Eco-friendly and efficient monitoring of physico-chemical parameters of some mineral water from Slanic Moldova (Romania) during storage in different conditions – a case study

1[1]. French Food Safety Agency, Guidelines for the Safety Assessment of Natural Mineral Waters, 2008. https://www.anses.fr/en/system/files/EAUX-Ra-EauxMineralesEN (accessed Oct. 21, 2022). Search in Google Scholar

2[2]. M. Bycroft, Iatrochemistry and the evaluation of mineral waters in France, 1600-1750, Bulletin of the History of Medicine 91 (2017) 303–330. Doi: 10.1353/bhm.2017.0028. Search in Google Scholar

3[3]. Directive 2009/54/EC of the European Parliament and of the Council of 18 June 2009 on the exploitation and marketing of natural mineral waters (Official Journal of the European Union, 26.06.2009, L 164, 45-58. http://data.europa.eu/eli/dir/2009/54/oj). Search in Google Scholar

4[4]. A.J. Whelton, A.M. Dietrich, G.A. Burlingame, M. Schechs, S.E. Duncan, Minerals in drinking water: impacts on taste and importance to consumer health, Water Science and Technology 55 (2007) 283–291. Doi: 10.2166/wst.2007.190. Search in Google Scholar

5[5]. S. Quanttrini, B. Pampaloni, M.L. Brandi, Natural mineral waters: chemical characteristics and health effects, Clinical Cases in Mineral and Bone Metabolism 13 (2016) 173–180. Doi: 10.11138/ccmbm/2016.13.3.173. Search in Google Scholar

6[6]. M.C. Albertini, M. Dachà, L. Teodori, M.E. Conti, Drinking mineral waters: biochemical effects and health implications, International Journal of Environmental Health Research 1 (2007) 153–169. Doi: 10.1504/IJENVH.2007.012230. Search in Google Scholar

7[7]. E. Wynn, E. Raetz, P. Burckhardt, The composition of mineral waters sourced from Europe and North America in respect to bone health: composition of mineral water optimal for bone, British Journal of Nutrition 101 (2009) 1195–1199. Doi: 10.1017/S0007114508061515. Search in Google Scholar

8[8]. M.G. Evandri, P. Bolle, Pharmaco-toxicological screening of commercially available Italian natural mineral waters, Il Farmaco 56 (2001) 475–482. Doi: 10.1016/S0014-827X(01)01066-7. Search in Google Scholar

9[9]. N.Đ. Pantelić, S. Jaćimović, J. Štrbački, D.B. Milovanović, B.P. Dojčinović, A.Ž. Kostić, Assessment of spa mineral water quality from Vrnjačka Banja, Serbia: geochemical, bacteriological, and health risk aspects, Environmental Monitoring and Assessment 191 (2019) 648. Doi:10.1007/s10661-019-7848-7. Search in Google Scholar

10[10]. E. Dinelli, A. Lima, B. De Vivo, S. Albanese, D. Cicchella, P. Valera, Hydrogeochemical analysis on Italian bottled mineral waters: effects of geology, Journal of Geochemical Exploration 107 (2010) 317–335. Doi: 10.1016/j.gexplo.2010.06.004. Search in Google Scholar

11[11]. A. Feru, A Comparative Revue of the Bottled Mineral Natural Water Characteristics in Roumania and the Most Important European States, Proceedings of the International Symposium A. H. R. “Mineral and thermal groundwater”, Miercurea Ciuc, Romania, 24-27 June, 1998, pp. 77–82. Search in Google Scholar

12[12]. K. Kurek, A. Operacz, P. Bugajski, D. Młyński, A. Wałega, J. Pawełek, Prediction of the stability of chemical composition of therapeutic groundwater, Water 12 (2020) 103. Doi: 10.3390/w12010103. Search in Google Scholar

13[13]. G. Ciotoli, M. Guerra, Distribution and physico-chemical data of Italian bottled natural mineral waters, Journal of Maps 12 (2016) 917–935. Doi: 10.1080/17445647.2015.1096846. Search in Google Scholar

14[14]. J.Đ. Cvejanov, B.D. Škrbić, Application of principal component and hierarchical cluster analyses in the classification of Serbian bottled waters and a comparison with waters from some other European countries, Journal of the Serbian Chemical Society 82 (2017) 711–721. Doi: 10.2298/JSC170219034C. Search in Google Scholar

