<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml">Epoxidation of crotyl alcohol (CA) with 30 wt% hydrogen peroxide over Ti-MWW catalyst has been studied with methanol as a solvent and at autogenic pressure. The influence of temperature in the range of 20-120°C, the molar ratio of CA/H2O2 1:1-5:1, methanol concentration 5-90 wt%, Ti-MWW catalyst concentration 0.0-5.0 wt% and the reaction time 5-300 min have been studied. The main product of CA epoxidation is 2,3-epoxybutane-1-ol (2,3EB1O), a compound with many applications.</abstract>

Epoxidation of crotyl alcohol (CA) with 30 wt% hydrogen peroxide over Ti-MWW catalyst has been studied with methanol as a solvent and at autogenic pressure. The influence of temperature in the range of 20-120°C, the molar ratio of CA/H2O2 1:1-5:1, methanol concentration 5-90 wt%, Ti-MWW catalyst concentration 0.0-5.0 wt% and the reaction time 5-300 min have been studied. The main product of CA epoxidation is 2,3-epoxybutane-1-ol (2,3EB1O), a compound with many applications.

Epoxidation of crotyl alcohol in the presence of titanium silicalite Ti-MWW catalyst — the new and friendly method of 2,3-epoxybutane-1-ol synthesis

Institute of Organic Chemical Technology, West Pomeranian University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

Polish Journal of Chemical Technology

Epoxidation of crotyl alcohol (CA) with 30 wt% hydrogen peroxide over Ti-MWW catalyst has been studied with methanol as a solvent and at autogenic pressure....

Epoxidation of crotyl alcohol in the presence of titanium silicalite Ti-MWW catalyst — the new and friendly method of 2,3-epoxybutane-1-ol synthesis

Publié en ligne: 09 juil. 2010

Pages: 57 - 61

DOI: https://doi.org/10.2478/v10026-010-0019-9

Mots clés
Ti-MWW, crotyl alcohol epoxidation, 2,3-epoxybutane-1-ol

This content is open access.

Epoxidation of crotyl alcohol in the presence of titanium silicalite Ti-MWW catalyst — the new and friendly method of 2,3-epoxybutane-1-ol synthesis

Publié en ligne: 09 juil. 2010

Pages: 57 - 61

DOI: https://doi.org/10.2478/v10026-010-0019-9

Mots clésTi-MWW, crotyl alcohol epoxidation, 2,3-epoxybutane-1-ol

This content is open access.

Mots clés
Ti-MWW, crotyl alcohol epoxidation, 2,3-epoxybutane-1-ol