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Co@Co3O4@Nitrogen doped carbon (Co@Co3O4@NDC) composite is synthesized by high temperature carbonization of ionic liquids followed by low temperature thermal oxidation. In the process of high temperature carbonization, cobalt ions are reduced to metallic cobalt, producing Co@Nitrogen doped carbon (Co@NDC). Co@Co3O4@NDC composite is obtained after low temperature oxidation, in which a part of the metallic cobalt is oxidized to Co3O4. The structural characterizations indicate that the composite is composed of three crystalline phases (carbon, Co and Co3O4). The results of transmission electron microscopy study show that the carbon materials not only coat the Co@Co3O4 nanoparticles, but also form carbon network that connects the Co@Co3O4 nanoparticles. This conductive carbon network is beneficial to improve the electrochemical performance of the composite. The electrochemical test results show that the Co@Co3O4@NDC composite exhibits excellent electrochemical performance, delivering the discharge capacities of 790 and 304 mAh˙g−1 after 1500 cycles at 5 C and 10 C. This excellent electrochemical performance is due to synergistic effects of Co3O4, cobalt nanoparticles embedded in carbon which has high conductivity, and nitrogen functional groups.
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Co@Co3O4@Nitrogen doped carbon (Co@Co3O4@NDC) composite is synthesized by high temperature carbonization of ionic liquids followed by low temperature thermal oxidation. In the process of high temperature carbonization, cobalt ions are reduced to metallic cobalt, producing Co@Nitrogen doped carbon (Co@NDC). Co@Co3O4@NDC composite is obtained after low temperature oxidation, in which a part of the metallic cobalt is oxidized to Co3O4. The structural characterizations indicate that the composite is composed of three crystalline phases (carbon, Co and Co3O4). The results of transmission electron microscopy study show that the carbon materials not only coat the Co@Co3O4 nanoparticles, but also form carbon network that connects the Co@Co3O4 nanoparticles. This conductive carbon network is beneficial to improve the electrochemical performance of the composite. The electrochemical test results show that the Co@Co3O4@NDC composite exhibits excellent electrochemical performance, delivering the discharge capacities of 790 and 304 mAh˙g−1 after 1500 cycles at 5 C and 10 C. This excellent electrochemical performance is due to synergistic effects of Co3O4, cobalt nanoparticles embedded in carbon which has high conductivity, and nitrogen functional groups.

Facile preparation of Co@Co3O4@Nitrogen doped carbon composite from ionic liquid as anode material for high performance lithium-ion batteries

State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Facile preparation of Co@CoO@Nitrogen doped carbon composite from ionic liquid as anode material for high performance lithium-ion batteries

Co@Co3O4@Nitrogen doped carbon (Co@Co3O4@NDC) composite is synthesized by high temperature carbonization of ionic liquids followed by low temperature thermal...

Facile preparation of Co@Co₃O₄@Nitrogen doped carbon composite from ionic liquid as anode material for high performance lithium-ion batteries

Publié en ligne: 13 avr. 2021

Pages: 601 - 612

Reçu: 25 juil. 2018

Accepté: 23 avr. 2019

DOI: https://doi.org/10.2478/msp-2020-0065

Mots clés
Co@CoO@Nitrogen doped carbon composite, ionic liquid, lithium ion battery, anode material

© 2020 Mingjun Xiao et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Facile preparation of Co@Co3O4@Nitrogen doped carbon composite from ionic liquid as anode material for high performance lithium-ion batteries

Publié en ligne: 13 avr. 2021

Pages: 601 - 612

Reçu: 25 juil. 2018

Accepté: 23 avr. 2019

DOI: https://doi.org/10.2478/msp-2020-0065

Mots clésCo@CoO@Nitrogen doped carbon composite, ionic liquid, lithium ion battery, anode material

© 2020 Mingjun Xiao et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Facile preparation of Co@Co₃O₄@Nitrogen doped carbon composite from ionic liquid as anode material for high performance lithium-ion batteries

Mots clés
Co@CoO@Nitrogen doped carbon composite, ionic liquid, lithium ion battery, anode material