15[15]. I.F. Barut, N. Erdogan, E. Basak, Hydrogeochemical evaluation of Western Anatolian mineral waters, Environmental Earth Sciences 45 (2004) 494–503. Doi: 10.1007/s00254-003-0904-0. Search in Google Scholar

16[16]. D. Bodiš, J. Kordik, I. Slaninka, P. Malík, P. Liščák, D. Panák, J. Božíková, D. Marcin, Mineral waters in Slovakia - Evaluation of chemical composition stability using both historical records and the most recent data, Journal of Geochemical Exploration 107 (2010) 382–390. Doi: 10.1016/j.gexplo.2010.06.009. Search in Google Scholar

17[17]. M.B. Rajković, I.D. Sredović, M.B. Račović, M.D. Stojanović, Analysis of quality mineral water of Serbia: Region Arandjelovac, Journal of Water Resource and Protection 4 (2012) 783–794. Doi: 10.4236/jwarp.2012.49090. Search in Google Scholar

18[18]. J.M. Carbajo, F. Maraver, Sulphurous mineral waters: new applications for health, Evidence-Based Complementary and Alternative Medicine (2017) 8034084. Doi:10.1155/2017/8034084. Search in Google Scholar

19[19]. J.C. Tapias, R. Melián, A. Sendrós, X. Font, A. Casas, Geochemical characterisation and health concerns of mineral bottled waters in Catalonia (North-Eastern Spain), Water 14 (2022) 3581. Doi: 10.3390/w14213581. Search in Google Scholar

20[20]. B.S. Frengstad, K. Lax, T. Tarvainen, Ø. Jæger, B.J. Wigum, The chemistry of bottled mineral and spring waters from Norway, Sweden, Finland and Iceland, Journal of Geochemical Exploration 107 (2010) 350–361. Doi: 10.1016/j.gexplo.2010.07.001. Search in Google Scholar

21[21]. L. Petraccia, G. Liberati, S.G. Masciullo, M. Grassi, A. Fraioli, Water, mineral waters and health, Clinical Nutrition 25 (2006) 377–385. Doi: 10.1016/j.clnu.2005.10.002. Search in Google Scholar

22[22]. K. Bodor, Z. Bodor, A. Szép, R. Szép, Classification and hierarchical cluster analysis of principal Romanian bottled mineral waters, Journal of Food Composition and Analysis 100 (2021) 103903. Doi: 10.1016/j.jfca.2021.103903. Search in Google Scholar

23[23]. Ordin nr. 116 din 27 ianuarie 2023 privind aprobarea Listei apelor minerale naturale recunoscute în România [Order no. 116 from January 27, 2023 regarding the approval of the List of natural mineral waters recognized in Romania.]. Bucharest, Romania: Agenţia Naţională pentru Resurse Minerale [National Agency for Mineral Resources]. Accessed February 11, 2023. https://lege5.ro/gratuit/geztgmbwgu2te/ordinulnr-116-2023-privind-aprobarea-listei-apelorminerale-naturale-recunoscute-in-romania. Search in Google Scholar

24[24]. A. Feru, Bottled natural mineral waters in Romania, Environmental Geology 46 (2004) 670–674. Doi: 10.1007/s00254-004-1006-3. Search in Google Scholar

25[25]. A. Feru, Ghidul apelor minerale naturale [Natural mineral water guide], Editura Novis [Novis Publishing House], Cluj Napoca, Romania, 2012 (in Romanian). Search in Google Scholar

26[26]. C. Munteanu, Ape minerale terapeutice [Therapeutic mineral waters], Editura Balneara [Balneara Publishing House], Bucharest, 2013 (in Romanian). Search in Google Scholar

27[27]. E. Berlescu, T. Chioreanu, E. Cociașu, A. Dene, T. Dinculescu, S. Ștefănescu, I. Tătăranu, Îndreptar pentru trimiteri la cura balneo-climaterică [Directory for referrals to balneo-climate therapy], Editura Medicala [Medical Publishing House], Bucharest, 1965, pp. 28–41 and pp. 172–173 (in Romanian). Search in Google Scholar

28[28]. A. Pricăjan, Apele minerale si termale din Romania [Mineral and thermal waters from Romania, Editura Tehnică [Technical Publishing House], Bucharest, 1972 (in Romanian). Search in Google Scholar

