<abstract xmlns="http://www.w3.org/1999/xhtml">Gadolinium doped barium cerate (BCG) electrolytes Ce0.8Gd0.2O1.9 + xBaO (x = 0.1 and 0.4) were prepared by wet chemical method for the use in solid oxide fuel cells operating at intermediate temperatures (600 °C to 800 °C). The as-prepared powder sample was calcined at 900 °C. The calcination temperature was identified using differential scanning calorimetry (DSC) analysis. The orthorhombic perovskite phase formation was confirmed by XRD analysis. From TEM results, the particle size was found to be about 32 nm which is in a good agreement with XRD results. BCG nanoparticles were formed at lower sintering temperature due to using microwave furnace. By reducing the sintering temperature of solid electrolyte through microwave technique, the percentage of barium loss was successfully reduced and the prepared electrolyte can be a good choice for solid oxide fuel cells operating at intermediate temperatures.</abstract>

Gadolinium doped barium cerate (BCG) electrolytes Ce0.8Gd0.2O1.9 + xBaO (x = 0.1 and 0.4) were prepared by wet chemical method for the use in solid oxide fuel cells operating at intermediate temperatures (600 °C to 800 °C). The as-prepared powder sample was calcined at 900 °C. The calcination temperature was identified using differential scanning calorimetry (DSC) analysis. The orthorhombic perovskite phase formation was confirmed by XRD analysis. From TEM results, the particle size was found to be about 32 nm which is in a good agreement with XRD results. BCG nanoparticles were formed at lower sintering temperature due to using microwave furnace. By reducing the sintering temperature of solid electrolyte through microwave technique, the percentage of barium loss was successfully reduced and the prepared electrolyte can be a good choice for solid oxide fuel cells operating at intermediate temperatures.

Structural and morphological analysis of barium cerate electrolyte for SOFC application

Ceramic Processing Lab, Department of Physics

Materials Science-Poland

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Gadolinium doped barium cerate (BCG) electrolytes Ce0.8Gd0.2O1.9 + xBaO (x = 0.1 and 0.4) were prepared by wet chemical method for the use in solid oxide fuel...

Structural and morphological analysis of barium cerate electrolyte for SOFC application

Publié en ligne: 24 févr. 2017

Pages: 120 - 125

Reçu: 04 mai 2016

Accepté: 04 janv. 2017

DOI: https://doi.org/10.1515/msp-2017-0021

Mots clés
BCG nanoparticles, co-precipitation, microwave sintering, solid oxide fuel cell (SOFC)

© 2017 A. Senthil Kumar, R. Balaji, P. Puviarasu, S. Jayakumar

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Structural and morphological analysis of barium cerate electrolyte for SOFC application

Publié en ligne: 24 févr. 2017

Pages: 120 - 125

Reçu: 04 mai 2016

Accepté: 04 janv. 2017

DOI: https://doi.org/10.1515/msp-2017-0021

Mots clésBCG nanoparticles, co-precipitation, microwave sintering, solid oxide fuel cell (SOFC)

© 2017 A. Senthil Kumar, R. Balaji, P. Puviarasu, S. Jayakumar

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Mots clés
BCG nanoparticles, co-precipitation, microwave sintering, solid oxide fuel cell (SOFC)