1. bookVolume 37 (2019): Issue 3 (September 2019)
Journal Details
License
Format
Journal
eISSN
2083-134X
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
access type Open Access

Growth, electrical, thermal, mechanical and etching studies on 4-chloroanilinium hydrogen (2R, 3R)-tartrate monohydrate-an organic NLO single crystal

Published Online: 18 Oct 2019
Volume & Issue: Volume 37 (2019) - Issue 3 (September 2019)
Page range: 310 - 316
Received: 18 Jun 2016
Accepted: 23 Apr 2019
Journal Details
License
Format
Journal
eISSN
2083-134X
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
Abstract

An organic single crystal of 4-chloroanilinium hydrogen (2R,3R)-tartrate monohydrate (4CAHT) was grown by slow evaporation solution growth technique at room temperature. Single crystal XRD study confirmed that the crystal belongs to monoclinic system with the space group P21. Powder XRD analysis confirmed the crystalline nature of the compound. The presence of various functional groups in the compound was revealed by FT-IR analysis. UV studies showed the absence of absorption in the entire visible region. To determine the thermal stability of the grown crystals it was subjected to thermogravimetric and differential thermal analyses. Microhardness and etching studies were also carried out for the crystal. The powder second harmonic generation efficiency of 4CAHT was tested by Kurtz and Perry powder technique and the relative SHG efficiency of 4CAHT was found to be 1.44 times greater than that of standard KDP.

Keywords

[1] Sornamurthya B.M., Peramaiyan G., Rekha P., Arunkumar A., Mohan Kumar R., Manivannan V., Optik, 125 (2014), 5695.10.1016/j.ijleo.2014.06.091Search in Google Scholar

[2] Bincy I.P., Gopalakrishnan R., J. Cryst. Growth, 402 (2014), 22.10.1016/j.jcrysgro.2014.03.024Search in Google Scholar

[3] Pandi P., Peramaiyan G., Krishna Kumar M., Mohan Kumar R., Jayavel R., Spectrochim. Acta A, 88 (2012), 77.10.1016/j.saa.2011.11.060Search in Google Scholar

[4] Sudharsana N., Subramanian G., Krishnakumar V., Nagalakshmi R., Spectrochim. Acta A, 97 (2012), 798.10.1016/j.saa.2012.07.048Search in Google Scholar

[5] Kannan V., Thirupugalmani K., Brahadeeswaran S., J. Mol. Struct., 1049 (2013), 268.10.1016/j.molstruc.2013.06.055Search in Google Scholar

[6] Babu B., Chandrasekaran J., Balaprabhakaran S., Optik, 125 (2014), 3005.10.1016/j.ijleo.2013.12.030Search in Google Scholar

[7] Chandrasekaran J., Balaprabhakaran S., Babu B., Optik, 124 (2013), 4296.10.1016/j.ijleo.2013.01.041Search in Google Scholar

[8] Meena K., Muthu K., Meenatchi V., Rajasekar M., Bhagavannarayana G., Meenakshisundaram S.P., Spectrochim. Acta A, 124 (2014), 663.10.1016/j.saa.2014.01.072Search in Google Scholar

[9] Moovendaran K., Bikshandarkoil R. Srinivasan, Kalyana Sundar J., Martin Britto Dhas S.A., Natarajan S., Spectrochim. Acta A, 92 (2012), 388.10.1016/j.saa.2012.02.089Search in Google Scholar

[10] Mohana Priyadarshini K., Chandramohan A., Anandha Babu G., Ramasamy P., Solid State Sci., 28 (2014), 95.10.1016/j.solidstatesciences.2013.12.010Search in Google Scholar

[11] Peramaiyan G., Pandi P., Sornamurthy B.M., Bhagavannarayana G., Mohan Kumar R., Spectrochim. Acta A, 95 (2012), 310.10.1016/j.saa.2012.03.082Search in Google Scholar

[12] Joseph Daniel D., Ramasamy P., Mater. Res. Bull., 47 (2012), 708.10.1016/j.materresbull.2011.12.009Search in Google Scholar

[13] Smith G., Wermuth U.D., White J.M., Acta Cryst. Sec. E, 63 (2007), o3432.10.1107/S1600536807032473Search in Google Scholar

[14] Balaprabhakaran S., Chandrasekaran J., Babu B., Thirumurugan R., Anitha K., Spectrochim. Acta A, 136 (2015), 700.10.1016/j.saa.2014.09.084Search in Google Scholar

[15] Bhagavannarayana G., Riscob B., Mohd. Shakir, Mater. Chem. Phys., 126 (2011), 20.10.1016/j.matchemphys.2010.12.040Search in Google Scholar

[16] Senthil Pandian M., Balamurugan N., Ganesh V., Raja Shekar P.V., Krishan Rao K., Ramasamy P., Mater. Lett., 62 (2008), 3830.10.1016/j.matlet.2008.04.078Search in Google Scholar

[17] Senthil Pandian M., Pattanaboonmee N., Ramasamy P., Manyum P., J. Cryst. Growth, 314 (2011), 207.10.1016/j.jcrysgro.2010.11.093Search in Google Scholar

[18] Kurtz S.K., Perry T.T., J. Appl. Phys., 39 (1968), 3798.10.1063/1.1656857Search in Google Scholar

[19] Peramaiyan G., Pandi P., Sornamurthy B.M., Bhagavannarayana G., Mohan Kumar R., Spectrochim. Acta Part A, 95 (2012), 310.10.1016/j.saa.2012.03.082Search in Google Scholar

[20] Vivek P., Murugakoothan P., Optik, 124 (2013), 3510.10.1016/j.ijleo.2012.12.004Search in Google Scholar

[21] Babu B., Chandrasekaran J., Balaprabhakaran S., Mater. Sci.-Poland, 32 (2014), 164.10.2478/s13536-013-0176-7Search in Google Scholar

[22] Prakash M., Lydia Caroline M., Geetha D., Spectrochim. Acta Part A, 108 (2013), 32.10.1016/j.saa.2013.01.078Search in Google Scholar

Recommended articles from Trend MD

Plan your remote conference with Sciendo