<abstract xmlns="http://www.w3.org/1999/xhtml">

<p>A polyester plasticizer (RSOP) for polyvinyl chloride based on rubber seed oil (RSO) was synthesized. Firstly, RSO monoglyceride were synthesized by the transesterification of RSO with glycerol at 220–240 °C. Secondly, RSOP was synthesized from RSO monoglyceride and adipic acid by esterification. The polyester plasticizer was characterized by GPC, FT-IR, <sup>1</sup>H NMR and DSC. Plasticized polyvinyl chloride (PVC) materials with RSOP and dioctyl phthalate (DOP) in varying ratios were prepared via thermal melting process, RSOP was used as a second plasticizer. The properties of the plasticized PVC materials were characterized by a universal testing machine, TGA, DMA and solvent extraction resistance. The obtained PVC materials showed improved thermal stability and lower glass transition temperature than PVC. Solvent extraction resistance and plasticization of plasticized PVC were also improved. This study provides a new strategy for preparing bio-based polyester plasticizer from RSO.</p>
</abstract>

A polyester plasticizer (RSOP) for polyvinyl chloride based on rubber seed oil (RSO) was synthesized. Firstly, RSO monoglyceride were synthesized by the transesterification of RSO with glycerol at 220–240 °C. Secondly, RSOP was synthesized from RSO monoglyceride and adipic acid by esterification. The polyester plasticizer was characterized by GPC, FT-IR, 1H NMR and DSC. Plasticized polyvinyl chloride (PVC) materials with RSOP and dioctyl phthalate (DOP) in varying ratios were prepared via thermal melting process, RSOP was used as a second plasticizer. The properties of the plasticized PVC materials were characterized by a universal testing machine, TGA, DMA and solvent extraction resistance. The obtained PVC materials showed improved thermal stability and lower glass transition temperature than PVC. Solvent extraction resistance and plasticization of plasticized PVC were also improved. This study provides a new strategy for preparing bio-based polyester plasticizer from RSO.

Synthesis of a polyester plasticizer from rubber seed oil for polyvinyl chloride

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution 4.0 International License.

{"article-title":"Synthesis of a polyester plasticizer from rubber seed oil for polyvinyl chloride"}

A polyester plasticizer (RSOP) for polyvinyl chloride based on rubber seed oil (RSO) was synthesized. Firstly, RSO monoglyceride were synthesized by the...

Synthesis of a polyester plasticizer from rubber seed oil for polyvinyl chloride

Online veröffentlicht: 26. Dez. 2022

Seitenbereich: 1 - 6

DOI: https://doi.org/10.2478/pjct-2022-0023

Schlüsselwörter
Rubber seed oil, polyester, polyvinyl chloride, plasticizer, leaching test

© 2022 Huabei Li et al., published by Sciendo

This work is licensed under the Creative Commons Attribution 4.0 International License.

Synthesis of a polyester plasticizer from rubber seed oil for polyvinyl chloride

Online veröffentlicht: 26. Dez. 2022

Seitenbereich: 1 - 6

DOI: https://doi.org/10.2478/pjct-2022-0023

SchlüsselwörterRubber seed oil, polyester, polyvinyl chloride, plasticizer, leaching test

© 2022 Huabei Li et al., published by Sciendo

This work is licensed under the Creative Commons Attribution 4.0 International License.

Schlüsselwörter
Rubber seed oil, polyester, polyvinyl chloride, plasticizer, leaching test