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<p>Tartaric acid is generally not an effective soil washing solution, hence this study focuses on enhancing its usage for soil-Pb decontamination. Three tropical soil types (sandy, clay and loamy) with different lead concentrations were subjected to single batch washing using 0.01, 0.1, 0.5 and 1 M tartaric acid with 5% and 10% KCl modification at 3% soil-pulp-density for 2, 6, 12 and 24 h washing time. The optimum washing conditions were 1 M tartaric acid at 24 h washing time, with Pb removal efficiency: sandy- 94.3%, clay-67.6% and loamy-36.8%. Modification of tartaric acid with 5% and 10% KCl brought about some degree of enhancement of Pb removal efficiency especially for clay and loamy soils. Removal efficiency for 5% KCl modification were: sandy-97.9%, clay-96.2% with 1 M tartaric acid at 24 h washing time, loamy-76.7% for 0.5 M tartaric acid. Similarly, 10% KCl modification were: sandy-96.7%, clay-97.2% for 1 M tartaric acid at 24 h, loamy-82.1% for 0.5 M tartaric acid. Removal efficiency was soil concentration dependent. Generally, removal efficiency increased with increasing tartaric acid concentrations and washing time. Tartaric acid washing is promising and recommended in events of moderate contamination and 10% KCl modification in event of high level contamination. Further study is needed on enhancing very low concentrations of tartaric acid for large scale applications.</p>
</abstract>

Tartaric acid is generally not an effective soil washing solution, hence this study focuses on enhancing its usage for soil-Pb decontamination. Three tropical soil types (sandy, clay and loamy) with different lead concentrations were subjected to single batch washing using 0.01, 0.1, 0.5 and 1 M tartaric acid with 5% and 10% KCl modification at 3% soil-pulp-density for 2, 6, 12 and 24 h washing time. The optimum washing conditions were 1 M tartaric acid at 24 h washing time, with Pb removal efficiency: sandy- 94.3%, clay-67.6% and loamy-36.8%. Modification of tartaric acid with 5% and 10% KCl brought about some degree of enhancement of Pb removal efficiency especially for clay and loamy soils. Removal efficiency for 5% KCl modification were: sandy-97.9%, clay-96.2% with 1 M tartaric acid at 24 h washing time, loamy-76.7% for 0.5 M tartaric acid. Similarly, 10% KCl modification were: sandy-96.7%, clay-97.2% for 1 M tartaric acid at 24 h, loamy-82.1% for 0.5 M tartaric acid. Removal efficiency was soil concentration dependent. Generally, removal efficiency increased with increasing tartaric acid concentrations and washing time. Tartaric acid washing is promising and recommended in events of moderate contamination and 10% KCl modification in event of high level contamination. Further study is needed on enhancing very low concentrations of tartaric acid for large scale applications.

Enhancement of tartaric acid modified washing solutions for lead decontamination of tropical soils

Ovidius University Annals of Chemistry

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Tartaric acid is generally not an effective soil washing solution, hence this study focuses on enhancing its usage for soil-Pb decontamination. Three tropical...

Enhancement of tartaric acid modified washing solutions for lead decontamination of tropical soils

Online veröffentlicht: 04. Mai 2020

Seitenbereich: 27 - 32

Eingereicht: 04. März 2020

Akzeptiert: 11. Apr. 2020

DOI: https://doi.org/10.2478/auoc-2020-0006

Schlüsselwörter
soil remediation, lead, tartaric acid, soil contamination

© 2020 Effiong Ukorebi Etim, published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Enhancement of tartaric acid modified washing solutions for lead decontamination of tropical soils

Online veröffentlicht: 04. Mai 2020

Seitenbereich: 27 - 32

Eingereicht: 04. März 2020

Akzeptiert: 11. Apr. 2020

DOI: https://doi.org/10.2478/auoc-2020-0006

Schlüsselwörtersoil remediation, lead, tartaric acid, soil contamination

© 2020 Effiong Ukorebi Etim, published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Schlüsselwörter
soil remediation, lead, tartaric acid, soil contamination