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Contamination of bottom sediments by lead, zinc and cadmium in Rzeszow reservoir

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Figure 1

Location of the bottom sediment measurement sites
Location of the bottom sediment measurement sites

Classification of bottom sediments quality, used by Polish Geological Institute [Bojakowska 2001, Bojakowska Sokołowska 1998]

Heavy metalGeochemical backgroundI noncontaminatedII moderately contaminatedIII highly contaminatedIV very highly contaminated
Pb1530100200> 200
Cd< 0.513.56> 6
Zn732005001000> 1000

Comparison the results with the methods for assessment of sediment contamination

Location date and collectionElementRME*PEL/PECLEL/SELPGIIgeo/classLAW classification
1 VI 2018Pb↓/↓↓/↓I-0.01/0I
Cd↓/↓↑/↓I0.20/III
Zn↓/↓↓/↓I0.01/II-II
2 VI 2018Pb↓/↓↓/↓I0.18/II-II
Cd↓/↓↓/↓I-4.44/0I
Zn↓/↓↓/↓I-0.56/0I
3 VI 2018Pb↓/↓↓/↓I0.08/II
Cd↓/↓↓/↓I-6.42/0I
Zn↓/↓↓/↓I-0.54/0I
4 VI 2018Pb↓/↓↓/↓I-0.73/0I
Cd↓/↓↓/↓I-0.34/0I-II
Zn↓/↓↓/↓I-0.99/0I
5 VI 2018Pb↓/↓↓/↓I-0.77/0I
Cd↓/↓↑/↓I0.08/III
Zn↓/↓↓/↓I-0.45/0I
1 X 2018Pb↓/↓↓/↓I-0.73/0I
Cd↓/↓↑/↓I0.01/III
Zn↓/↓↓/↓I-0.46/0I
2 X 2018Pb↓/↓↓/↓I-0.07/0I
Cd↓/↓↓/↓I-5.00/0I
Zn↓/↓↓/↓I-1.01/0I
3 X 2018Pb↓/↓↓/↓I0.07/II
Cd↓/↓↓/↓I-6.03/0I
Zn↓/↓↓/↓I-0.59/0I
4 X 2018Pb↓/↓↓/↓I-1.37/0I
Cd↓/↓↑/↓I0.00/III
Zn↓/↓↓/↓I-0.07/0I-II
5 X 2018Pb↓/↓↓/↓I-2.92/0I
Cd↓/↓↑/↓I0.30/III
Zn↓/↓↑/↓I0.23/II-II

Contents of heavy metals in samples of bottom sediments presented as mg·kg–1d.m

xPbCdZn
LocationVI 2016X 2016VI 2016X 2016VI 2016X 2016
122.3513.520.860.76110.5579.82
225.4221.380.030.0274.3254.39
323.8123.690.010.0175.5572.64
413.548.720.590.7555.21104.30
513.222.980.800.9280.15128.00
M19.6614.060.460.4979.1587.83
SD5.848.630.410.4419.9828.72
Gb150.573

The limit value of trace elements in sediments (presented as mg·kg–1d.m.) [Macdonald et al. 2000, http://ekoinfonet.gios.gov.pl]

Heavy metalRMEPELPECLELSEL
Pb2009112831250
Cd7.53.54.980.610
Zn1000315459120820

Geoaccumulation indexes for metals [Müller 1981]

Index Value ClassClassDescription quality of sediment
Igeo ≤ 00uncontaminated
0 < Igeo < 11uncontaminated contaminated to moderately
1 < Igeo < 22moderately contaminated
2 < Igeo < 33moderately contaminated to strongly
3 < Igeo < 44strongly contaminated
4 < Igeo < 55strongly contaminated to extremely
5 < Igeo6extremely contaminated

Permissible concentration of heavy metals in bottom sediments by LAW classification [Länderarbeitsgemeinschaft Wasser 1998]

ElementPbCdZnSediment quality
I≤ 25≤ 0.3≤ 100I - Uncontaminated
I-II≤ 50≤ 0.6≤ 200I-Moderately II - Contaminated polluted /
II≤ 100≤ 1.2≤ 400II - Moderately polluted
II-III≤ 200≤ 2.4≤ 800II-III - Moderately polluted / Heavily contaminated
III≤400≤ 4.8≤ 1600III - Heavily polluted
III-IV≤ 800≤ 9.6≤ 3200III-IV heavily - Strongly polluted / Very
IV> 800> 9.6> 3200IV - Very polluted heavily
eISSN:
2353-8589
Lingua:
Inglese
Frequenza di pubblicazione:
4 volte all'anno
Argomenti della rivista:
Life Sciences, Ecology