Volume 50 (2019): Issue 1-4 (December 2019)

One of the most effective methods for the immobilization of toxic metals involves the use of minerals from the apatite supergroup. The formation of cadmium chlorapatite may lead to successful entrapping of cadmium; thus, it is important to examine the solubility constant to determine the stability of cadmium in the the apatite structure. Cadmium chlorapatite was synthetized and characterized by X-ray diffraction, infrared spectroscopy, Raman spectroscopy, and scanning electron microscopy. The solubility constant (log) K_sp of cadmium chlorapatite was -65.58. The Gibbs free energy of formation of cadmium chlorapatite reached -3950.48 kJ mol⁻¹. The solubility constant turned out to be low but was enough for cadmium chlorapatiteto be considered a very stable compound..

Twenty-four areas with lamprophyric formations have been located through a bibliographic search in Macedonia, Thrace, the islands and Attica. Most lamprophyre types have been identified including rare “alkali minette”. In most localities the dikes/sills appear to be late mantle products associated with deep faulting following extensional activity in granitoids.

The Bahram-Gur area in the southeastern part of the Sanandaj – Sirjan metamorphic zone, contains metabasites and metasediments. The metasedimentary rocks are mainly garnet schists and garnet-staurolite schists that were metamorphosed under amphibolite facies conditions. The rocks consist of garnet ± staurolite, biotite, muscovite, chlorite and quartz. The geochemistry of the Bahram-Gur metasediments classifies them as quartziferous sedimentary rocks. The protoliths of the metasedimentary rocks were close to greywackes from an ensialic arc basin depositional setting, with a source comprising mostly mixture of acid and intermediate magmatic rocks in the upper continental crust. The metamorphic conditions of formation of the Bahram-Gur metasedimentary are investigated by geothermobarometric methods. The results show that the metasedimentary rocks formed at temperatures of 600-750°C and pressures of 5-7.5 kbar.