.D.S., Abdelsalam, M.G., Gera, S., Gani, M.R. (2009): Stratigraphic and structural evolution of the Blue Nile Basin, Northwestern Ethiopian Plateau. Geological Journal, 44, pp. 30–56. Gani N.D.S. Abdelsalam M.G. Gera S. Gani M.R. ( 2009 ): Stratigraphic and structural evolution of the Blue Nile Basin, Northwestern Ethiopian Plateau . Geological Journal , 44 , pp. 30 56 . Search in Google Scholar

Russo, A., Assefa, G., Atnafu, B. (1994): Sedimentary evolution of the Abay River (Blue Nile) Basin, Ethiopia. Neues Jahrbuch Für Geologie und Paläontologie, 5, pp. 291–308. Russo A. Assefa G. Atnafu B . ( 1994 ): Sedimentary evolution of the Abay River (Blue Nile) Basin, Ethiopia . Neues Jahrbuch Für Geologie und Paläontologie , 5 , pp. 291 308 . Search in Google Scholar

Bosellini, A. (1988): The continental margins of Somalia. Geology and Geophysics of continental margins. American Association of Petroleum Geologists Memoir, 53, pp. 185–205. Bosellini A . ( 1988 ): The continental margins of Somalia . Geology and Geophysics of continental margins. American Association of Petroleum Geologists Memoir , 53 , pp. 185 205 . Search in Google Scholar

Coffin, M.F., Rabinowitz, P.D. (1988): Evolution of the Conjugate East African-Madagascan margins and the Western Somali Basin. Geological Society of America, Special Paper, 226, pp. 1–78. Coffin M.F. Rabinowitz P.D. ( 1988 ): Evolution of the Conjugate East African-Madagascan margins and the Western Somali Basin . Geological Society of America, Special Paper , 226 , pp. 1 78 . Search in Google Scholar

Bosworth, W. (1992): Mesozoic and early Tertiary rift tectonics in East Africa. In: Seismology and Related Sciences in Africa, Ebinger, C.J., Gupta, H.K., Nyambok, I.O. (eds.). Tectonophysics, 209, pp. 115–137. Bosworth W . ( 1992 ): Mesozoic and early Tertiary rift tectonics in East Africa . In: Seismology and Related Sciences in Africa , Ebinger C.J. Gupta H.K. Nyambok I.O. (eds.). Tectonophysics , 209 , pp. 115 137 . Search in Google Scholar

Worku, T., Astin, T.R. (1992): The Karoo sediments (Late Palaeozoic to Early Jurassic) of the Ogaden Basin, Ethiopia. Sedimentary Geology, 76, pp. 7–21. Worku T. Astin T.R. ( 1992 ): The Karoo sediments (Late Palaeozoic to Early Jurassic) of the Ogaden Basin, Ethiopia . Sedimentary Geology , 76 , pp. 7 21 . Search in Google Scholar

Bosworth, W., Morley, C.K. (1994): Structural and stratigraphic evolution of the Anza rift, Kenya. Tectonophysics, 236, pp. 93–115. Bosworth W. Morley C.K. ( 1994 ): Structural and stratigraphic evolution of the Anza rift, Kenya . Tectonophysics , 236 , pp. 93 115 . Search in Google Scholar

Hankel, O. (1994): Early Permian to Middle Jurassic rifting and sedimentation in East Africa and Madagascar. Geologische Rundschau, 83, pp. 703–710. Hankel O . ( 1994 ): Early Permian to Middle Jurassic rifting and sedimentation in East Africa and Madagascar . Geologische Rundschau , 83 , pp. 703 710 . Search in Google Scholar

Alemu, T., Abdelsalam, M.G., Dawit, E.L., Atnafu, B., Mickus, K.L. (2018): The Paleozoic-Mesozoic Mekele Sedimentary Basin in Ethiopia: An example of an exhumed IntraCONtinental Sag (ICONS) basin. Journal of African Earth Sciences, 143, pp. 40–58. Alemu T. Abdelsalam M.G. Dawit E.L. Atnafu B. Mickus K.L. ( 2018 ): The Paleozoic-Mesozoic Mekele Sedimentary Basin in Ethiopia: An example of an exhumed IntraCONtinental Sag (ICONS) basin . Journal of African Earth Sciences , 143 , pp. 40 58 . Search in Google Scholar