29[29]. O. Vaselli, A. Minissale, F. Tassi, G. Magro, I. Seghedi, D. Ioane, A. Szakacs, A geochemical traverse across the Eastern Carpathians (Romania): constraints on the origin and evolution of the mineral water and gas discharges, Chemical Geology 182 (2002) 637–654. Doi: 10.1016/S0009-2541(01)00348-5. Search in Google Scholar

30[30]. B.M. Kis, C. Baciu. The mineral waters from the Eastern Carpathians: a chemical review, Studia UBB Ambientum 59 (2014) 71-81. Search in Google Scholar

31[31]. H. Mitrofan, C. Marin, A. Tudorache, M. Vişan, Diagnosing non-meteorically induced variations in the chemistry of saline springs of the Vrancea seismic area (Romania), Pure and Applied Geophysics 171 (2014) 2315–2338. Doi: 10.1007/s00024-014-0810-2. Search in Google Scholar

32[32]. C. Stoica, Slănic-Moldova – “Perla” Carpaților Orientali [Slanic Moldova – “Pearl” of the Eastern Carpathians], Editura Magic Print [Magic Print Publishing House], Onesti, 2021 (in Romanian). Search in Google Scholar

33[33]. City Hall of Slănic Moldova, https://primariaslanicmoldova.ro/izvoareleminerale/ (accessed February 24, 2023). Search in Google Scholar

34[34]. H.G. nr. 532 din 2 iunie 2010 privind modificarea şi completarea Normelor tehnice de exploatare şi comercializare a apelor minerale naturale, aprobate prin Hotărârea Guvernului nr. 1.020/2005 [Decision no. 532 of 2 June 2010 amending and supplementing the technical norms of exploitation and marketing of natural mineral waters, approved by Government Decision no. 1020/2005]. Bucharest, Romania: Monitorul Oficial nr. 400 din 16 iunie 2010 [Published in the Official Gazette no. 400 of June 16, 2010]. Accessed January 11, 2023. http://www.namr.ro/legislation/romanian-legislation/water-domain. Search in Google Scholar

35[35]. World Health Organization (WHO), Guidelines for Drinking-Water Quality, 4th edition, incorporating the 1st addendum (World Health Organization, Geneva, 2017). https://www.who.int/publications/i/item/9789241549950 (accessed Jan. 11, 2023). Search in Google Scholar

36[36]. L. Varga, Bacteriological quality of bottled natural mineral waters commercialized in Hungary, Food Control 22 (2011) 591–595. Doi: 10.1016/j.foodcont.2010.10.009. Search in Google Scholar

37[37]. H. Leclerc, A. Moreau, Microbiological safety of natural mineral water, FEMS Microbiology Reviews 26 (2002) 207–222. Doi: 10.1111/j.1574-6976.2002.tb00611.x. Search in Google Scholar

38[38]. E.M. Carstea, E.A. Levei, M.A. Hoaghia, R. Savastru, Quality assessment of Romanian bottled mineral water and tap water, Environmental Monitoring and Assessment 188 (2016) 521. Doi: 10.1007/s10661-016-5531-9. Search in Google Scholar

39[39]. M. Birke, C. Reimann, A. Demetriades, U. Rauch, H. Lorenz, B. Harazim, W. Glatte, Determination of major and trace elements in European bottled mineral water - Analytical methods, Journal of Geochemical Exploration 107 (2010) 217–226. Doi: 10.1016/j.gexplo.2010.05.005. Search in Google Scholar

40[40]. L. Misăilă, N. Bârsan, F. M. Nedeff, D. Răducanu, L. Grosu, O.I. Patriciu, L. Gavrilă, A.L. Fînaru, Quality assessment of Slanic-Moldova mineral waters stored in reusable bottles, Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry 21 (2020) 253–262. Search in Google Scholar

41[41]. A. Versari, G.P. Parpinello, S. Galassi, Chemometric survey of Italian bottled mineral waters by means of their labelled physico-chemical and chemical composition, Journal of Food Composition and Analysis 15 (2002) 251–264. Doi: 10.1006/jfca.2002.1058. Search in Google Scholar

42[42]. D. Bodiš, J. Božíková, D. Mackových, Mineral waters of the Slovak spas - Chemical analysis, history and present, Slovak Geological Magazine 16 (2016) 41–56. Search in Google Scholar

