1. bookVolume 7 (2014): Issue 1 (April 2014)
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Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
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2 times per year
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English
access type Open Access

On the structure of [Al(DMSO2)3]3+

Published Online: 27 May 2014
Volume & Issue: Volume 7 (2014) - Issue 1 (April 2014)
Page range: 9 - 14
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
Abstract

The most stable [Al(DMSO2)3]3+ complex cation in dimethyl sulfone (DMSO2, (CH3)2SO2) has D3 symmetry with twofold axes in Al-S lines coincident with the twofold rotation axes of mutually turned DMSO2 ligands by ca 60°. The central Al atom is hexacoordinated by six O atoms with nearly octahedral coordination. More than one electron is transferred to the Al central atom from DMSO2 ligands. Weaker and longer S-O, stronger and shorter S-C bonds, lower O-S-O bond angles and greater O-S-C and C-S-C ones in [Al(DMSO2)3]3+ than in free DMSO2 are implied by weak Al-O bonding.

Keywords

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