<abstract xmlns="http://www.w3.org/1999/xhtml">This work presents the studies on the oxidation of limonene with hydrogen peroxide and tert-butyl hydroperoxide (TBHP) in the presence of : TS-2, Ti-Beta, Ti-MCM-41 and Ti-MWW catalysts, at the autogenic pressure and atmospheric pressure. The examination were performed at the following conditions: the temperature of 140°C (studies in the autoclave) and 80°C (studies in glass reactor), the molar ratio of limonene/oxidant (H2O2 or WNTB) = 1:1, the methanol concentration 80 wt%, the catalyst content 3 wt%, the reaction time 3 h and the intensity of stirring 500 rpm. The analysis of the results showed that in process not only 1,2-epoxylimonene was formed but also: 1,2-epoxylimonene diol, carveol, carvone and perillyl alcohol but for 1,2-epoxylimonene obtaining the better method was the method at the autogenic pressure and in the presence of TBHP.</abstract>

This work presents the studies on the oxidation of limonene with hydrogen peroxide and tert-butyl hydroperoxide (TBHP) in the presence of : TS-2, Ti-Beta, Ti-MCM-41 and Ti-MWW catalysts, at the autogenic pressure and atmospheric pressure. The examination were performed at the following conditions: the temperature of 140°C (studies in the autoclave) and 80°C (studies in glass reactor), the molar ratio of limonene/oxidant (H2O2 or WNTB) = 1:1, the methanol concentration 80 wt%, the catalyst content 3 wt%, the reaction time 3 h and the intensity of stirring 500 rpm. The analysis of the results showed that in process not only 1,2-epoxylimonene was formed but also: 1,2-epoxylimonene diol, carveol, carvone and perillyl alcohol but for 1,2-epoxylimonene obtaining the better method was the method at the autogenic pressure and in the presence of TBHP.

The oxidation of limonene at raised pressure and over the various titanium-silicate catalysts

West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

This work presents the studies on the oxidation of limonene with hydrogen peroxide and tert-butyl hydroperoxide (TBHP) in the presence of : TS-2, Ti-Beta,...

The oxidation of limonene at raised pressure and over the various titanium-silicate catalysts

Publié en ligne: 27 nov. 2015

Pages: 82 - 87

DOI: https://doi.org/10.1515/pjct-2015-0072

Mots clés
limonene oxidation, hydrogen peroxide, TBHP

© 2015 Agnieszka Wróblewska et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

The oxidation of limonene at raised pressure and over the various titanium-silicate catalysts

Publié en ligne: 27 nov. 2015

Pages: 82 - 87

DOI: https://doi.org/10.1515/pjct-2015-0072

Mots cléslimonene oxidation, hydrogen peroxide, TBHP

© 2015 Agnieszka Wróblewska et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mots clés
limonene oxidation, hydrogen peroxide, TBHP