<abstract xmlns="http://www.w3.org/1999/xhtml">A carbon-based solid acid catalyst was prepared by the sulfonation of carbonized seed shells of <italic>Jatropha curcas</italic> (<italic>J. curcas</italic> L.). The structure of amorphous carbon consisting of polycyclic aromatic carbon sheets attached a high density of acidic SO3H groups (2.0 mmol · g−1) was identified with scanning electron microscopy (SEM), fourier transform infrared (FTIR) spectroscopy, powder X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The performance of the solid acid catalyst was evaluated for biodiesel production in the esterification of oleic acid with methanol. 95.7% yield of biodiesel was obtained after 2 h reaction and the conversions with reused catalyst varied in the range of 95.7% to 95.1%, showing better activity and stability than commercial catalyst amberlyst-46. It was also observed that the prepared catalyst showed enhanced activity in the transesterification of triolein with methanol when compared with other solid acid catalysts. A synergistic effect results from the high density of SO3H groups and the good access of reactants to the acidic sites can be used to explain the excellent catalytic activity, as well as the strong affinity between the hydrophilic reactants and the neutral OH groups bonded to the polycyclic aromatic carbon rings.</abstract>

A carbon-based solid acid catalyst was prepared by the sulfonation of carbonized seed shells of Jatropha curcas (J. curcas L.). The structure of amorphous carbon consisting of polycyclic aromatic carbon sheets attached a high density of acidic SO3H groups (2.0 mmol · g−1) was identified with scanning electron microscopy (SEM), fourier transform infrared (FTIR) spectroscopy, powder X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The performance of the solid acid catalyst was evaluated for biodiesel production in the esterification of oleic acid with methanol. 95.7% yield of biodiesel was obtained after 2 h reaction and the conversions with reused catalyst varied in the range of 95.7% to 95.1%, showing better activity and stability than commercial catalyst amberlyst-46. It was also observed that the prepared catalyst showed enhanced activity in the transesterification of triolein with methanol when compared with other solid acid catalysts. A synergistic effect results from the high density of SO3H groups and the good access of reactants to the acidic sites can be used to explain the excellent catalytic activity, as well as the strong affinity between the hydrophilic reactants and the neutral OH groups bonded to the polycyclic aromatic carbon rings.

Carbon-based acid catalyst from waste seed shells: preparation and characterization

Tianjin Modern Vocational Technology College, Department of Biochemical Engineering, Tianjin 300350, China

Chendu Vocational College of Agricultural Science and Technology, Chendu 611000, China

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

A carbon-based solid acid catalyst was prepared by the sulfonation of carbonized seed shells of Jatropha curcas (J. curcas L.). The structure of amorphous...

Carbon-based acid catalyst from waste seed shells: preparation and characterization

Publié en ligne: 27 nov. 2015

Pages: 37 - 41

DOI: https://doi.org/10.1515/pjct-2015-0066

Mots clés
carbon-based solid acid, waste seed shells, esterification, transesterification, biodiesel

© 2015 Li H. Wang et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Carbon-based acid catalyst from waste seed shells: preparation and characterization

Publié en ligne: 27 nov. 2015

Pages: 37 - 41

DOI: https://doi.org/10.1515/pjct-2015-0066

Mots cléscarbon-based solid acid, waste seed shells, esterification, transesterification, biodiesel

© 2015 Li H. Wang et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mots clés
carbon-based solid acid, waste seed shells, esterification, transesterification, biodiesel