SiO2 | 49.680 | 49.830 | SiO2 | 42.453 | 41.804 | 43.680 | 42.904 | 43.139 | 42.786 | |
TiO2 | 0.037 | 0.114 | TiO2 | 2.038 | 1.450 | 1.505 | 1.669 | 1.826 | 1.993 | |
Al2O3 | 0.618 | 0.682 | Al2O3 | 10.389 | 10.342 | 9.819 | 10.039 | 10.174 | 10.186 | |
FeO | 32.470 | 31.910 | FeO | 18.095 | 17.894 | 17.156 | 18.178 | 18.975 | 18.580 | |
Cr2O3 | 0.000 | 0.010 | Cr2O3 | 0.000 | 0.000 | 0.043 | 0.132 | 0.053 | 0.101 | |
MnO | 0.585 | 0.712 | MnO | 0.058 | 0.016 | 0.111 | 0.132 | 0.049 | 0.054 | |
MgO | 15.200 | 15.070 | MgO | 9.163 | 9.361 | 9.943 | 9.474 | 9.399 | 9.622 | |
CaO | 0.618 | 0.495 | CaO | 11.305 | 11.394 | 11.575 | 11.465 | 11.431 | 11.455 | |
Na2O | 0.014 | 0.055 | Na2O | 1.533 | 1.338 | 1.108 | 1.386 | 1.406 | 1.443 | |
K2O | 0.057 | 0.030 | K2O | 1.409 | 1.430 | 1.215 | 1.411 | 1.347 | 1.349 | |
Total | 99.290 | 98.900 | Cl | 0.071 | 0.085 | 0.063 | 0.077 | 0.043 | 0.140 | |
TSi | 1.958 | 1.970 | Total | 96.510 | 95.110 | 96.180 | 96.740 | 97.79 | 97.610 | |
TAl | 0.029 | 0.030 | O_Cl | 0.020 | 0.020 | 0.010 | 0.020 | 0.010 | 0.030 | |
TFe3+ | 0.014 | 0.000 | TSi | 6.553 | 6.517 | 6.681 | 6.580 | 6.556 | 6.512 | |
M1Al | 0.000 | 0.002 | TAl | 1.447 | 1.483 | 1.319 | 1.420 | 1.444 | 1.488 | |
M1Ti | 0.001 | 0.003 | Sum_T | 8 | 8 | 8 | 8 | 8 | 8 | |
M1Fe3+ | 0.044 | 0.026 | CAl | 0.442 | 0.416 | 0.449 | 0.393 | 0.377 | 0.337 | |
M1Fe2+ | 0.062 | 0.080 | CFe+3 | 0.000 | 0.038 | 0 | 0 | 0 | 0 | |
M1Cr | 0.000 | 0.000 | CTi | 0.237 | 0.170 | 0.173 | 0.193 | 0.209 | 0.228 | |
M1Mg | 0.893 | 0.888 | CMg | 2.109 | 2.176 | 2.267 | 2.166 | 2.129 | 2.183 | |
M2Mg | 0.000 | 0.000 | CFe+2 | 2.213 | 2.201 | 2.106 | 2.232 | 2.279 | 2.240 | |
M2Fe2 | 0.950 | 0.949 | Sum_C | 5 | 5 | 5 | 5 | 5 | 5 | |
M2Mn | 0.020 | 0.024 | BFe+2 | 0.123 | 0.095 | 0.089 | 0.099 | 0.132 | 0.125 | |
M2Ca | 0.026 | 0.021 | BMn | 0.008 | 0.002 | 0.014 | 0.017 | 0.006 | 0.007 | |
M2Na | 0.001 | 0.004 | BCa | 1.870 | 1.903 | 1.897 | 1.884 | 1.861 | 1.868 | |
M2K | 0.003 | 0.002 | Sum_B | 2 | 2 | 2 | 2 | 2 | 2 | |
Sum (cat) | 3.997 | 3.998 | ANa | 0.459 | 0.404 | 0.329 | 0.412 | 0.414 | 0.426 | |
Ca | 1.337 | 1.069 | AK | 0.277 | 0.284 | 0.237 | 0.276 | 0.261 | 0.262 | |