Assefa, G. (1988): Potential hydrocarbon-generating rock units within the Phanerozoic sequence of the Ogaden Basin, Ethiopia: A preliminary assessment using the Lopatin model. Journal of Petroleum Geology, 11(4), pp. 461–472. Assefa G . ( 1988 ): Potential hydrocarbon-generating rock units within the Phanerozoic sequence of the Ogaden Basin, Ethiopia: A preliminary assessment using the Lopatin model . Journal of Petroleum Geology , 11 ( 4 ), pp. 461 472 . Search in Google Scholar

Worku, T. (1988): Sedimentology, diagenesis and hydrocarbon potential of the Karoo sediments (Late Paleozoic to early Jurassic) Ogaden Basin, Ethiopia. M. Phil. Thesis. University of Readnig: UK, 222 p. Worku T . ( 1988 ): Sedimentology, diagenesis and hydrocarbon potential of the Karoo sediments (Late Paleozoic to early Jurassic) Ogaden Basin, Ethiopia . M. Phil. Thesis . University of Readnig : UK , 222 p. Search in Google Scholar

Geleta, S. (1998): Biostratigraphy, depositional environment, basin evolution and hydrocarbon potential of the late Triassic to late Jurassic succession, Ogaden Basin, Ethiopia. PhD Thesis. Institute und Museum fur Geologie und palontologie: Tubingen, 78 p. Geleta S . ( 1998 ): Biostratigraphy, depositional environment, basin evolution and hydrocarbon potential of the late Triassic to late Jurassic succession, Ogaden Basin, Ethiopia . PhD Thesis . Institute und Museum fur Geologie und palontologie : Tubingen , 78 p. Search in Google Scholar

Oljira, T., Nton, M.E., Sonibare, O.O. (2020): Organic Geochemical Evaluation of Shale Units of Bokh Formation, Ogaden Basin, Ethiopia. Open Journal of Geology,10, pp. 565–578. Oljira T. Nton M.E. Sonibare O.O. ( 2020 ): Organic Geochemical Evaluation of Shale Units of Bokh Formation, Ogaden Basin, Ethiopia . Open Journal of Geology , 10 , pp. 565 578 . Search in Google Scholar

Mammo, T. (2012): Analysis of gravity field to reconstruct the structure of Omo basin in SW Ethiopia and implications for hydrocarbon potential. Marine and Petroleum Geology, 29, pp. 104–114. Mammo T . ( 2012 ): Analysis of gravity field to reconstruct the structure of Omo basin in SW Ethiopia and implications for hydrocarbon potential . Marine and Petroleum Geology , 29 , pp. 104 114 . Search in Google Scholar

Beyth, M. (1972): Paleozoic-Mesozoic Sedimentary Basin of Mekele Outlier, Northern Ethiopia. American Association of Petroleum Geologists Bulletin, 56(12), pp. 2426–2439. Beyth M . ( 1972 ): Paleozoic-Mesozoic Sedimentary Basin of Mekele Outlier, Northern Ethiopia . American Association of Petroleum Geologists Bulletin , 56 ( 12 ), pp. 2426 2439 . Search in Google Scholar

Bussert, R., Dawit, E.L. (2009): Unexpected diversity: New results on the stratigraphy and sedimentology of Palaeozoic and Mesozoic siliciclastic sediments in Northern Ethiopia. ZentralblattFür Geologie und Paläontologie, Teil I, pp. 181–198. Bussert R. Dawit E.L. ( 2009 ): Unexpected diversity: New results on the stratigraphy and sedimentology of Palaeozoic and Mesozoic siliciclastic sediments in Northern Ethiopia . ZentralblattFür Geologie und Paläontologie , Teil I , pp. 181 198 . Search in Google Scholar

Dow, D., Beyth, M., Hailu, T. (1971): Palaeozoic glacial rocks recently discovered in northern Ethiopia. Geological Magazine, 108, pp. 53–60. Dow D. Beyth M. Hailu T . ( 1971 ): Palaeozoic glacial rocks recently discovered in northern Ethiopia . Geological Magazine , 108 , pp. 53 60 . Search in Google Scholar

Bussert, R., Schrank, E. (2007): Palynological evidence for a latest Carboniferous-Early Permian glaciation in Northern Ethiopia. Journal of African Earth Sciences, 49, pp. 201–210. Bussert R. Schrank E . ( 2007 ): Palynological evidence for a latest Carboniferous-Early Permian glaciation in Northern Ethiopia . Journal of African Earth Sciences , 49 , pp. 201 210 . Search in Google Scholar

Bussert, R. (2014): Depositional environments during the Late Palaeozoic ice age (LPIA) in northern Ethiopia, NE Africa. Journal of African Earth Sciences, 99, pp. 386–407. Bussert R . ( 2014 ): Depositional environments during the Late Palaeozoic ice age (LPIA) in northern Ethiopia, NE Africa . Journal of African Earth Sciences , 99 , pp. 386 407 . Search in Google Scholar

