Feed composition M1 | Conversion [%] | Integral value | C = Im/Ia | Copolymer composition m1 | |
---|---|---|---|---|---|
Im | Ia | ||||
0.15 | 7.6 | 3.34 | 9.63 | 0.3468 | 0.24 |
0.30 | 10.3 | 0.88 | 1.13 | 0.6616 | 0.36 |
0.50 | 14.2 | 1.73 | 1.64 | 1.0548 | 0.59 |
0.70 | 8.7 | 2.31 | 9.77 | 0.2364 | 0.82 |
0.85 | 11.8 | 1.64 | 7.29 | 0.2249 | 0.91 |
Feed composition M1 | Conversion [%] | Integral value | C = Ia/Ie | Copolymer composition m1 | |
---|---|---|---|---|---|
Ia | Ie | ||||
0.15 | 11.5 | 9.98 | 2.25 | 4.44 | 0.27 |
0.30 | 15.6 | 5.35 | 0.94 | 5.69 | 0.47 |
0.50 | 13.2 | 6.14 | 1.02 | 6.82 | 0.57 |
0.70 | 17.2 | 1.31 | 0.12 | 10.91 | 0.75 |
0.85 | 9.3 | 4.13 | 0.21 | 19.66 | 0.86 |
Polymer | TGA | Molecular weight | UV data | ||||
---|---|---|---|---|---|---|---|
1st [°C] | 2nd [°C] | Mn × 103 | Mw × 103 | Mw/Mn | Ar. C=C | Vinyl C=C | |
Poly(DCP) | 315 | 430 | 1.9 | 2.9 | 1.8 | 265 | 315 |
Poly(DCP-co-HEA) | 330 | 440 | 2.5 | 3.8 | 1.6 | 260 | 315 |
Poly(DCP-co-S) | 320 | 430 | 1.9 | 3.1 | 1.7 | 260 | 315 |
Polymer | Method | r1 | r2 | r1.r2 |
---|---|---|---|---|
FR | 1.53±0.10 | 0.76±0.16 | 1.16 | |
Poly(DCP-co-HEA) | KT | 1.67±0.13 | 0.58±0.05 | 0.96 |
ex-KT | 1.65±0.13 | 0.6±0.08 | 0.99 | |
FR | 1.1±0.06 | 0.66±0.16 | 0.73 | |
Poly(DCP-co-S) | KT | 1.25±0.16 | 0.45±0.13 | 0.56 |
ex-KT | 1.31±0.11 | 0.49±0.16 | 0.64 |
I.T | Poly(DCP) | Poly(DCP-co-HEA) | Poly(DCP-co-S) | |||
---|---|---|---|---|---|---|
A (310 nm) | C [%] | A (316 nm) | C [%] | A (312 nm) | C [%] | |
0 | 1.709 | 0 | 0.804 | 0 | 2.703 | 0 |
60 | 1.608 | 5.9 | 0.695 | 13.5 | 2.641 | 2.2 |
180 | 1.532 | 10.3 | 0.671 | 16.5 | 2.402 | 11.1 |
300 | 1.468 | 14.1 | 0.644 | 19.9 | 2.130 | 21.2 |
600 | 1.286 | 24.7 | 0.480 | 40.2 | 2.042 | 24.5 |
900 | 1.176 | 31.2 | 0.357 | 55.6 | 1.556 | 42.4 |
1200 | 1.043 | 38.9 | 0.188 | 76.6 | 1.054 | 61.0 |
1500 | 1.040 | 39.2 | 0.005 | 99.3 | 0.992 | 63.3 |