Mg | 45.770 | 45.260 | Sum_A | 0.736 | 0.689 | 0.566 | 0.688 | 0.675 | 0.688 | |
Fe2_Mn | 52.890 | 53.670 | Sum_cat | 15.736 | 15.689 | 15.566 | 15.688 | 15.675 | 15.688 | |
JD1 | 0.000 | 0.108 | CCl | 0.019 | 0.022 | 0.016 | 0.020 | 0.011 | 0.036 | |
AE1 | 0.202 | 0.186 | Sum_oxy | 23.102 | 23.000 | 23.023 | 23.031 | 23.016 | 23.002 | |
CFTS1 | 2.056 | 1.168 | ||||||||
CTTS1 | 0.056 | 0.174 | ||||||||
CATS1 | 0.000 | 0.000 | ||||||||
WO1 | 0.000 | 0.000 | ||||||||
EN1 | 45.780 | 45.560 | ||||||||
FS1 | 51.902 | 52.800 | ||||||||
Q | 1.931 | 1.939 | ||||||||
J | 0.002 | 0.008 | ||||||||
WO | 1.299 | 1.055 | ||||||||
EN | 44.460 | 44.670 | ||||||||
FS | 54.240 | 54.280 | ||||||||
WEF | 99.890 | 99.570 | ||||||||
JD | 0.000 | 0.032 | ||||||||
AE | 0.100 | 0.396 |
SiO2 | 0.046 |
TiO2 | 50.787 |
Al2O3 | 0.02 |
FeO | 46.372 |
Cr2O3 | 0.075 |
MnO | 0.477 |
MgO | 0.267 |
CaO | 0 |
Na2O | 0.061 |
Total | 98.11 |
Si | 0.001 |
Al | 0.001 |
Ti | 0.986 |
Fe2+ | 1.001 |
Cr | 0.002 |
Mn | 0.01 |
Mg | 0.01 |
Ca | 0 |
Na | 0.003 |
Cations | 2.014 |
SiO2 | 35.20 | 35.10 | 35.19 | 34.71 | 35.52 | 35.34 | 35.95 | 35.42 |
TiO2 | 5.23 | 5.15 | 4.97 | 4.84 | 4.84 | 4.97 | 5.09 | 5.00 |
Al2O3 | 13.63 | 13.79 | 14.14 | 13.75 | 13.92 | 13.35 | 13.82 | 13.83 |
Cr2O3 | 0.04 | 0.06 | 0.00 | 0.03 | 0.02 | 0.05 | 0.03 | 0.00 |
FeO | 21.02 | 20.48 | 20.75 | 20.96 | 19.97 | 20.59 | 20.41 | 20.72 |
MnO | 0.00 | 0.04 | 0.03 | 0.03 | 0.00 | 0.01 | 0.00 | 0.02 |
MgO | 9.88 | 9.95 | 10.15 | 9.93 | 10.00 | 10.07 | 9.99 | 9.64 |
CaO | 0.01 | 0.07 | 0.00 | 0.04 | 0.02 | 0.00 | 0.00 | 0.04 |
Na2O | 0.13 | 0.11 | 0.09 | 0.14 | 0.09 | 0.08 | 0.14 | 0.11 |
K2O | 9.74 | 9.71 | 9.57 | 9.62 | 9.56 | 8.54 | 9.63 | 9.74 |
Cl | 0.15 | 0.11 | 0.12 | 0.15 | 0.09 | 0.09 | 0.10 | 0.10 |
H2O | 1.80 | 1.81 | 1.81 | 1.78 | 1.81 | 1.80 | 1.83 | 1.81 |
Total | 95.03 | 94.57 | 95.01 | 94.2 | 94.03 | 93.09 | 95.16 | 94.62 |
Si | 5.739 | 5.735 | 5.717 | 5.714 | 5.803 | 5.823 | 5.812 | 5.782 |
AlIV | 2.261 | 2.265 | 2.283 | 2.286 | 2.197 | 2.177 | 2.188 | 2.218 |
AlVI | 0.356 | 0.388 | 0.423 | 0.380 | 0.481 | 0.414 | 0.443 | 0.441 |
Ti | 0.641 | 0.633 | 0.607 | 0.599 | 0.595 | 0.616 | 0.619 | 0.614 |
Fe2+ | 2.866 | 2.798 | 2.819 | 2.885 | 2.729 | 2.837 | 2.759 | 2.829 |
