<abstract xmlns="http://www.w3.org/1999/xhtml"> A new colorimetric detector tube for the detection of trace concentrations of nitrite in water was developed. The detector tube is based on a diazo coupling reaction of nitrite with dapsone and N-(1-naphthyl) ethylenediamine dihydrochloride during the formation of red-violet azo dye. Spherical granules (pellets) made from the composite material were used as the carrier of chemical reagents. They were prepared by pelletizing the mixture of microcrystalline cellulose, lactose, kaolin and polyvinylpyrrolidone. Colouring is done on a layer of silica gel impregnated with citric acid. The detector tube is highly sensitive, selective and stable when stored. The detection limit is 0.1 μg.ml-1, i.e. 0.03 μg.ml-1 N(NO2 -). The optimal measuring range of nitrite concentration in the analyzed sample ranges from 0.5 to 80 μg.ml-1, i.e. 0.15-24.36 μg.ml-1 N(NO2 -). The detector tube can easily be structurally modified for analysis of nitrates with a detection limit of 1 μg/ml-1, i.e. 0.23 μg.ml-1 N(NO3 -).</abstract>

A new colorimetric detector tube for the detection of trace concentrations of nitrite in water was developed. The detector tube is based on a diazo coupling reaction of nitrite with dapsone and N-(1-naphthyl) ethylenediamine dihydrochloride during the formation of red-violet azo dye. Spherical granules (pellets) made from the composite material were used as the carrier of chemical reagents. They were prepared by pelletizing the mixture of microcrystalline cellulose, lactose, kaolin and polyvinylpyrrolidone. Colouring is done on a layer of silica gel impregnated with citric acid. The detector tube is highly sensitive, selective and stable when stored. The detection limit is 0.1 μg.ml-1, i.e. 0.03 μg.ml-1 N(NO2 -). The optimal measuring range of nitrite concentration in the analyzed sample ranges from 0.5 to 80 μg.ml-1, i.e. 0.15-24.36 μg.ml-1 N(NO2 -). The detector tube can easily be structurally modified for analysis of nitrates with a detection limit of 1 μg/ml-1, i.e. 0.23 μg.ml-1 N(NO3 -).

New detector tube for the detection of nitrite in water

Oritest spol. s r.o., Staropramenná 17, 15000 Praha, Czech Republic

NBC Defence Institute (Vyškov), University of Defence, Kounicova 65, 66200 Brno, Czech Republic

Faculty of Pharmacy, Veterinary and Pharmaceutical University Brno, Palackého 1-3, 61200 Brno, Czech Republic

Acta Chimica Slovaca

{"article-title":"New detector tube for the detection of nitrite in water"}

A new colorimetric detector tube for the detection of trace concentrations of nitrite in water was developed. The detector tube is based on a diazo coupling...

New detector tube for the detection of nitrite in water

Publié en ligne: 22 mai 2013

Pages: 100 - 105

DOI: https://doi.org/10.2478/acs-2013-0016

Mots clés
detector tube, composite carrier, dapsone, N-(1-naphthyl) ethylenediamine dihydrochloride

This content is open access.

New detector tube for the detection of nitrite in water

Publié en ligne: 22 mai 2013

Pages: 100 - 105

DOI: https://doi.org/10.2478/acs-2013-0016

Mots clésdetector tube, composite carrier, dapsone, N-(1-naphthyl) ethylenediamine dihydrochloride

This content is open access.

Mots clés
detector tube, composite carrier, dapsone, N-(1-naphthyl) ethylenediamine dihydrochloride