<abstract xmlns="http://www.w3.org/1999/xhtml"> X-ray diffraction and Mössbauer spectroscopy techniques were used to study the structure and hyperfine interactions of multiferroic Aurivillius compounds Bim+1Ti3Fem-3O3m+3. Samples were synthesized by two methods, that is, the solid-state sintering at various temperatures and mechanical activation in a high-energy ball mill. The compounds were obtained from a mixture of three polycrystalline powder oxides, that is, TiO2, Fe2O3 and Bi2O3. At room temperature, the Aurivillius compounds are paramagnetic materials with orthorhombic crystal structure. The c lattice parameter of the unit cell depends linearly on the m − number of layers with perovskite-like structure. Based on the Mössbauer studies, it is concluded that the hyperfine interactions parameters do not change with m number.</abstract>

X-ray diffraction and Mössbauer spectroscopy techniques were used to study the structure and hyperfine interactions of multiferroic Aurivillius compounds Bim+1Ti3Fem-3O3m+3. Samples were synthesized by two methods, that is, the solid-state sintering at various temperatures and mechanical activation in a high-energy ball mill. The compounds were obtained from a mixture of three polycrystalline powder oxides, that is, TiO2, Fe2O3 and Bi2O3. At room temperature, the Aurivillius compounds are paramagnetic materials with orthorhombic crystal structure. The c lattice parameter of the unit cell depends linearly on the m − number of layers with perovskite-like structure. Based on the Mössbauer studies, it is concluded that the hyperfine interactions parameters do not change with m number.

A comparative study of hyperfine interactions in Aurivillius compounds prepared by mechanical activation and solid-state sintering

Nukleonika

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X-ray diffraction and Mössbauer spectroscopy techniques were used to study the structure and hyperfine interactions of multiferroic Aurivillius compounds...

A comparative study of hyperfine interactions in Aurivillius compounds prepared by mechanical activation and solid-state sintering

Data publikacji: 09 cze 2017

Zakres stron: 153 - 157

Otrzymano: 04 lip 2016

Przyjęty: 05 paź 2016

DOI: https://doi.org/10.1515/nuka-2017-0023

Słowa kluczowe
Aurivillius compounds, solid-state sintering, mechanical activation, Mössbauer spectroscopy, hyperfine interactions

© by Elżbieta Jartych

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

A comparative study of hyperfine interactions in Aurivillius compounds prepared by mechanical activation and solid-state sintering

Data publikacji: 09 cze 2017

Zakres stron: 153 - 157

Otrzymano: 04 lip 2016

Przyjęty: 05 paź 2016

DOI: https://doi.org/10.1515/nuka-2017-0023

Słowa kluczoweAurivillius compounds, solid-state sintering, mechanical activation, Mössbauer spectroscopy, hyperfine interactions

© by Elżbieta Jartych

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Słowa kluczowe
Aurivillius compounds, solid-state sintering, mechanical activation, Mössbauer spectroscopy, hyperfine interactions