<abstract xmlns="http://www.w3.org/1999/xhtml"><p>Modified PVC (M-PVC) material with suppressed migration and low glass transition temperature was prepared via click reaction of a monooctyl phthalate derivative. Chemical structure and composition of M-PVC were characterized by FT-IR, 1H NMR and element analysis. Thermal stability, glass transition temperature and migration stability of M-PVC were studied with TGA, DSC and migration tests, respectively. The study showed that M-PVC exhibited poor thermal stability, and low glass transition temperature of 66.0°C. No migration was found in distilled water, 10% (v/v) ethanol, 30% (w/v)acetic acid and petroleum ether. The PVC material is expected to preparing PVC products in the areas with high migration resistance requirement.</p></abstract>

Modified PVC (M-PVC) material with suppressed migration and low glass transition temperature was prepared via click reaction of a monooctyl phthalate derivative. Chemical structure and composition of M-PVC were characterized by FT-IR, 1H NMR and element analysis. Thermal stability, glass transition temperature and migration stability of M-PVC were studied with TGA, DSC and migration tests, respectively. The study showed that M-PVC exhibited poor thermal stability, and low glass transition temperature of 66.0°C. No migration was found in distilled water, 10% (v/v) ethanol, 30% (w/v)acetic acid and petroleum ether. The PVC material is expected to preparing PVC products in the areas with high migration resistance requirement.

Self-Plasticization of PVC via click reaction of a monooctyl phthalate derivative

Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF)

National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, State Forestry Administration; and Key Lab of Biomass Energy and Materials

Chinese Academy of Forest (CAF), Institute of New Technology of Forestry

College of Materials Science and Engineering

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Modified PVC (M-PVC) material with suppressed migration and low glass transition temperature was prepared via click reaction of a monooctyl phthalate...

Self-Plasticization of PVC via click reaction of a monooctyl phthalate derivative

Published Online: Oct 10, 2017

Page range: 16 - 19

DOI: https://doi.org/10.1515/pjct-2017-0042

Keywords
poly(vinyl chloride), plasticization, migration, TGA

© 2017 Puyou Jia et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Self-Plasticization of PVC via click reaction of a monooctyl phthalate derivative

Published Online: Oct 10, 2017

Page range: 16 - 19

DOI: https://doi.org/10.1515/pjct-2017-0042

Keywordspoly(vinyl chloride), plasticization, migration, TGA

© 2017 Puyou Jia et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Keywords
poly(vinyl chloride), plasticization, migration, TGA