<abstract xmlns="http://www.w3.org/1999/xhtml">This article discusses the growth and characterization of (((4-sulfonatophenyl) ammonio)oxy) zirconium (SAOZ) single crystals. Sulphanilic acid incorporated zirconium oxychloride semi-organic single crystals have been synthesized by slow evaporation technique. From the X-ray studies, lattice parameters a = 7.31 Å, b = 7.51 Å, c = 13.92 Å, volume = 765 Å3 have been found and so the crystal has been identified as orthorhombic with non-centrosymmetric space group P212121. The powder XRD examination demonstrated the quality and high crystalline nature of the grown crystal. The presence of functional groups was confirmed by FT-IR technique. The chemical structure of the compound was established by 1H and 13C NMR spectra. The optical transmittance window and the low cutoff wavelength of SAOZ have been identified by UV-Vis-NIR studies. Photoluminescence studies showed a wide blue light emission. TG and DTA examinations were carried out to characterize the thermal behavior of the grown crystal. The mechanical strength of the grown crystal was analyzed by the Vickers microhardness test. The elemental analysis was done by EDAX. The dielectric response of the crystals was analyzed in the frequency range of 50 Hz to 5 MHz at various temperatures and the outcomes were discussed. The SHG efficiency was estimated in correlation with KDP by employing powder Kurtz method.</abstract>

This article discusses the growth and characterization of (((4-sulfonatophenyl) ammonio)oxy) zirconium (SAOZ) single crystals. Sulphanilic acid incorporated zirconium oxychloride semi-organic single crystals have been synthesized by slow evaporation technique. From the X-ray studies, lattice parameters a = 7.31 Å, b = 7.51 Å, c = 13.92 Å, volume = 765 Å3 have been found and so the crystal has been identified as orthorhombic with non-centrosymmetric space group P212121. The powder XRD examination demonstrated the quality and high crystalline nature of the grown crystal. The presence of functional groups was confirmed by FT-IR technique. The chemical structure of the compound was established by 1H and 13C NMR spectra. The optical transmittance window and the low cutoff wavelength of SAOZ have been identified by UV-Vis-NIR studies. Photoluminescence studies showed a wide blue light emission. TG and DTA examinations were carried out to characterize the thermal behavior of the grown crystal. The mechanical strength of the grown crystal was analyzed by the Vickers microhardness test. The elemental analysis was done by EDAX. The dielectric response of the crystals was analyzed in the frequency range of 50 Hz to 5 MHz at various temperatures and the outcomes were discussed. The SHG efficiency was estimated in correlation with KDP by employing powder Kurtz method.

Semi-organic nonlinear optical material: (((4-sulfonatophenyl)ammonio)oxy)zirconium for dielectric and photonics applications

Post Graduate and Research Department of Physics, Government Arts College

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

This article discusses the growth and characterization of (((4-sulfonatophenyl) ammonio)oxy) zirconium (SAOZ) single crystals. Sulphanilic acid incorporated...

Semi-organic nonlinear optical material: (((4-sulfonatophenyl)ammonio)oxy)zirconium for dielectric and photonics applications

Published Online: Dec 12, 2020

Page range: 434 - 442

Received: Jun 10, 2018

Accepted: Apr 23, 2019

DOI: https://doi.org/10.2478/msp-2020-0055

Keywords
slow evaporation, SHG efficiency, soft material, dielectric, nonlinear optical

© 2020 E. Vinoth et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Semi-organic nonlinear optical material: (((4-sulfonatophenyl)ammonio)oxy)zirconium for dielectric and photonics applications

Published Online: Dec 12, 2020

Page range: 434 - 442

Received: Jun 10, 2018

Accepted: Apr 23, 2019

DOI: https://doi.org/10.2478/msp-2020-0055

Keywordsslow evaporation, SHG efficiency, soft material, dielectric, nonlinear optical

© 2020 E. Vinoth et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Keywords
slow evaporation, SHG efficiency, soft material, dielectric, nonlinear optical