<abstract xmlns="http://www.w3.org/1999/xhtml">Metathesis ionic exchange reaction process was used to synthesize a novel nonlinear optical material: 4-N,N-dimethylamino-4′- N′-methylstilbazolium 2,4-dimethylbenzenesulfonate (DSDMS). The growth of DSDMS single crystals was carried out by adopting the solution growth technique. The crystal perfection and lattice parameters were elucidated from single XRD and powder XRD, respectively and its morphology was interpreted by WinXMorph program. FT-IR and Raman spectral analyses confirmed the existence of functional groups and their corresponding vibrational modes. UV-Vis spectral studies revealed the optical transmission region. Mechanical stability of the crystal was determined from Vickers microhardness number Hv, Meyer’s index n and elastic stiffness constant C11. Dielectric and thermal behavior of the grown crystal were elucidated by using impedance analyser and thermogravimetric analysis.</abstract>

Metathesis ionic exchange reaction process was used to synthesize a novel nonlinear optical material: 4-N,N-dimethylamino-4′- N′-methylstilbazolium 2,4-dimethylbenzenesulfonate (DSDMS). The growth of DSDMS single crystals was carried out by adopting the solution growth technique. The crystal perfection and lattice parameters were elucidated from single XRD and powder XRD, respectively and its morphology was interpreted by WinXMorph program. FT-IR and Raman spectral analyses confirmed the existence of functional groups and their corresponding vibrational modes. UV-Vis spectral studies revealed the optical transmission region. Mechanical stability of the crystal was determined from Vickers microhardness number Hv, Meyer’s index n and elastic stiffness constant C11. Dielectric and thermal behavior of the grown crystal were elucidated by using impedance analyser and thermogravimetric analysis.

Investigation on growth, optical and thermal properties of stilbazolium derivative crystal: 4-N,N-dimethylamino-4′-N′-methylstilbazolium 2,4-dimethylbenzenesulfonate

Department of Physics, Presidency College, Chennai, 600 005,

Department of Physics, Kalasalingam University, Krishnankoil, 626 126,

Department of Chemistry, Presidency College, Chennai, 600 005,

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Metathesis ionic exchange reaction process was used to synthesize a novel nonlinear optical material: 4-N,N-dimethylamino-4′- N′-methylstilbazolium...

Investigation on growth, optical and thermal properties of stilbazolium derivative crystal: 4-N,N-dimethylamino-4′-N′-methylstilbazolium 2,4-dimethylbenzenesulfonate

Publié en ligne: 19 déc. 2016

Pages: 811 - 818

Reçu: 06 avr. 2016

Accepté: 28 sept. 2016

DOI: https://doi.org/10.1515/msp-2016-0113

Mots clés
ionic crystals, DSDMS, solution growth technique, nonlinear optical material

© Wroclaw University of Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Investigation on growth, optical and thermal properties of stilbazolium derivative crystal: 4-N,N-dimethylamino-4′-N′-methylstilbazolium 2,4-dimethylbenzenesulfonate

Publié en ligne: 19 déc. 2016

Pages: 811 - 818

Reçu: 06 avr. 2016

Accepté: 28 sept. 2016

DOI: https://doi.org/10.1515/msp-2016-0113

Mots clésionic crystals, DSDMS, solution growth technique, nonlinear optical material

© Wroclaw University of Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mots clés
ionic crystals, DSDMS, solution growth technique, nonlinear optical material