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Figure 1.

Mixed gas UV spectral absorption curve
Mixed gas UV spectral absorption curve

Figure 2.

Absorption spectra of SO2 and NO2
Absorption spectra of SO2 and NO2

Figure 3.

NO2 and SO2 gas concentration iterative algorithm flow chart
NO2 and SO2 gas concentration iterative algorithm flow chart

Figure 4.

SO2 concentration and the number of iterations curve
SO2 concentration and the number of iterations curve

Figure 5.

NO2 concentration and the number of iterations curve
NO2 concentration and the number of iterations curve

Figure 6.

Experimental system composition diagram
Experimental system composition diagram

Figure 7.

Four gas photon spectrum line graph
Four gas photon spectrum line graph

Figure 8.

Fitting curve of SO2 at 271.98 nm
Fitting curve of SO2 at 271.98 nm

Figure 9.

Fitting curve of NO at 225.94 nm
Fitting curve of NO at 225.94 nm

Figure 10.

Fitting curve of NO at 271.98 nm
Fitting curve of NO at 271.98 nm

Figure 11.

Fitting curve of NH3 at 271.98 nm
Fitting curve of NH3 at 271.98 nm

200PPM SO2 AND NO GAS SPECTRAL DATA

271.98nm 225.94nm dark noise
zero gas 56434 43973 2900
SO2 100ppm 52851 42754 2900
zero gas 56434 43973 2900
NO2 100ppm 56386 40749 2900

SPECTRAL DATA FOR MIXED GAS

271.98nm 225.94nm dark noise
zero gas 56434 43973 2900
mixed gas 52050 39588 2900

ANALYSIS OF RESULTS

gas species standard value (ppm) measured value (ppm) difference value maximum difference error
SO2 102 104 2 -4 0.8%
200 196 -4
499 501 2
NO 104 108 4 -7 1.4%
200 206 6
500 493 -7
NO2 116 112 -4 -9.7 1.94%
201.5 195 -6.5
501.7 493 -9.7
NH3 50 53 3 3 1.5%
200 199 -1
conclusion Accuracy error is less than 3%, which meets the design standard.

SPECTRAL TABLES FOR SO2 AND NO2 AT WAVELENGTH 273.33NM AND WAVELENGTH 231.33NM

Wavelength 231.33 273.33
NO2 absorbance 0.03003444 0.00456189
SO2 absorbance 0.00482312 0.07984884
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