Cr | 0.005 | 0.008 | 0.000 | 0.004 | 0.003 | 0.007 | 0.004 | 0.000 |
Mn | 0.000 | 0.006 | 0.004 | 0.004 | 0.000 | 0.001 | 0.000 | 0.003 |
Mg | 2.401 | 2.423 | 2.458 | 2.437 | 2.436 | 2.474 | 2.408 | 2.346 |
Ca | 0.002 | 0.012 | 0.000 | 0.007 | 0.004 | 0.000 | 0.000 | 0.007 |
Na | 0.041 | 0.035 | 0.028 | 0.045 | 0.029 | 0.026 | 0.044 | 0.035 |
K | 2.026 | 2.024 | 1.984 | 2.020 | 1.993 | 1.795 | 1.986 | 2.028 |
Cations | 16.338 | 16.327 | 16.323 | 16.381 | 16.270 | 16.170 | 16.263 | 16.303 |
CCl | 0.083 | 0.061 | 0.066 | 0.084 | 0.050 | 0.050 | 0.055 | 0.055 |
OH | 1.959 | 1.970 | 1.967 | 1.958 | 1.975 | 1.975 | 1.973 | 1.972 |
O | 24 | 24 | 24 | 24 | 24 | 24 | 24 | 24 |
Fe/(Fe + Mg) | 0.5400 | 0.54 | 0.530 | 0.540 | 0.530 | 0.530 | 0.530 | 0.550 |
Mg/(Fe + Mg) | 0.460 | 0.460 | 0.470 | 0.460 | 0.470 | 0.470 | 0.470 | 0.450 |
SiO2 | 58.96 | 59.05 | 59.39 | 59.47 | 58.84 | 58.19 | 58.45 | 59.22 | 59.23 | 58.7 | 59.76 | 60.19 | 58.14 | 58.57 |
TiO2 | 0.02 | 0 | 0 | 0 | 0.04 | 0 | 0.37 | 0.01 | 0 | 0 | 0.04 | 0 | 0.03 | 0 |
Al2O3 | 25.53 | 25.59 | 25.55 | 25.03 | 25.72 | 25.77 | 25.8 | 25.65 | 25.34 | 25.26 | 24.06 | 24.78 | 25.24 | 25.49 |
FeO | 0.12 | 0.07 | 0.05 | 0.15 | 0.02 | 0.07 | 0.24 | 0.07 | 0.11 | 0.17 | 0 | 0.08 | 0.01 | 0.01 |
MnO | 0.01 | 0.01 | 0.05 | 0.02 | 0.01 | 0.04 | 0 | 0.03 | 0 | 0.04 | 0.02 | 0 | 0 | 0 |
MgO | 0 | 0.01 | 0 | 0 | 0.01 | 0 | 0 | 0 | 0.02 | 0 | 0 | 0.01 | 0 | 0 |
BaO | 0.01 | 0.04 | 0.08 | 0.05 | 0.07 | 0 | 0.07 | 0.03 | 0.09 | 0 | 0.06 | 0.01 | 0.08 | 0.03 |
CaO | 8.05 | 8.04 | 7.98 | 7.82 | 8.13 | 8.58 | 8.49 | 8.21 | 7.78 | 7.88 | 7.18 | 7.3 | 8.34 | 8.15 |
Na2O | 6.87 | 6.88 | 5.99 | 7.04 | 6.75 | 6.7 | 6.26 | 6.62 | 6.93 | 7.01 | 7.35 | 7.35 | 6.07 | 6.53 |
K2O | 0.38 | 0.37 | 0.39 | 0.39 | 0.34 | 0.37 | 0.36 | 0.34 | 0.37 | 0.36 | 0.49 | 0.41 | 0.37 | 0.39 |
Total | 99.95 | 100.06 | 99.48 | 99.97 | 99.93 | 99.72 | 100.04 | 100.18 | 99.87 | 99.42 | 98.96 | 100.13 | 98.28 | 99.17 |
Si | 2.639 | 2.64 | 2.659 | 2.661 | 2.633 | 2.616 | 2.617 | 2.642 | 2.651 | 2.642 | 2.697 | 2.683 | 2.642 | 2.639 |
Al | 1.346 | 1.347 | 1.347 | 1.319 | 1.356 | 1.364 | 1.36 | 1.347 | 1.336 | 1.339 | 1.279 | 1.301 | 1.351 | 1.353 |
