<abstract xmlns="http://www.w3.org/1999/xhtml">The new iron(II) complex [Fe(<italic>bpta</italic>)2(EtOH)2(NCS)2] (<italic>bpta</italic> = 3,3’-(1,2,4-thiadiazole-3,5-diyl) dipyridine; EtOH = ethanol) has been prepared by refluxing Fe(NCS)3 or Fe(NCS)2 with thionicotinamide in an ethanol solution and characterized by elemental analysis, infrared spectroscopy, thermal decomposition and X-ray structural analysis. The characterized compound is a mixture of three regioisomers resulting from differential coordination by the 3- and 5-position 2-pyridyl groups. The <italic>bpta</italic> ligand was generated <italic>in situ</italic> by the oxidation dimerization of thionicotinamide. X-ray single-crystal diffraction revealed that the crystal structure is centrosymmetric and the complex crystallizes in the triclinic space group <italic>P</italic>-1. The iron(II) atom lies in the centre of symmetry and it is octahedrally coordinated by two nitrogen atoms from two thiocyanate anions and two oxygen atoms from ethanol molecules in the equatorial plane and two nitrogen atoms of pyridine rings from two <italic>bpta</italic> ligands in the axial positions. This complex represents the second example of metal complex with <italic>bpta</italic>.</abstract>

The new iron(II) complex [Fe(bpta)2(EtOH)2(NCS)2] (bpta = 3,3’-(1,2,4-thiadiazole-3,5-diyl) dipyridine; EtOH = ethanol) has been prepared by refluxing Fe(NCS)3 or Fe(NCS)2 with thionicotinamide in an ethanol solution and characterized by elemental analysis, infrared spectroscopy, thermal decomposition and X-ray structural analysis. The characterized compound is a mixture of three regioisomers resulting from differential coordination by the 3- and 5-position 2-pyridyl groups. The bpta ligand was generated in situ by the oxidation dimerization of thionicotinamide. X-ray single-crystal diffraction revealed that the crystal structure is centrosymmetric and the complex crystallizes in the triclinic space group P-1. The iron(II) atom lies in the centre of symmetry and it is octahedrally coordinated by two nitrogen atoms from two thiocyanate anions and two oxygen atoms from ethanol molecules in the equatorial plane and two nitrogen atoms of pyridine rings from two bpta ligands in the axial positions. This complex represents the second example of metal complex with bpta.

Synthesis, structure, thermal decomposition and spectral properties of neutral [Fe(<italic>bpta</italic>)2(etOH)2(NCS)2]

Institute of Inorganic Chemistry, Technology and Materials, Slovak University of Technology, Radlinského 9, SK – 812 37 Bratislava, Slovakia

Faculty of Industrial Technologies in Púchov, University of Alexander Dubček in Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovakia

Acta Chimica Slovaca

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Synthesis, structure, thermal decomposition and spectral properties of neutral [Fe()(etOH)(NCS)]

The new iron(II) complex [Fe(bpta)2(EtOH)2(NCS)2] (bpta = 3,3’-(1,2,4-thiadiazole-3,5-diyl) dipyridine; EtOH = ethanol) has been prepared by refluxing Fe(NCS)3...

Synthesis, structure, thermal decomposition and spectral properties of neutral [Fe(bpta)₂(etOH)₂(NCS)₂]

Pubblicato online: 15 giu 2015

Pagine: 78 - 85

DOI: https://doi.org/10.1515/acs-2015-0014

Parole chiave
3,3′-(1,2,4-Thiadiazole-3,5-diyl)dipyridine, Thiocyanate complex, Iron(II) complex, Crystal structure

© Zuzana Lukačovičová et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Synthesis, structure, thermal decomposition and spectral properties of neutral [Fe(bpta)2(etOH)2(NCS)2]

Pubblicato online: 15 giu 2015

Pagine: 78 - 85

DOI: https://doi.org/10.1515/acs-2015-0014

Parole chiave3,3′-(1,2,4-Thiadiazole-3,5-diyl)dipyridine, Thiocyanate complex, Iron(II) complex, Crystal structure

© Zuzana Lukačovičová et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Synthesis, structure, thermal decomposition and spectral properties of neutral [Fe(bpta)₂(etOH)₂(NCS)₂]

Parole chiave
3,3′-(1,2,4-Thiadiazole-3,5-diyl)dipyridine, Thiocyanate complex, Iron(II) complex, Crystal structure