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<p>Nanoscale zero-valent iron-doped carbonized zeolitic imidazolate framework-8 (nZVI/CZIF-8) was prepared by carbonation of ferric nitrate and ZIF-8 at 800 °C and used as an adsorbent to remove methylene blue (MB) from water. The synthesized nZVI/CZIF-8 has a specific surface area of 806.9 m2/g, a pore volume of 0.86 cm<sup>3</sup>/g and an nZVI content of 1.35%, respectively. Both the nZVI/CZIF-8 and CZIF-8 have identical functional groups of O-H, C-H and C=C. With the increase of CZIF-8 size, MB removal rate increased. The doping of nZVI increased the MB removal percentage from 74.5% for ZIF-8 to 96.2% within 80 min for nZVI/CZIF-8. The MB removal percentage increased with the dosage of nZVI/CZIF-8. The MB adsorption with the adsorbents conforms to the Freundlich adsorption isothermal model and the removal rate fitted well to a pseudo-first-order model. The results demonstrate the feasibility of synthesizing high active and stable nZVI/CZIF-8 particles.</p>
</abstract>

Nanoscale zero-valent iron-doped carbonized zeolitic imidazolate framework-8 (nZVI/CZIF-8) was prepared by carbonation of ferric nitrate and ZIF-8 at 800 °C and used as an adsorbent to remove methylene blue (MB) from water. The synthesized nZVI/CZIF-8 has a specific surface area of 806.9 m2/g, a pore volume of 0.86 cm3/g and an nZVI content of 1.35%, respectively. Both the nZVI/CZIF-8 and CZIF-8 have identical functional groups of O-H, C-H and C=C. With the increase of CZIF-8 size, MB removal rate increased. The doping of nZVI increased the MB removal percentage from 74.5% for ZIF-8 to 96.2% within 80 min for nZVI/CZIF-8. The MB removal percentage increased with the dosage of nZVI/CZIF-8. The MB adsorption with the adsorbents conforms to the Freundlich adsorption isothermal model and the removal rate fitted well to a pseudo-first-order model. The results demonstrate the feasibility of synthesizing high active and stable nZVI/CZIF-8 particles.

Synthesis of nanoscale zero-valent iron doped carbonized zeolitic imidazolate framework-8 for methylene blue removal in water

School of Energy and Materials, Shanghai Polytechnic University, Shanghai Engineering Research Center of Advanced Thermal Functional Materials

Shanghai Key Laboratory of Engineering Materials Application and Evaluation

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution 4.0 International License.

Nanoscale zero-valent iron-doped carbonized zeolitic imidazolate framework-8 (nZVI/CZIF-8) was prepared by carbonation of ferric nitrate and ZIF-8 at 800 °C...

Synthesis of nanoscale zero-valent iron doped carbonized zeolitic imidazolate framework-8 for methylene blue removal in water

Published Online: Mar 29, 2023

Page range: 12 - 19

DOI: https://doi.org/10.2478/pjct-2023-0003

Keywords
Nanoscale zero-valent iron, Carbonized zeolitic imidazolate framework-8, Mesoporous carbon, Methylene blue

© 2023 Shuai Chen et al., published by Sciendo

This work is licensed under the Creative Commons Attribution 4.0 International License.

Synthesis of nanoscale zero-valent iron doped carbonized zeolitic imidazolate framework-8 for methylene blue removal in water

Published Online: Mar 29, 2023

Page range: 12 - 19

DOI: https://doi.org/10.2478/pjct-2023-0003

KeywordsNanoscale zero-valent iron, Carbonized zeolitic imidazolate framework-8, Mesoporous carbon, Methylene blue

© 2023 Shuai Chen et al., published by Sciendo

This work is licensed under the Creative Commons Attribution 4.0 International License.

Keywords
Nanoscale zero-valent iron, Carbonized zeolitic imidazolate framework-8, Mesoporous carbon, Methylene blue