Accumulation of metallic elements into the superficial peat layer of mires and wet mineral soils of Estonian forest land / Akumulacja metali w powierzchniowej warstwie gleb torfowych i wilgotnych glebach mineralnych ekosystemów leśnych Estonii

This article studied the extent of accumulation of aqua regia extractable metallic elements (Al, Mg, Pb, Zn, Hg, Cd) into peaty (histic) epipedon (EP) of fen soils, transitional bog soils, peaty gley soils and peaty podzols. The accumulation coefficients (Kac) of the elements in EP were estimated in relation of forest floor (FF, as an input) as a comparison to deeper levels (SS, as a past background). The study revealed that the extent of accumulation and its order depend on soil (peat) type or pedo-ecological conditions of peatification. In the forming of EP from FF, the concentrations of Al and Pb were increased on an average 2.5-5.0 times, but that of Hg increased significantly only in peaty soils (on an average 1.5-1.6 times). The contents of Zn were significantly decreased (Kac 0.1-0.5) in all soil groups. The comparison of EP peats concentrations with SS data demonstrated a considerable accumulation of Pb, Cd, Zn and Hg into thin (~20 cm) superficial peat layer.