<abstract xmlns="http://www.w3.org/1999/xhtml">In this research, a series of Ru(II) complexes, ([Ru(1-7)(ina)(NCS)2] (1-7=5-[6-(5-mercapto-1,3,4-oxadiazol-2-yl)pyridin- 2-yl]-1,3,4-oxadiazole-2-thiol’s, ina=isonicotinic acid) were synthesized and characterized using different spectroscopic and analytic techniques, such as NMR, UV, IR, CV and CHN. Also, the new complexes were used in dye-sensitized solar cells (DSSC) as sensitizers. Current-voltage characteristics showed that the modifications of ligands clearly affected DSSC yield. Additionally, DFT calculations were performed and showed locations of frontier molecular orbitals of the complexes. While the locations of HOMO and HOMO – 1 orbitals are on Ru(II) metal center and SCN− ligands, the location of LUMO and LUMO + 1 orbitals are on the 1-7 ligands.</abstract>

In this research, a series of Ru(II) complexes, ([Ru(1-7)(ina)(NCS)2] (1-7=5-[6-(5-mercapto-1,3,4-oxadiazol-2-yl)pyridin- 2-yl]-1,3,4-oxadiazole-2-thiol’s, ina=isonicotinic acid) were synthesized and characterized using different spectroscopic and analytic techniques, such as NMR, UV, IR, CV and CHN. Also, the new complexes were used in dye-sensitized solar cells (DSSC) as sensitizers. Current-voltage characteristics showed that the modifications of ligands clearly affected DSSC yield. Additionally, DFT calculations were performed and showed locations of frontier molecular orbitals of the complexes. While the locations of HOMO and HOMO – 1 orbitals are on Ru(II) metal center and SCN− ligands, the location of LUMO and LUMO + 1 orbitals are on the 1-7 ligands.

Synthesis, characterization and application of Ru(II) complexes containing pyridil ligands for dye-sensitized solar cells

Faculty of Sciences and Art, Department of Chemistry

Faculty of Education, Department of Mathematics and Science Education

Faculty of Sciences and Art, Department of Physics

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

In this research, a series of Ru(II) complexes, ([Ru(1-7)(ina)(NCS)2] (1-7=5-[6-(5-mercapto-1,3,4-oxadiazol-2-yl)pyridin- 2-yl]-1,3,4-oxadiazole-2-thiol’s,...

Synthesis, characterization and application of Ru(II) complexes containing pyridil ligands for dye-sensitized solar cells

Publié en ligne: 12 déc. 2020

Pages: 450 - 458

Reçu: 24 oct. 2018

Accepté: 23 avr. 2019

DOI: https://doi.org/10.2478/msp-2020-0060

Mots clés
Ru(II) complexes, dye-sensitized solar cells (DSSCs), sensitizer, DFT, current-voltage characteristics

© 2020 Osman Dayan et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Synthesis, characterization and application of Ru(II) complexes containing pyridil ligands for dye-sensitized solar cells

Publié en ligne: 12 déc. 2020

Pages: 450 - 458

Reçu: 24 oct. 2018

Accepté: 23 avr. 2019

DOI: https://doi.org/10.2478/msp-2020-0060

Mots clésRu(II) complexes, dye-sensitized solar cells (DSSCs), sensitizer, DFT, current-voltage characteristics

© 2020 Osman Dayan et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Mots clés
Ru(II) complexes, dye-sensitized solar cells (DSSCs), sensitizer, DFT, current-voltage characteristics