Adefris, D., Nton, M.E., Boboye, O.A., Atnafu, B. (2021): Aspects of Diagenetic and Sequence Stratigraphic Framework on Reservoir Potential of Antalo Limestone, Mekelle Basin, northern Ethiopia. Nigerian Association of Petroleum Explorationists Bulletin, 30, pp. 26–37. Adefris D. Nton M.E. Boboye O.A. Atnafu B . ( 2021 ): Aspects of Diagenetic and Sequence Stratigraphic Framework on Reservoir Potential of Antalo Limestone, Mekelle Basin, northern Ethiopia . Nigerian Association of Petroleum Explorationists Bulletin , 30 , pp. 26 37 . Search in Google Scholar

Peterson, J.A. (1985): Geology and petroleum resources of central and east-central Africa. OpenFile Report 85-589. United States Geological Survey, 48 p. Peterson J.A. ( 1985 ): Geology and petroleum resources of central and east-central Africa . OpenFile Report 85-589. United States Geological Survey , 48 p. Search in Google Scholar

Arkin, Y., Beyth, M., Dow, D.B., Levitte, D., Haile, T., Hailu, T. (1971): Geological Map of Mekele Sheet Area ND 37-11, Tigre Province. Geological Survey of Ethiopia, Addis Ababa, 1p. Arkin Y. Beyth M. Dow D.B. Levitte D. Haile T. Hailu T . ( 1971 ): Geological Map of Mekele Sheet Area ND 37-11, Tigre Province . Geological Survey of Ethiopia , Addis Ababa , 1 p. Search in Google Scholar

MoWR (2009): Water information and knowledge management project: strengthening water quality data generation and management. Draft Final Report, August 2009; 240 p. MoWR ( 2009 ): Water information and knowledge management project: strengthening water quality data generation and management . Draft Final Report , August 2009 ; 240 p. Search in Google Scholar

Weiss, H.M., Wilhelms, A., Mills, N., Scotchmer, J., Hall, P.B., Lind, K., Brekke, T. (2000): NIGOGA–The Norwegian Industry Guide to Organic Geochemical Analyses [online]. Edition 4.0, Norsk Hydro, Statoil, Geolab Nor, SINTEF Petroleum Research and the Norwegian Petroleum Directorate, 102 p. Weiss H.M. Wilhelms A. Mills N. Scotchmer J. Hall P.B. Lind K. Brekke T . ( 2000 ): NIGOGA–The Norwegian Industry Guide to Organic Geochemical Analyses [online]. Edition 4.0 , Norsk Hydro, Statoil, Geolab Nor, SINTEF Petroleum Research and the Norwegian Petroleum Directorate , 102 p. Search in Google Scholar

Tissot, B.P., Welte, D.H. (1984): Petroleum Formation and Occurrence. Springer-Verlag: Berlin, 699 p. Tissot B.P. Welte D.H. ( 1984 ): Petroleum Formation and Occurrence . Springer-Verlag : Berlin , 699 p. Search in Google Scholar

Krokstad, W., Schou, L., Leith, L.T., Vigran, J.O., Due, A., Andersen, W., Berg, T., Haugen, G., Vinge, T. (1986): Source Rock Evaluation of Well 15/12-4. Hydrocarbon Characterisation of Oil, Cuttings and Cores. Issue 16, 300 p. Krokstad W. Schou L. Leith L.T. Vigran J.O. Due A. Andersen W. Berg T. Haugen G. Vinge T . ( 1986 ): Source Rock Evaluation of Well 15/12-4. Hydrocarbon Characterisation of Oil, Cuttings and Cores . Issue 16 , 300 p. Search in Google Scholar

Peters, K.E. (1986): Guidelines for evaluating petroleum source rock using programmed pyrolysis. American Association of Petroleum Geologists Bulletin, 70(3), pp. 318–329. Peters K.E. ( 1986 ): Guidelines for evaluating petroleum source rock using programmed pyrolysis . American Association of Petroleum Geologists Bulletin , 70 ( 3 ), pp. 318 329 . Search in Google Scholar

Peters, K.E., Cassa, M.R. (1994): Applied Source Rock Geochemistry. In: The petroleum system-from source to trap, Magoon, L.B., Dow, W.G. (eds.). American Association of Petroleum Geologists Memoir, 60, pp. 93–120. Peters K.E. Cassa M.R. ( 1994 ): Applied Source Rock Geochemistry . In: The petroleum system-from source to trap , Magoon L.B. Dow W.G. (eds.). American Association of Petroleum Geologists Memoir , 60 , pp. 93 120 . Search in Google Scholar

