<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml"><p>HNS (2, 2′, 4, 4′, 6, 6′-hexanitrostillbene) is a heat-resistant photosensitive explosive widely used in the booster charge. Investigation of the photodecomposition mechanism may provide important information for controlling and enhancing the detonation performance, also for the lifetime prediction. The UV-induced photodecomposition of HNS has been subjected to experimental studies. The UV-Vis spectra, X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance spectra (EPR) demonstrate the formation of NO2 free radicals and nitroso derivatives of HNS upon UV irradiation, which proves well known facts that C-NO2 breaking and removal of oxygen from the nitro group take part in the photodecomposition of HNS.</p></abstract>

HNS (2, 2′, 4, 4′, 6, 6′-hexanitrostillbene) is a heat-resistant photosensitive explosive widely used in the booster charge. Investigation of the photodecomposition mechanism may provide important information for controlling and enhancing the detonation performance, also for the lifetime prediction. The UV-induced photodecomposition of HNS has been subjected to experimental studies. The UV-Vis spectra, X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance spectra (EPR) demonstrate the formation of NO2 free radicals and nitroso derivatives of HNS upon UV irradiation, which proves well known facts that C-NO2 breaking and removal of oxygen from the nitro group take part in the photodecomposition of HNS.

UV-induced photodecomposition of 2, 2′, 4, 4′, 6, 6′-hexanitrostillbene (HNS)

Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang Sichuan, People’s Republic of China, 621900

School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing Jiangsu, People’s Republic of China, 210094

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

HNS (2, 2′, 4, 4′, 6, 6′-hexanitrostillbene) is a heat-resistant photosensitive explosive widely used in the booster charge. Investigation of the...

UV-induced photodecomposition of 2, 2′, 4, 4′, 6, 6′-hexanitrostillbene (HNS)

Publié en ligne: 29 août 2013

Pages: 306 - 311

DOI: https://doi.org/10.2478/s13536-013-0105-9

Mots clés
HNS, photodecomposition, C-NO2 breaking, removal of oxygen

© 2013 Wroclaw University of Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

UV-induced photodecomposition of 2, 2′, 4, 4′, 6, 6′-hexanitrostillbene (HNS)

Publié en ligne: 29 août 2013

Pages: 306 - 311

DOI: https://doi.org/10.2478/s13536-013-0105-9

Mots clésHNS, photodecomposition, C-NO2 breaking, removal of oxygen

© 2013 Wroclaw University of Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mots clés
HNS, photodecomposition, C-NO2 breaking, removal of oxygen