<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml"><p>In the work, sulfonated poly(ether-ether-ketone) (SPEEK) ionomers were synthesized using an original (submitted for patent) and simple method. The resulting membranes were tested to determine parameters that are important for the use of this material in fuel cells (water absorption, sulfonation degree, conductivity, etc.). The thermo-gravimetric analysis has shown a good thermal stability in the range from RT to 200-220 °C, and two characteristic regions of weight loss - 7.4% at ~140 °C (reversible water loss) and 10.3% at 200-220 °C (due to polymer degradation when cross-linked polymer chains permanently break down and their SO<sub>3</sub>H-groups are lost). The conductivity values obtained by the through-plane measurements of SPEEK membranes were 12 mS/cm at RT and 23 mS/cm at 80 °C.</p></abstract>

In the work, sulfonated poly(ether-ether-ketone) (SPEEK) ionomers were synthesized using an original (submitted for patent) and simple method. The resulting membranes were tested to determine parameters that are important for the use of this material in fuel cells (water absorption, sulfonation degree, conductivity, etc.). The thermo-gravimetric analysis has shown a good thermal stability in the range from RT to 200-220 °C, and two characteristic regions of weight loss - 7.4% at ~140 °C (reversible water loss) and 10.3% at 200-220 °C (due to polymer degradation when cross-linked polymer chains permanently break down and their SO3H-groups are lost). The conductivity values obtained by the through-plane measurements of SPEEK membranes were 12 mS/cm at RT and 23 mS/cm at 80 °C.

Sulfonated Poly(Ether-Ether-Ketone) Polymer Membranes for Fuel Cells

Institute of Solid State Physics, University of Latvia, 8 Kengaraga Str., Riga, LV-1063, LATVIA

Latvian Journal of Physics and Technical Sciences

{"article-title":"Sulfonated Poly(Ether-Ether-Ketone) Polymer Membranes for Fuel Cells"}

In the work, sulfonated poly(ether-ether-ketone) (SPEEK) ionomers were synthesized using an original (submitted for patent) and simple method. The resulting...

Sulfonated Poly(Ether-Ether-Ketone) Polymer Membranes for Fuel Cells

Publié en ligne: 20 janv. 2009

Pages: 55 - 60

DOI: https://doi.org/10.2478/v10047-008-0029-z

Mots clés
proton conductor, polymer membrane, SPEEK, differential thermal analysis

This content is open access.

Sulfonated Poly(Ether-Ether-Ketone) Polymer Membranes for Fuel Cells

Publié en ligne: 20 janv. 2009

Pages: 55 - 60

DOI: https://doi.org/10.2478/v10047-008-0029-z

Mots clésproton conductor, polymer membrane, SPEEK, differential thermal analysis

This content is open access.

Mots clés
proton conductor, polymer membrane, SPEEK, differential thermal analysis