<abstract xmlns="http://www.w3.org/1999/xhtml">Three new nitrosalicylatocopper(II) complexes have been prepared and characterized. Compounds of the composition Cu(5-NSal)2(2-ampy)2 (1), Cu(5-NSal)2(2-hmpy)2 (2) and Cu(3,5-DNSal)2(2-hmpy)2 (3), where 2-ampy = (2-aminomethyl)pyridine, 2-hmpy = (2-hydroxymethyl)pyridine, 5-NSal = 5-nitrosalicylate anion and 3,5-DNSal = 3,5-dinitrosalicylate anion, were characterized by elemental analyses, EPR and IR spectroscopy. EPR spectra are consistent with the dx2-y2ground electronic state. Spectral properties have shown “classic” monodentate coordination of 5-nitrosalicylate anion. Similarly, bonding mode of the 3,5‑dinitrosalicylate anion in (3) is assumed to be unidentate via the carboxyl group, which is surprising compared with the previously studied complex, where the preferred coordination via the phenolate group anion was observed.</abstract>

Three new nitrosalicylatocopper(II) complexes have been prepared and characterized. Compounds of the composition Cu(5-NSal)2(2-ampy)2 (1), Cu(5-NSal)2(2-hmpy)2 (2) and Cu(3,5-DNSal)2(2-hmpy)2 (3), where 2-ampy = (2-aminomethyl)pyridine, 2-hmpy = (2-hydroxymethyl)pyridine, 5-NSal = 5-nitrosalicylate anion and 3,5-DNSal = 3,5-dinitrosalicylate anion, were characterized by elemental analyses, EPR and IR spectroscopy. EPR spectra are consistent with the dx2-y2ground electronic state. Spectral properties have shown “classic” monodentate coordination of 5-nitrosalicylate anion. Similarly, bonding mode of the 3,5‑dinitrosalicylate anion in (3) is assumed to be unidentate via the carboxyl group, which is surprising compared with the previously studied complex, where the preferred coordination via the phenolate group anion was observed.

Nitrosalicylatocopper(II) complexes with chelating pyridine derivatives

Acta Chimica Slovaca

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

{"article-title":"Nitrosalicylatocopper(II) complexes with chelating pyridine derivatives"}

Three new nitrosalicylatocopper(II) complexes have been prepared and characterized. Compounds of the composition Cu(5-NSal)2(2-ampy)2 (1), Cu(5-NSal)2(2-hmpy)2...

Nitrosalicylatocopper(II) complexes with chelating pyridine derivatives

Publié en ligne: 06 juil. 2018

Pages: 21 - 25

DOI: https://doi.org/10.2478/acs-2018-0004

Mots clés
nitrosalicylatocopper(II) complexes, (2-aminomethyl)pyridine, (2-hydroxymethyl)pyridine, spectral properties

© 2018 Flóra Jozefíková, published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Nitrosalicylatocopper(II) complexes with chelating pyridine derivatives

Publié en ligne: 06 juil. 2018

Pages: 21 - 25

DOI: https://doi.org/10.2478/acs-2018-0004

Mots clésnitrosalicylatocopper(II) complexes, (2-aminomethyl)pyridine, (2-hydroxymethyl)pyridine, spectral properties

© 2018 Flóra Jozefíková, published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Mots clés
nitrosalicylatocopper(II) complexes, (2-aminomethyl)pyridine, (2-hydroxymethyl)pyridine, spectral properties