<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml">The electron transfer reaction of L-cysteine (RSH) with pyridinium chlorochromate (PCC) has been studied spectrophotometrically over the range 2.0 ≤ 103 [RSH] ≤ 6.0; 0.01 ≤ [H+] ≤ 0.2; 298 ≤ T ≤ 318 K and I = 0.3 mol dm-3 (NaClO4). The electron transfer reaction has also been carried out in the presence of anionic, cationic and neutral micelle. The reaction in acid medium is strongly catalyzed by changing [SDS]T (sodium dodecyl sulfate) up to 3 × 10-2 mol dm-3, beyond this concentration of SDS, the rate is retarded. The cationic and neutral micelle has a small effect on the rate. <italic>ΔH≠</italic> (kJ mol-1) and <italic>ΔS≠</italic> (JK-1 mol-1) values for the k1 and k2 paths are 30.20 ± 0.25, -159.65 ± 0.83 and 29.60 ± 0.62, -127.09 ± 2.17, respectively. The negative activation entropy is indicative of the ordered transition state for the electron transfer reaction. Formation of 2-amino-3-(2-amino-2-carboxy-ethyl) disulfanyl-propanoic acid as product is strongly supported by IR spectra.</abstract>

The electron transfer reaction of L-cysteine (RSH) with pyridinium chlorochromate (PCC) has been studied spectrophotometrically over the range 2.0 ≤ 103 [RSH] ≤ 6.0; 0.01 ≤ [H+] ≤ 0.2; 298 ≤ T ≤ 318 K and I = 0.3 mol dm-3 (NaClO4). The electron transfer reaction has also been carried out in the presence of anionic, cationic and neutral micelle. The reaction in acid medium is strongly catalyzed by changing [SDS]T (sodium dodecyl sulfate) up to 3 × 10-2 mol dm-3, beyond this concentration of SDS, the rate is retarded. The cationic and neutral micelle has a small effect on the rate. ΔH≠ (kJ mol-1) and ΔS≠ (JK-1 mol-1) values for the k1 and k2 paths are 30.20 ± 0.25, -159.65 ± 0.83 and 29.60 ± 0.62, -127.09 ± 2.17, respectively. The negative activation entropy is indicative of the ordered transition state for the electron transfer reaction. Formation of 2-amino-3-(2-amino-2-carboxy-ethyl) disulfanyl-propanoic acid as product is strongly supported by IR spectra.

Kinetics and mechanism of electron transfer to pyridinium chlorochromate (VI) from sulfur containing amino acid, L-cysteine in aqueous and micellar media

PG Department of Chemistry, Utkal University, Vani Vihar, Bhubaneswar-751004, Orissa, India

PG Department of Chemistry, Ravenshaw Uiversity, Cuttack-753003, Orissa, India

PG Department of Chemistry, Khallikote College, Berhampur-76001, Orissa, India

Polish Journal of Chemical Technology

The electron transfer reaction of L-cysteine (RSH) with pyridinium chlorochromate (PCC) has been studied spectrophotometrically over the range 2.0 ≤ 103 [RSH]...

Kinetics and mechanism of electron transfer to pyridinium chlorochromate (VI) from sulfur containing amino acid, L-cysteine in aqueous and micellar media

Publié en ligne: 16 juin 2011

Pages: 6 - 10

DOI: https://doi.org/10.2478/v10026-011-0016-7

Mots clés
kinetics mechanism, electron transfer, pyridinium chlorochromate, cysteine, micellar media

This content is open access.

Kinetics and mechanism of electron transfer to pyridinium chlorochromate (VI) from sulfur containing amino acid, L-cysteine in aqueous and micellar media

Publié en ligne: 16 juin 2011

Pages: 6 - 10

DOI: https://doi.org/10.2478/v10026-011-0016-7

Mots cléskinetics mechanism, electron transfer, pyridinium chlorochromate, cysteine, micellar media

This content is open access.

Mots clés
kinetics mechanism, electron transfer, pyridinium chlorochromate, cysteine, micellar media