<abstract xmlns="http://www.w3.org/1999/xhtml"><p>A class of very important industrial-grade biolubricants was synthesized from plant-derived fatty acids (oleic and isostearic acid) by direct esterification of trimethylolpropane according to novel effective and high selective method using Sn bis(2-ethylhexanoate) as catalyst. Model transesterification reactions were performed with oleic and isostearic acids to optimize the reaction conditions to obtain maximum content of TMP triesters. Used specific homogeneous Sn catalyst allows to obtain TMP esters with very high content of triesters, above of 94 wt% without deep vacuum purifying distillation. Both TMP esters were evaluated for their physicochemical and tribological properties using ASTM standards. Both TMP esters exhibited high viscosity indexes and excellent low temperature properties.</p></abstract>

A class of very important industrial-grade biolubricants was synthesized from plant-derived fatty acids (oleic and isostearic acid) by direct esterification of trimethylolpropane according to novel effective and high selective method using Sn bis(2-ethylhexanoate) as catalyst. Model transesterification reactions were performed with oleic and isostearic acids to optimize the reaction conditions to obtain maximum content of TMP triesters. Used specific homogeneous Sn catalyst allows to obtain TMP esters with very high content of triesters, above of 94 wt% without deep vacuum purifying distillation. Both TMP esters were evaluated for their physicochemical and tribological properties using ASTM standards. Both TMP esters exhibited high viscosity indexes and excellent low temperature properties.

Statistical optimization of the synthesis of plant-derived fatty acid esters of TMP over homogeneous organometallic tin catalyst

Institute of Heavy Organic Synthesis “Blachownia”

Institute for Sustainable Technologies – National Research Inst.

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

A class of very important industrial-grade biolubricants was synthesized from plant-derived fatty acids (oleic and isostearic acid) by direct esterification of...

Statistical optimization of the synthesis of plant-derived fatty acid esters of TMP over homogeneous organometallic tin catalyst

Publié en ligne: 25 juil. 2018

Pages: 61 - 70

DOI: https://doi.org/10.2478/pjct-2018-0024

Mots clés
tin catalyst, trimethylolpropane esters, statistical optimization, tribology

© 2018 Janusz Nowicki et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Statistical optimization of the synthesis of plant-derived fatty acid esters of TMP over homogeneous organometallic tin catalyst

Publié en ligne: 25 juil. 2018

Pages: 61 - 70

DOI: https://doi.org/10.2478/pjct-2018-0024

Mots cléstin catalyst, trimethylolpropane esters, statistical optimization, tribology

© 2018 Janusz Nowicki et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mots clés
tin catalyst, trimethylolpropane esters, statistical optimization, tribology