<abstract xmlns="http://www.w3.org/1999/xhtml"><p>A new technological approach to the synthesis of multilayer nanostructures which allows their use in high-performance storage of electrical energy at the nanoscale level is discussed in this paper. In particular, the effect of co-intercalation of histidine (his), water and a solution of KOH into layered semiconductors of GaSe and InSe on the charge accumulation are studied. Based on the data of the cyclic current-voltage characteristics (CVC) a power storage mechanism (capacitive/pseudocapacitive) in each of these structures is described. This mechanism is in a good accord with the results of galvanostatic studies. The simulation of the parameters of the impedance equivalent circuit has been carried out, proving the possibility of using the described structures for nanoelectronics and nanoenergy devices. The observed values of tangent of electrical losses tgδ (&lt;1) in coherence with a high dielectric constant ε are promising for the creation of quantum batteries and capacitors.</p></abstract>

A new technological approach to the synthesis of multilayer nanostructures which allows their use in high-performance storage of electrical energy at the nanoscale level is discussed in this paper. In particular, the effect of co-intercalation of histidine (his), water and a solution of KOH into layered semiconductors of GaSe and InSe on the charge accumulation are studied. Based on the data of the cyclic current-voltage characteristics (CVC) a power storage mechanism (capacitive/pseudocapacitive) in each of these structures is described. This mechanism is in a good accord with the results of galvanostatic studies. The simulation of the parameters of the impedance equivalent circuit has been carried out, proving the possibility of using the described structures for nanoelectronics and nanoenergy devices. The observed values of tangent of electrical losses tgδ (<1) in coherence with a high dielectric constant ε are promising for the creation of quantum batteries and capacitors.

The impact of phase state of guest histidine on properties and practical applications of nanohybrids on InSe and GaSe basis

Materials Science-Poland

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

A new technological approach to the synthesis of multilayer nanostructures which allows their use in high-performance storage of electrical energy at the...

The impact of phase state of guest histidine on properties and practical applications of nanohybrids on InSe and GaSe basis

Publié en ligne: 29 avr. 2017

Pages: 239 - 245

Reçu: 22 juin 2016

Accepté: 23 déc. 2016

DOI: https://doi.org/10.1515/msp-2017-0019

Mots clés
histidine intercalation, impedance spectroscopy, negative capacitance, quantum batteries

© 2017 F.O. Ivashchyshyn, I.I. Grygorchak, O.V. Balaban, B.O. Seredyuk

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

The impact of phase state of guest histidine on properties and practical applications of nanohybrids on InSe and GaSe basis

Publié en ligne: 29 avr. 2017

Pages: 239 - 245

Reçu: 22 juin 2016

Accepté: 23 déc. 2016

DOI: https://doi.org/10.1515/msp-2017-0019

Mots cléshistidine intercalation, impedance spectroscopy, negative capacitance, quantum batteries

© 2017 F.O. Ivashchyshyn, I.I. Grygorchak, O.V. Balaban, B.O. Seredyuk

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Mots clés
histidine intercalation, impedance spectroscopy, negative capacitance, quantum batteries