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Self-Plasticization of PVC via click reaction of a monooctyl phthalate derivative

Puyou Jia

Puyou Jia

Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, State Forestry Administration; and Key Lab of Biomass Energy and MaterialsNanjing, China
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Jia, Puyou
, 
Rui Wang

Rui Wang

Nanjing Forestry University, College of Materials Science and EngineeringNanjing, China
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Wang, Rui
, 
Lihong Hu

Lihong Hu

  • Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, State Forestry Administration; and Key Lab of Biomass Energy and MaterialsNanjing, China
  • Chinese Academy of Forest (CAF), Institute of New Technology of ForestryBeijing, China
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Hu, Lihong
, 
Meng Zhang

Meng Zhang

  • Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, State Forestry Administration; and Key Lab of Biomass Energy and MaterialsNanjing, China
  • Chinese Academy of Forest (CAF), Institute of New Technology of ForestryBeijing, China
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Zhang, Meng
 oraz 
Yonghong Zhou

Yonghong Zhou

Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, State Forestry Administration; and Key Lab of Biomass Energy and MaterialsNanjing, China
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Zhou, Yonghong
  
10 paź 2017
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Data publikacji: 10 paź 2017
Zakres stron: 16 - 19
DOI: https://doi.org/10.1515/pjct-2017-0042
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© 2017 Puyou Jia et al., published by De Gruyter Open
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Modified PVC (M-PVC) material with suppressed migration and low glass transition temperature was prepared via click reaction of a monooctyl phthalate derivative. Chemical structure and composition of M-PVC were characterized by FT-IR, 1H NMR and element analysis. Thermal stability, glass transition temperature and migration stability of M-PVC were studied with TGA, DSC and migration tests, respectively. The study showed that M-PVC exhibited poor thermal stability, and low glass transition temperature of 66.0°C. No migration was found in distilled water, 10% (v/v) ethanol, 30% (w/v)acetic acid and petroleum ether. The PVC material is expected to preparing PVC products in the areas with high migration resistance requirement.

Język:
Angielski
Częstotliwość wydawania:
4 razy w roku
Dziedziny czasopisma:
Chemia przemysłowa, Biotechnologia, Inżynieria chemiczna, Inżynieria procesowa
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