<abstract xmlns="http://www.w3.org/1999/xhtml"> Reprocessing of spent nuclear fuel usually employs the solvent extraction technique to recover fissile material, isolate other valuable radionuclides, recover precious metals, and remove contaminants. Efficient recovery of these species from highly radioactive solutions requires a detailed understanding of reaction conditions and metal speciation that leads to their isolation in pure forms. Due to the complex nature of these systems, identification of ideal reaction conditions for the efficient extraction of specific metals can be challenging. Thus, the development of experimental approaches that have the potential to reduce the number of experiments required to identify ideal conditions are desirable. In this study, a full-factorial experimental design was used to identify the main effects and variable interactions of three chemical parameters on the extraction of protactinium (Pa). Specifically we investigated the main effects of the anion concentration (NO3-, Cl-) extractant concentration, and solution acidity on the overall extraction of protactinium by 2,6-dimethyl-4-heptanol (diisobutylcarbinol; DIBC) from both HCl and HNO3 solutions. Our results indicate that in HCl, the extraction of protactinium was dominated by the solution acidity, while in nitric acid the extraction was strongly effected by the [DIBC]. Based on our results, a mathematical model was derived, that describes the relationship between concentrations of anions, extractant, and solution acidity and the expected values of Pa distribution coefficients in both HCl and HNO3. This study demonstrates the potential to predict the distribution coefficient values, based upon a mathematical model generated by a full-factorial experimental design.</abstract>

Reprocessing of spent nuclear fuel usually employs the solvent extraction technique to recover fissile material, isolate other valuable radionuclides, recover precious metals, and remove contaminants. Efficient recovery of these species from highly radioactive solutions requires a detailed understanding of reaction conditions and metal speciation that leads to their isolation in pure forms. Due to the complex nature of these systems, identification of ideal reaction conditions for the efficient extraction of specific metals can be challenging. Thus, the development of experimental approaches that have the potential to reduce the number of experiments required to identify ideal conditions are desirable. In this study, a full-factorial experimental design was used to identify the main effects and variable interactions of three chemical parameters on the extraction of protactinium (Pa). Specifically we investigated the main effects of the anion concentration (NO3-, Cl-) extractant concentration, and solution acidity on the overall extraction of protactinium by 2,6-dimethyl-4-heptanol (diisobutylcarbinol; DIBC) from both HCl and HNO3 solutions. Our results indicate that in HCl, the extraction of protactinium was dominated by the solution acidity, while in nitric acid the extraction was strongly effected by the [DIBC]. Based on our results, a mathematical model was derived, that describes the relationship between concentrations of anions, extractant, and solution acidity and the expected values of Pa distribution coefficients in both HCl and HNO3. This study demonstrates the potential to predict the distribution coefficient values, based upon a mathematical model generated by a full-factorial experimental design.

A calculation model for liquid-liquid extraction of protactinium by 2,6-dimethyl-4-heptanol

Department of Chemistry, E373 CB, The University of Iowa, Iowa City, IA 52246, USA

Interdisciplinary Human Toxicology Program, E373 CB, The University of Iowa, Iowa City, IA 2246, USA

Department of Chemistry, E373 CB, The University of Iowa, Iowa City, IA 52246, USA and Interdisciplinary Human Toxicology Program, E373 CB, The University of Iowa, IA 52246, USA and Departments of Radiology and Radiation Oncology (Free Radical and Radiation Biology Program), The University of Iowa, ML B180 FRRB, 500 Newton Road, Iowa City, IA 52246, USA, Tel.: +1 319 335-8017

Nukleonika

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Reprocessing of spent nuclear fuel usually employs the solvent extraction technique to recover fissile material, isolate other valuable radionuclides, recover...

A calculation model for liquid-liquid extraction of protactinium by 2,6-dimethyl-4-heptanol

Publié en ligne: 30 déc. 2015

Pages: 837 - 845

Reçu: 01 juil. 2015

Accepté: 26 sept. 2015

DOI: https://doi.org/10.1515/nuka-2015-0154

Mots clés
design of experiments, protactinium, solvent extraction

© by Michael K. Schultz

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

A calculation model for liquid-liquid extraction of protactinium by 2,6-dimethyl-4-heptanol

Publié en ligne: 30 déc. 2015

Pages: 837 - 845

Reçu: 01 juil. 2015

Accepté: 26 sept. 2015

DOI: https://doi.org/10.1515/nuka-2015-0154

Mots clésdesign of experiments, protactinium, solvent extraction

© by Michael K. Schultz

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Mots clés
design of experiments, protactinium, solvent extraction