<abstract xmlns="http://www.w3.org/1999/xhtml"> In this work the compositional dependence of hyperfine interactions and magnetoelectric coupling in (BiFeO3)x-(BaTiO3)1-x solid solutions where x = 0.5-0.9 fabricated from commercial BaTiO3 in terms of the solid-state sintering method at various temperatures and over different time periods is described. In general, as the content of BaTiO3 increases, a decrease in the hyperfine magnetic field (Bhf) at 57Fe nuclei was observed. However, for samples exhibiting lower homogeneity in which the ions of Bi3+ and Fe3+ are replaced by Ba2+ and Ti4+ with lower probability, higher values of Bhf are obtained. For the sample where x = 0.6 that exhibits the coexistence of rhombohedral, regular and tetragonal phases, the highest value of the αME coefficient (3.57 mV/A) was observed, which is more than three times higher when compared to the hitherto published results. </abstract>

In this work the compositional dependence of hyperfine interactions and magnetoelectric coupling in (BiFeO3)x-(BaTiO3)1-x solid solutions where x = 0.5-0.9 fabricated from commercial BaTiO3 in terms of the solid-state sintering method at various temperatures and over different time periods is described. In general, as the content of BaTiO3 increases, a decrease in the hyperfine magnetic field (Bhf) at 57Fe nuclei was observed. However, for samples exhibiting lower homogeneity in which the ions of Bi3+ and Fe3+ are replaced by Ba2+ and Ti4+ with lower probability, higher values of Bhf are obtained. For the sample where x = 0.6 that exhibits the coexistence of rhombohedral, regular and tetragonal phases, the highest value of the αME coefficient (3.57 mV/A) was observed, which is more than three times higher when compared to the hitherto published results.

Compositional dependence of hyperfine interactions and magnetoelectric coupling in (BiFeO3)x-(BaTiO3)1–x solid solutions

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Compositional dependence of hyperfine interactions and magnetoelectric coupling in (BiFeO)-(BaTiO) solid solutions

In this work the compositional dependence of hyperfine interactions and magnetoelectric coupling in (BiFeO3)x-(BaTiO3)1-x solid solutions where x = 0.5-0.9...

Compositional dependence of hyperfine interactions and magnetoelectric coupling in (BiFeO₃)_x-(BaTiO₃)_1–x solid solutions

Online veröffentlicht: 09. Juni 2017

Seitenbereich: 117 - 122

Eingereicht: 31. Juli 2016

Akzeptiert: 08. Okt. 2016

DOI: https://doi.org/10.1515/nuka-2017-0016

Schlüsselwörter
hyperfine interactions, magnetoelectric coupling, Mössbauer spectroscopy

© by Karol Kowal

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Compositional dependence of hyperfine interactions and magnetoelectric coupling in (BiFeO3)x-(BaTiO3)1–x solid solutions

Online veröffentlicht: 09. Juni 2017

Seitenbereich: 117 - 122

Eingereicht: 31. Juli 2016

Akzeptiert: 08. Okt. 2016

DOI: https://doi.org/10.1515/nuka-2017-0016

Schlüsselwörterhyperfine interactions, magnetoelectric coupling, Mössbauer spectroscopy

© by Karol Kowal

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Compositional dependence of hyperfine interactions and magnetoelectric coupling in (BiFeO₃)_x-(BaTiO₃)_1–x solid solutions

Schlüsselwörter
hyperfine interactions, magnetoelectric coupling, Mössbauer spectroscopy