Critical comparison of INAA and ICP-MS applied in the characterization of purity of TRISO fuel and substrates to its production
e | 25 nov 2021
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Article Category: Original Paper
Pubblicato online: 25 nov 2021
Pagine: 121 - 126
Ricevuto: 09 feb 2021
Accettato: 12 apr 2021
DOI: https://doi.org/10.2478/nuka-2021-0018
Parole chiave
© 2021 Ewelina Chajduk et al., published by Sciendo
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Fig. 1
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Fig. 3
Chosen features of ICP-MS and INAA used in elemental analysis of nuclear materials
| ICP-MS | INAA | |
|---|---|---|
| Accuracy | Good | Excellent |
| Sensitivity | High | High |
| Matrix effect | Yes | No |
| Time response | Low-medium | Low |
Mean concentrations of elements as determined by NAA and LA ICP-MS in the analysed silicon carbide (n = 3) and pyrolytic graphite
| Silicon carbide |
||
| Element | NAA (ng/g) | LA-ICP-MS (ng/g) |
| Co | 678 | (950) |
| Eu | 42 | n.d. |
| Fe | 980 | (1390) |
| Hf | 648 | n.d. |
| Sc | 140 | n.d. |
| Pyrolytic graphite |
||
| Element | NAA (ng/g) | LA-ICP-MS (ng/g) |
| Ag | 320 | (560) |
Mean concentration of elements in ascorbic acid and silicone oil by ICP-MS and INAA (n = 3)
| Element | Ascorbic acid | Silicone oil | ||
|---|---|---|---|---|
| ICP-MS | NAA | ICP-MS | NAA | |
| U (ppb) | <5 | <250 | 152 | <250 |
| Mn (ppb) | 189 | n.d. | 1269 | n.d. |
| Co (ppb) | <50 | <50 | <50 | <50 |
| Cd (ppb) | <50 | n.d. | 1269 | n.d. |
| Th (ppb) | <5 | <100 | 1988 | 1780 |
| Cu (ppb) | <250 | n.d. | 1413 | n.d. |
| Pb (ppb) | 987 | n.d. | 1015 | n.d. |
| V (ppb) | <180 | n.d. | 205 | n.d. |
| Sb (ppb) | <200 | <150 | <200 | <150 |
| Se (ppb) | <500 | <100 | <500 | 72 |
| Al (ppm) | 17.9 | n.d. | 47.9 | n.d. |
| Cr (ppm) | <2.5 | <1 | <2.5 | 1.4 |
| Ni (ppm) | <0.5 | <2.5 | 2.5 | n.d. |
| Fe (ppm) | <1 | <0.5 | 186 | 150 |
| Zn (ppm) | 0.26 | 0.33 | 5.0 | 4.8 |