<abstract xmlns="http://www.w3.org/1999/xhtml">Organic-inorganic nano-CoFe2O4/PANI (polyaniline) multi-core/shell composites have been successfully synthesized by chemical oxidative polymerization of aniline. The characterization results showed that the ferrite nanocrystals were efficiently embedded in PANI. The electromagnetic parameters of the composites were measured by a vector network analyser in the frequency range of 2 GHz to 18 GHz. Double-layer absorbers based on the CoFe2O4/PANI composite (matching layer) and calcined CoFe2O4 ferrite (absorbing layer) have been designed. The reflection loss of the microwave absorbers of both single layer and double-layer with a total thickness of 2.0 mm and 2.5 mm was calculated according to transmission-line theory. The results indicated that the minimum reflection loss of the CoFe2O4/PANI composite was −19.0 dB at 16.2 GHz at the thickness of 2.0 mm and −23.6 dB at 13.1 GHz at the thickness of 2.5 mm, respectively. The minimum reflection loss for double-layer absorbers reached −28.8 dB at 16.2 GHz at the total thickness of 2.0 mm, and −31.1 dB at 12.8 GHz at the total thickness of 2.5 mm. The absorption bandwidth under −10 dB was 4.2 GHz (13.8 GHz to 18.0 GHz) and 5.5 GHz (10.3 GHz to 15.8 GHz), respectively. The results show that the reflection loss and absorption bandwidth of the double-layer absorbers are obviously enhanced compared to corresponding single layer absorbers.</abstract>

Organic-inorganic nano-CoFe2O4/PANI (polyaniline) multi-core/shell composites have been successfully synthesized by chemical oxidative polymerization of aniline. The characterization results showed that the ferrite nanocrystals were efficiently embedded in PANI. The electromagnetic parameters of the composites were measured by a vector network analyser in the frequency range of 2 GHz to 18 GHz. Double-layer absorbers based on the CoFe2O4/PANI composite (matching layer) and calcined CoFe2O4 ferrite (absorbing layer) have been designed. The reflection loss of the microwave absorbers of both single layer and double-layer with a total thickness of 2.0 mm and 2.5 mm was calculated according to transmission-line theory. The results indicated that the minimum reflection loss of the CoFe2O4/PANI composite was −19.0 dB at 16.2 GHz at the thickness of 2.0 mm and −23.6 dB at 13.1 GHz at the thickness of 2.5 mm, respectively. The minimum reflection loss for double-layer absorbers reached −28.8 dB at 16.2 GHz at the total thickness of 2.0 mm, and −31.1 dB at 12.8 GHz at the total thickness of 2.5 mm. The absorption bandwidth under −10 dB was 4.2 GHz (13.8 GHz to 18.0 GHz) and 5.5 GHz (10.3 GHz to 15.8 GHz), respectively. The results show that the reflection loss and absorption bandwidth of the double-layer absorbers are obviously enhanced compared to corresponding single layer absorbers.

Double-layer microwave absorber based on nanocrystalline CoFe2O4 and CoFe2O4/PANI multi-core/shell composites

School of Physics and Optoelectronic Engineering

Materials Science-Poland

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Double-layer microwave absorber based on nanocrystalline CoFeO and CoFeO/PANI multi-core/shell composites

Organic-inorganic nano-CoFe2O4/PANI (polyaniline) multi-core/shell composites have been successfully synthesized by chemical oxidative polymerization of...

Double-layer microwave absorber based on nanocrystalline CoFe₂O₄ and CoFe₂O₄/PANI multi-core/shell composites

Publié en ligne: 24 févr. 2017

Pages: 94 - 104

Reçu: 23 janv. 2016

Accepté: 30 nov. 2016

DOI: https://doi.org/10.1515/msp-2017-0010

Mots clés
cobalt ferrite, polyaniline, double-layer absorber, reflection loss

© 2017 Yewen Xu, Guozhu Shen, Hongyan Wu, Bin Liu, Xumin Fang, Ding Zhang, Jun Zhu

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Double-layer microwave absorber based on nanocrystalline CoFe2O4 and CoFe2O4/PANI multi-core/shell composites

Publié en ligne: 24 févr. 2017

Pages: 94 - 104

Reçu: 23 janv. 2016

Accepté: 30 nov. 2016

DOI: https://doi.org/10.1515/msp-2017-0010

Mots cléscobalt ferrite, polyaniline, double-layer absorber, reflection loss

© 2017 Yewen Xu, Guozhu Shen, Hongyan Wu, Bin Liu, Xumin Fang, Ding Zhang, Jun Zhu

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Double-layer microwave absorber based on nanocrystalline CoFe₂O₄ and CoFe₂O₄/PANI multi-core/shell composites

Mots clés
cobalt ferrite, polyaniline, double-layer absorber, reflection loss