1. bookVolume 7 (2014): Issue 2 (October 2014)
Journal Details
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Journal
eISSN
1339-3065
First Published
10 Dec 2012
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2 times per year
Languages
English
Open Access

Methyl- and methoxysalicylatocopper(II) complexes with 2-aminomethylpyridine

Published Online: 20 Dec 2014
Volume & Issue: Volume 7 (2014) - Issue 2 (October 2014)
Page range: 94 - 98
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
Abstract

As a part of our systematic study of copper(II) complexes in presence of biologically active ligands, we concluded to realize experiments with methyl- or methoxysalicylatocopper(II) complexes in presence of 2-aminomethylpyridine (ampy) ligand. This has resulted in four new complexes of the formula Cu(XSal)2(ampy) (where XSal are 3-MeSal = 3-methylsalicylate, 4-MeSal = 4-methylsalicylate, 5-MeSal = 5-methylsalicylate, or 4-MeOSal = 4-methoxylsalicylate anions). The synthesis, elemental analysis and spectral properties (EPR, electronic and infrared) are reported. The Cu(II) atom in all four complexes is probably coordinated by two nitrogen atom of the bidentate chelating ampy as well as monodentate and/or highly asymmetrically chelating salicylate anions. Based on the analyses it was concluded that the structure of these new compounds could be similar to [Cu(HCOO)2(ampy)], or [Cu(CH3COO)2(ampy)] that are reported in the literature.

Keywords

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