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Figure 1

Diagram of the process treatment of coke wastewater.
Diagram of the process treatment of coke wastewater.

Figure 2

Diagram of me multi-marge treatment of coke wastewater.
Diagram of me multi-marge treatment of coke wastewater.

Figure 3

Biological treatment scheme for process waters.
Biological treatment scheme for process waters.

Raw coke wastewater [Miodoński et al. 2010].

ParameterConcentration mg/dm3
Ammonium nitrogen600
Total nitrogen900
Chemical oxygen demand4500
Phenols2000
Thiocyanates30
Free cyanides5
Hydrogen sulphide50

Quality parameters of the wastewater discharged.

Type of substanceDz.U. 2006 nr 136 poz. 964 mg/dm3 mgO2/dm3Dz.U. 2014 poz. 1800 mg/dm3 mgO2/dm3Requirements of BAT 56

Decyzja …2012.

mg/dm3
Ammonium nitrogen100–20010-
Nitrite nitrogen101-
Total nitrogen-30<15–50
Chlorides10001000-
COD*250

The values of the indicators shall be determined on the basis of the permissible load of the treatment plant.

<220

The values of the indicators shall be determined on the basis of the permissible load of the treatment plant.

BOD5*25

The values of the indicators shall be determined on the basis of the permissible load of the treatment plant.

<20

The values of the indicators shall be determined on the basis of the permissible load of the treatment plant.

Free cyanides0.50.1<0.1
Combined cyanides55-
Thiocyanides--<4.0
Free sulphides-0.2<0.1
Thiocyanates3010-
Volatile phenols150.1<0.5
PAHs1515<0.05
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Life Sciences, Ecology