Fe3+ | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Ti | 0.001 | 0 | 0 | 0 | 0.001 | 0 | 0.012 | 0 | 0 | 0 | 0.001 | 0 | 0.001 | 0 |
Fe2+ | 0.004 | 0.003 | 0.002 | 0.006 | 0.001 | 0.003 | 0.009 | 0.003 | 0.004 | 0.006 | 0 | 0.003 | 0 | 0 |
Mn | 0 | 0 | 0.002 | 0.001 | 0 | 0.002 | 0 | 0.001 | 0 | 0.002 | 0.001 | 0 | 0 | 0 |
Mg | 0 | 0.001 | 0 | 0 | 0.001 | 0 | 0 | 0 | 0.001 | 0 | 0 | 0.001 | 0 | 0 |
Ba | 0 | 0.001 | 0.001 | 0.001 | 0.001 | 0 | 0.001 | 0.001 | 0.002 | 0 | 0.001 | 0 | 0.001 | 0.001 |
Ca | 0.386 | 0.385 | 0.383 | 0.375 | 0.39 | 0.413 | 0.407 | 0.392 | 0.373 | 0.38 | 0.347 | 0.349 | 0.406 | 0.393 |
Na | 0.596 | 0.596 | 0.52 | 0.611 | 0.586 | 0.584 | 0.543 | 0.573 | 0.602 | 0.612 | 0.643 | 0.635 | 0.535 | 0.571 |
K | 0.022 | 0.021 | 0.022 | 0.022 | 0.019 | 0.021 | 0.021 | 0.019 | 0.021 | 0.021 | 0.028 | 0.023 | 0.021 | 0.022 |
Cations | 4.994 | 4.995 | 4.937 | 4.997 | 4.989 | 5.003 | 4.971 | 4.979 | 4.992 | 5.002 | 4.998 | 4.995 | 4.958 | 4.98 |
X | 3.986 | 3.987 | 4.006 | 3.98 | 3.99 | 3.98 | 3.989 | 3.989 | 3.987 | 3.981 | 3.977 | 3.984 | 3.994 | 3.992 |
Z | 1.008 | 1.007 | 0.93 | 1.016 | 0.998 | 1.023 | 0.981 | 0.989 | 1.003 | 1.021 | 1.02 | 1.011 | 0.963 | 0.987 |
Ab | 59.4 | 59.5 | 56.2 | 60.6 | 58.9 | 57.4 | 55.9 | 58.2 | 60.4 | 60.4 | 63.2 | 63.1 | 55.6 | 57.9 |
An | 38.4 | 38.4 | 41.4 | 37.2 | 39.2 | 40.6 | 41.9 | 39.8 | 37.4 | 37.5 | 34.1 | 34.7 | 42.2 | 39.9 |
Or | 2.2 | 2.1 | 2.4 | 2.2 | 1.9 | 2.1 | 2.2 | 1.9 | 2.1 | 2.1 | 2.8 | 2.3 | 2.2 | 2.2 |
Wt% | ppm | ppm | |||
SiO2 | 50.93 | V | 188.28 | La | 57.71 |
Al2O3 | 15.51 | Cr | 95.31 | Ce | 119.2 |
CaO | 7.79 | Co | 107.09 | Pr | 14.13 |
Fe2O3 | 12.3 | Ni | 52.36 | Nd | 54.64 |
MgO | 5.14 | Cu | 41.17 | Sm | 9.05 |
K2O | 1.01 | Zn | 124.1 | Eu | 2.27 |
MnO | 0.15 | Rb | 18.36 | Gd | 7.325 |
Na2O | 3.33 | Sr | 583.8 | Tb | 0.856 |
TiO2 | 2.15 | Zr | 294.09 | Dy | 4.365 |
P2O5 | 0.65 | Nb | 20.61 | Ho | 0.8 |
Cr2O3 | 0.02 | Mo | 1.54 | Er | 2.02 |
LOI | 0.34 | Cs | 0.31 | Tm | 0.251 |
Total | 99.32 | Ba | 479.77 | Yb | 1.63 |
Hf | 6.49 | Lu | 0.22 | ||
Ta | 1.08 | Total | 274.4 | ||
Pb | 8.51 | LaN/YbN | 25.39 | ||
Th | 2.89 | GdN/YbN | 3.72 | ||
U | 0.45 | EuN/EuN* | 0.852 | ||
Ce/Ce* | 1.153 |