<abstract xmlns="http://www.w3.org/1999/xhtml"><p>In this paper, a mesoporous γ-alumina membrane coated on a macroporous α-alumina support via sol-gel method has been reported. A crack-free γ-alumina membrane was obtained by adding PVA to the alumina solution and optimum parameters of roughness, temperature and porosity were achieved. The support was dip-coated in different solutions using two new different solvents with different particle size distributions. Using these two solvents led to the uniform distribution of pore size in the final membrane. The alumina sols showed particle size distributions in the range of 20 to 55 nm which was measured by a DLS Zeta Sizer. X-ray diffraction technique, atomic force microscopy and scanning electron microscopy were used to characterize the membrane layer. XRD and DTA data for the γ-alumina membrane showed its thermal stability up to around 600 °C. The thickness of the mesoporous γ-alumina membrane was about 4 μm with 16 nm of surface roughness and 5 nm pore size. The resultant crack-free mesoporous membrane shows that the membrane preparation procedure was optimum. In this work, it has been investigated the performance of γ-alumina membranes for single gas permeation and separation of binary gas mixtures.</p></abstract>

In this paper, a mesoporous γ-alumina membrane coated on a macroporous α-alumina support via sol-gel method has been reported. A crack-free γ-alumina membrane was obtained by adding PVA to the alumina solution and optimum parameters of roughness, temperature and porosity were achieved. The support was dip-coated in different solutions using two new different solvents with different particle size distributions. Using these two solvents led to the uniform distribution of pore size in the final membrane. The alumina sols showed particle size distributions in the range of 20 to 55 nm which was measured by a DLS Zeta Sizer. X-ray diffraction technique, atomic force microscopy and scanning electron microscopy were used to characterize the membrane layer. XRD and DTA data for the γ-alumina membrane showed its thermal stability up to around 600 °C. The thickness of the mesoporous γ-alumina membrane was about 4 μm with 16 nm of surface roughness and 5 nm pore size. The resultant crack-free mesoporous membrane shows that the membrane preparation procedure was optimum. In this work, it has been investigated the performance of γ-alumina membranes for single gas permeation and separation of binary gas mixtures.

Preparation and characterization of multilayer mesoporous γ-alumina membrane obtained via sol-gel using new precursors

Department of Materials Science, Faculty of Engineering

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

In this paper, a mesoporous γ-alumina membrane coated on a macroporous α-alumina support via sol-gel method has been reported. A crack-free γ-alumina membrane...

Preparation and characterization of multilayer mesoporous γ-alumina membrane obtained via sol-gel using new precursors

Publié en ligne: 06 janv. 2016

Pages: 792 - 798

Reçu: 14 janv. 2015

Accepté: 14 juin 2015

DOI: https://doi.org/10.1515/msp-2015-0094

Mots clés
mesoporous, macroporous, coating, alumina, sol-gel

© 2015 R. Tafrishi et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Preparation and characterization of multilayer mesoporous γ-alumina membrane obtained via sol-gel using new precursors

Publié en ligne: 06 janv. 2016

Pages: 792 - 798

Reçu: 14 janv. 2015

Accepté: 14 juin 2015

DOI: https://doi.org/10.1515/msp-2015-0094

Mots clésmesoporous, macroporous, coating, alumina, sol-gel

© 2015 R. Tafrishi et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mots clés
mesoporous, macroporous, coating, alumina, sol-gel