<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml"><p>Nanocomposite materials based on vinylidene fluoride-hexafluoropropylene copolymer and organically modified montmorillonite Cloisite®15A were prepared by two different methods: melt mixing and co-precipitation. The changes taking place in crystalline structure, tensile strength, thermal behavior and the formation of piezoelectric b-phase as a result of the polymer system dissolution in dimethyl sulfoxide were studied. The technological specificity of each method has certain effect on the properties of the obtained nanocomposites. The highest content of b-phase — 95 % was achieved by co-precipitation from the solution of vinylidene fluoride-hexafluoropropylene copolymer in dimethyl sulfoxide and 6 mass % content of Cloisite®15A. Despite the common view that the use of solvents and prolonged technological procedure lead to overall higher expenses, the obtained nanocomposites could be promising for the preparation of new piezo-materials.</p></abstract>

Nanocomposite materials based on vinylidene fluoride-hexafluoropropylene copolymer and organically modified montmorillonite Cloisite®15A were prepared by two different methods: melt mixing and co-precipitation. The changes taking place in crystalline structure, tensile strength, thermal behavior and the formation of piezoelectric b-phase as a result of the polymer system dissolution in dimethyl sulfoxide were studied. The technological specificity of each method has certain effect on the properties of the obtained nanocomposites. The highest content of b-phase — 95 % was achieved by co-precipitation from the solution of vinylidene fluoride-hexafluoropropylene copolymer in dimethyl sulfoxide and 6 mass % content of Cloisite®15A. Despite the common view that the use of solvents and prolonged technological procedure lead to overall higher expenses, the obtained nanocomposites could be promising for the preparation of new piezo-materials.

A comparison of two different methods for formation of the beta phase in nanocomposites based on vinylidene fluoride-hexafluoropropylene copolymer

Department of Materials Science, Assen Zlatarov University, Y. Yakimov Str. 1, Burgas, 8010, Bulgaria

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Nanocomposite materials based on vinylidene fluoride-hexafluoropropylene copolymer and organically modified montmorillonite Cloisite®15A were prepared by two...

A comparison of two different methods for formation of the beta phase in nanocomposites based on vinylidene fluoride-hexafluoropropylene copolymer

Publicado en línea: 22 jul 2014

Páginas: 301 - 306

DOI: https://doi.org/10.2478/s13536-013-0180-y

Palabras clave
nanoclay, nanocomposites, vinylidene fluoride-hexafluoropropylene copolymer, b-phase

© 2014 Wroclaw University of Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

A comparison of two different methods for formation of the beta phase in nanocomposites based on vinylidene fluoride-hexafluoropropylene copolymer

Publicado en línea: 22 jul 2014

Páginas: 301 - 306

DOI: https://doi.org/10.2478/s13536-013-0180-y

Palabras clavenanoclay, nanocomposites, vinylidene fluoride-hexafluoropropylene copolymer, b-phase

© 2014 Wroclaw University of Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Palabras clave
nanoclay, nanocomposites, vinylidene fluoride-hexafluoropropylene copolymer, b-phase