<abstract xmlns="http://www.w3.org/1999/xhtml">Crystalline MoO3 nanoparticles were obtained by electrochemical synthesis process using tetrapropylammonium bromide as a stabilizer and structure-directing agent in ACN:THF(4:1) solvent. Formation of MoO3 nanoparticles took place at a constant supply current of 14 mA/cm2. These synthesized MoO3 nanoparticles were characterized by UV-Vis spectroscopy, FT-IR spectroscopy, powder X-ray diffraction (XRD), scanning electron microscopy (SEM). So prepared MoO3 nanoparticles were used as a heterogeneous catalyst for the synthesis of 2,6-bis(benzylidene)cyclohexanone derivatives. This protocol offers several advantages, such as simple work-up procedure, recyclability of the catalyst, excellent product yield in a short reaction time and purification of products with a non-chromatographic method.</abstract>

Crystalline MoO3 nanoparticles were obtained by electrochemical synthesis process using tetrapropylammonium bromide as a stabilizer and structure-directing agent in ACN:THF(4:1) solvent. Formation of MoO3 nanoparticles took place at a constant supply current of 14 mA/cm2. These synthesized MoO3 nanoparticles were characterized by UV-Vis spectroscopy, FT-IR spectroscopy, powder X-ray diffraction (XRD), scanning electron microscopy (SEM). So prepared MoO3 nanoparticles were used as a heterogeneous catalyst for the synthesis of 2,6-bis(benzylidene)cyclohexanone derivatives. This protocol offers several advantages, such as simple work-up procedure, recyclability of the catalyst, excellent product yield in a short reaction time and purification of products with a non-chromatographic method.

Nanosized MoO3 as a reusable heterogeneous catalyst for the synthesis of 2,6-bis(benzylidene)cyclohexanones

Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad – 431004 (M.S.), India

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Nanosized MoO as a reusable heterogeneous catalyst for the synthesis of 2,6-bis(benzylidene)cyclohexanones

Crystalline MoO3 nanoparticles were obtained by electrochemical synthesis process using tetrapropylammonium bromide as a stabilizer and structure-directing...

Nanosized MoO₃ as a reusable heterogeneous catalyst for the synthesis of 2,6-bis(benzylidene)cyclohexanones

Pubblicato online: 13 mar 2015

Pagine: 163 - 168

Ricevuto: 07 ago 2014

Accettato: 09 dic 2014

DOI: https://doi.org/10.1515/msp-2015-0024

© 2015

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.