43[43]. L. Misaila, N. Barsan, F.M. Nedeff, D. Raducanu, C. Radu, L. Grosu, O.I. Patriciu, L. Gavrila, A.L. Finaru, Perspectives for quality evaluation of some mineral waters from Slanic Moldova, Water 14 (2022) 2942. Doi: 10.3390/w14192942. Search in Google Scholar

44[44]. L. Misăilă, D. Răducanu, N. Bârsan, L. Grosu, O.I. Patriciu, L. Gavrilă, A.L. Fînaru, Microbiological quality assessment of some mineral waters from Slanic Moldova, Book of Abstract of XXXVI National Chemistry Conference (CNChim-2022), Călimăneşti-Căciulata, România, 2022. Search in Google Scholar

45[45]. A.D. Eaton, L.S. Clesceri, E.W. Rice, A.W. Greenberg, Standard Methods for the Examination of Water and Wastewater, 21st ed., American Public Health Association (APHA) Press, Washington, DC, 2005. Search in Google Scholar

46[46]. SR EN ISO 10523:2012, Water Quality - Determination of pH, Romanian Association for Standardization (ASRO), Bucharest, 2012. Search in Google Scholar

47[47]. SR EN 27888:1997, Water Quality - Determination of Electrical Conductivity, Romanian Association for Standardization (ASRO), Bucharest, 1997. Search in Google Scholar

48[48]. ISO 17294-1:2004, Water Quality - Application of Inductively Coupled Plasma Mass Spectrometry (ICP-MS) - Part 1: General Guidelines, International Organization of Standardization (ISO), Geneva, 2004. Search in Google Scholar

49[49]. HACH DR 3900 UV-Vis Spectrophotometer Procedures Manual, HACH Company Loveland, Colorado, 2018. Search in Google Scholar

50[50]. Commission Directive 2003/40/EC of 16 May 2003 establishing the list, concentration limits and labelling requirements for the constituents of natural mineral waters and the conditions for using ozone-enriched air for the treatment of natural mineral waters and spring waters (Official Journal of the European Union, 22.05.2003, L 126, 34-39, http://data.europa.eu/eli/dir/2003/40/oj). Search in Google Scholar

51[51]. Commission Directive 2009/90/EC of 31 July 2009 laying down, pursuant to Directive 2000/60/EC of the European Parliament and of the Council, technical specifications for chemical analysis and monitoring of water status (Official Journal of the European Union, 1.8.2009, L 201, 36-38 http://data.europa.eu/eli/dir/2009/90/oj). Search in Google Scholar

52[52]. J.P. Verma, Data Analysis in Management with SPSS Software, Springer, New York, 2013, pp. 321–362. Doi: 10.1007/978-81-322-0786-3. Search in Google Scholar

53[53]. A. Haldun, User’s guide to correlation coefficients, Turkish Journal of Emergency Medicine 18 (2018) 91–93. Doi: 10.1016/j.tjem.2018.08.001. Search in Google Scholar

54[54]. Y. Yang, W. Xu, J. Chen, Q. Chen, Z. Pan, Hydrochemical characteristics and groundwater quality assessment in the diluvial fan of Gaoqiao, Emei Mountain, China, Sustainability 10 (2018) 4507. Doi: 10.3390/su10124507. Search in Google Scholar

55[55]. L. Misăilă, F.M. Nedeff, N. Barsan, L. Grosu, O.I. Patriciu, L. Gavrilă, A.L. Fînaru, WATERSHED - Android application for the mineral waters classification, Revista de Chimie 70 (2019) 2212–2217. Doi: 10.37358/RC.19.6.7307. Search in Google Scholar

56[56]. H. Adamou, B. Ibrahim, S. Salack, R. Adamou, S. Sanfo, S. Liersch, Physico-chemical and bacteriological quality of groundwater in a rural area of Western Niger: a case study of Bonkoukou, Journal of Water and Health 18 (2020) 77–90. Doi: 10.2166/wh.2020.082. Search in Google Scholar

57[57]. Romanian National Agency for Mineral Resources, Order no. 87 of May 20, 2008 for the approval of technical instructions on the classification and assessment of resources/reserves of natural mineral water, therapeutic mineral water, geothermal water, accompanying gases and non-combustible gases (Official Gazette, Bucharest, 2008, http://www.namr.ro/legislation/romanian-legislation/water-domain) (in Romanian). Search in Google Scholar