<abstract xmlns="http://www.w3.org/1999/xhtml"><p> Batch time requirements are provided for the separation of binary zeotropic mixtures in two different multivessel columns (with and without vapor bypass), a non-cyclic two-vessel column and a regular batch column based on dynamic simulations. The first three columns are operated as closed (total reflux) systems and the regular batch column is operated as an open (partial reflux) system. We analyze the effects of feed composition, relative volatility and product specification on the time requirements. The multivessel arrangements perform better than the regular batch column, which requires from 4.00 to 34.67% more time to complete a given separation. The elimination of the vapor bypass in the multivessel column is impractical though it has a positive effect on the batch time requirements. Thus, the multivessel column, with the vapor stream bypassing the intermediate vessel, is proposed as the best candidate for a binary zeotropic mixture with low concentration of light component, low relative volatility and high product purity demand. Furthermore, an experimental multivessel column with vapor bypass is built and the corresponding experiments verify the simulations.</p></abstract>

Batch time requirements are provided for the separation of binary zeotropic mixtures in two different multivessel columns (with and without vapor bypass), a non-cyclic two-vessel column and a regular batch column based on dynamic simulations. The first three columns are operated as closed (total reflux) systems and the regular batch column is operated as an open (partial reflux) system. We analyze the effects of feed composition, relative volatility and product specification on the time requirements. The multivessel arrangements perform better than the regular batch column, which requires from 4.00 to 34.67% more time to complete a given separation. The elimination of the vapor bypass in the multivessel column is impractical though it has a positive effect on the batch time requirements. Thus, the multivessel column, with the vapor stream bypassing the intermediate vessel, is proposed as the best candidate for a binary zeotropic mixture with low concentration of light component, low relative volatility and high product purity demand. Furthermore, an experimental multivessel column with vapor bypass is built and the corresponding experiments verify the simulations.

Time requirements in closed and open batch distillation arrangements for separation of a binary mixture

Tianjin University, School of Chemical Engineering and Technology, Tianjin 300072, P.R. China

Tianjin University, Key Laboratory of Systems Bioengineering, Ministry of Education, Tianjin 300072, P.R. China

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Batch time requirements are provided for the separation of binary zeotropic mixtures in two different multivessel columns (with and without vapor bypass), a...

Time requirements in closed and open batch distillation arrangements for separation of a binary mixture

Online veröffentlicht: 11. Dez. 2014

Seitenbereich: 66 - 74

DOI: https://doi.org/10.2478/pjct-2014-0072

© by Shuo Zhao

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.