Al-Selwi, A., Joshi, M. (2015): Oil and Gas Research Source Rock Evaluation using Total Organic Carbon (TOC) and the Loss-On-Ignition (LOI) Techniques. Oil and Gas Research, 1(1), pp. 1–5. Al-Selwi A. Joshi M . ( 2015 ): Oil and Gas Research Source Rock Evaluation using Total Organic Carbon (TOC) and the Loss-On-Ignition (LOI) Techniques . Oil and Gas Research , 1 ( 1 ), pp. 1 5 . Search in Google Scholar

Waples, D.W. (1985): Geochemistry in Petroleum Exploration. D. Reidel Publishing Company: Boston, 232 p. Waples D.W. ( 1985 ): Geochemistry in Petroleum Exploration . D. Reidel Publishing Company : Boston , 232 p. Search in Google Scholar

McCarthy, K., Niemann, M., Palmowski, D., Peters, K. (2011): Basic Petroleum Geochemistry for Source Rock Evaluation. Oilfield Review, 23, pp. 32–43. McCarthy K. Niemann M. Palmowski D. Peters K . ( 2011 ): Basic Petroleum Geochemistry for Source Rock Evaluation . Oilfield Review , 23 , pp. 32 43 . Search in Google Scholar

Espitalie, J., Laporte, J.L., Madec, M., Marquis, F., Leplat, P., Paulet, J., Boutefeu, A. (1977): Rapid method of characterizing source rocks and their petroleum potential and degree of maturity. Revue de 1’Institut Francais du Petrole, 32, pp. 23–42. Espitalie J. Laporte J.L. Madec M. Marquis F. Leplat P. Paulet J. Boutefeu A . ( 1977 ): Rapid method of characterizing source rocks and their petroleum potential and degree of maturity . Revue de 1’Institut Francais du Petrole , 32 , pp. 23 42 . Search in Google Scholar

Barker, C.E., Johnson, R.C., Poole, F. (1990): RockEval pyrolysis data for petroleum-potential evaluation based on veil cuttings and core samples from Eastern Nevada collected during 1990. Open-File Report 90-698, pp. 1–15. Barker C.E. Johnson R.C. Poole F . ( 1990 ): RockEval pyrolysis data for petroleum-potential evaluation based on veil cuttings and core samples from Eastern Nevada collected during 1990 . Open-File Report 90-698 , pp. 1 15 . Search in Google Scholar

Stanley, R.G., Valin, Z.C., Pawlewicz, M.J. (1992): Rock-Eval pyrolysis and vitrinite reflectance results from outcrop samples of the Rincon Shale (lower Miocene) collected at the Tajiguas Landfill, Santa Barbara County, California. Open-File Report 92-571. United States Geological Survey, 27 p. Stanley R.G. Valin Z.C. Pawlewicz M.J. ( 1992 ): Rock-Eval pyrolysis and vitrinite reflectance results from outcrop samples of the Rincon Shale (lower Miocene) collected at the Tajiguas Landfill, Santa Barbara County, California . Open-File Report 92-571. United States Geological Survey , 27 p. Search in Google Scholar

Lafargue, E., Espitalié, J., Marquis, F., Pillot, D., Français, I., Préau, A.D.B. (1998): Rock-Eval 6 Applications in Hydrocarbon Exploration, Production and in Soil Contamination Studies. Revue de l’Institut Français Du Pétrole, 53(4), pp. 421–437. Lafargue E. Espitalié J. Marquis F. Pillot D. Français I Préau A.D.B . ( 1998 ): Rock-Eval 6 Applications in Hydrocarbon Exploration, Production and in Soil Contamination Studies . Revue de l’Institut Français Du Pétrole , 53 ( 4 ), pp. 421 437 . Search in Google Scholar

Cooke, I.L. (2014): User Guide Total Organic Carbon (TOC) data. Open Report, OR/14/056. British Geological Survey, Natural Environment Research Council (NERC). 14 p. Cooke I.L. ( 2014 ): User Guide Total Organic Carbon (TOC) data. Open Report, OR/14/056 . British Geological Survey , Natural Environment Research Council (NERC) . 14 p. Search in Google Scholar

Van Krevelen, D.W. (1984): Organic geochemistry-old and new. Organic Geochemistry, 6, pp. 1–10. Van Krevelen D.W. ( 1984 ): Organic geochemistry-old and new . Organic Geochemistry , 6 , pp. 1 10 . Search in Google Scholar

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