<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml">The extraction of palladium(II) from hydrochloric acid solutions of various concentrations in the presence of different amounts of sodium chloride with phosphonium ionic liquid Cyphos®IL101 in toluene was investigated. The extraction of Pd(II) is very effective. The percentage extraction of Pd(II) from 0.1 mol dm- 3 HCl solution amounts to 97% with Cyphos®IL101. Both the increase in HCl concentration and the presence of NaCl have a negative influence on the extraction. The extent of extraction from 0.1 mol dm-3 HCl solution in the presence of 0.5 mol dm-3 NaCl is about 80% and from 3 mol dm-3 HCl is lower and amounts to 56%. The extraction of Pd(II) from aqueous 0.1 mol dm-3 HCl and from 0.1 mol dm-3 HCl in the presence of 0.5 mol dm-3 NaCl with this phosphonium ionic liquid is rapid and the equilibrium is achieved after 1 - 2 minutes. The extraction of Pd(II) from aqueous 3 mol dm-3 HCl is slower and the equilibrium is achieved after 5 - 6 minutes.</abstract>

The extraction of palladium(II) from hydrochloric acid solutions of various concentrations in the presence of different amounts of sodium chloride with phosphonium ionic liquid Cyphos®IL101 in toluene was investigated. The extraction of Pd(II) is very effective. The percentage extraction of Pd(II) from 0.1 mol dm- 3 HCl solution amounts to 97% with Cyphos®IL101. Both the increase in HCl concentration and the presence of NaCl have a negative influence on the extraction. The extent of extraction from 0.1 mol dm-3 HCl solution in the presence of 0.5 mol dm-3 NaCl is about 80% and from 3 mol dm-3 HCl is lower and amounts to 56%. The extraction of Pd(II) from aqueous 0.1 mol dm-3 HCl and from 0.1 mol dm-3 HCl in the presence of 0.5 mol dm-3 NaCl with this phosphonium ionic liquid is rapid and the equilibrium is achieved after 1 - 2 minutes. The extraction of Pd(II) from aqueous 3 mol dm-3 HCl is slower and the equilibrium is achieved after 5 - 6 minutes.

Extraction of Palladium(II) Ions from Chloride Solutions with Phosphonium Ionic Liquid Cyphos®IL101

Institute of Chemical Engineering and Technology, Poznan University of Technology, pl. M. Skłodowskiej-Curie 2, 60-965 Poznań, Poland

Polish Journal of Chemical Technology

The extraction of palladium(II) from hydrochloric acid solutions of various concentrations in the presence of different amounts of sodium chloride with...

Extraction of Palladium(II) Ions from Chloride Solutions with Phosphonium Ionic Liquid Cyphos®IL101

Pubblicato online: 19 ott 2007

Pagine: 99 - 101

DOI: https://doi.org/10.2478/v10026-007-0037-4

Parole chiave
extraction of palladium(II), hydrochloric acid, phosphonium ionic liquids

This content is open access.

Extraction of Palladium(II) Ions from Chloride Solutions with Phosphonium Ionic Liquid Cyphos®IL101

Pubblicato online: 19 ott 2007

Pagine: 99 - 101

DOI: https://doi.org/10.2478/v10026-007-0037-4

Parole chiaveextraction of palladium(II), hydrochloric acid, phosphonium ionic liquids

This content is open access.

Parole chiave
extraction of palladium(II), hydrochloric acid, phosphonium ionic liquids