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In this paper, we successfully synthesized heterojunction manganese titanate/titanate nanoparticles (MnTiO3–TiO2 NPs)-decorated carbon nanofibers (CNFs) employing the electrospinning process. The morphology, crystallinity, and chemical composition of the MnTiO3/TiO2-decorated CNFs is characterized via SEM, FESEM, STEM, TEM EDX, and XRD techniques. The synthesized nanocomposite exhibits good performance for photodegradation of methylene blue (MB) dye and hydrolysis of ammonia–borane complex for hydrogen releasing experiment in a batch reactor under visible light. A mathematical model was developed to predict the photocatalytic activity of the produced nanocomposite with various parameters. The operational parameters include the effect of the initial concentration, catalyst dosage, light intensity, and reaction temperature, which are studied to validate the mathematical model. The reaction rate constant of MB photodegradation is found to be 0.0153 min−1 for an initial MB concentration of 5 mg·L−1 with a catalytic dosage of 200 mg·L−1 at a reaction temperature of 25°C under a light intensity of 25 W·m−2. Similarly, the H2 generation employing TiO2@CNFs and MnTiO3/TiO2@CNFs under visible light irradiation is observed to be 0.31 mol and 2.95 mol, respectively, corresponding to an exposure of 10 min. We also demonstrated that the yield of hydrogen employing MnTiO3/TiO2@CNFs under visible light increases to 2.95 mol compared with 1.51 mol in darkness. Finally, comparisons were made between the experimental and model-predicted values of the reaction rate constant and final concentrations. Theoretical and experimental data of photocatalytic activity are found to be in good agreement for MnTiO3/TiO2@CNFs.
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In this paper, we successfully synthesized heterojunction manganese titanate/titanate nanoparticles (MnTiO3–TiO2 NPs)-decorated carbon nanofibers (CNFs) employing the electrospinning process. The morphology, crystallinity, and chemical composition of the MnTiO3/TiO2-decorated CNFs is characterized via SEM, FESEM, STEM, TEM EDX, and XRD techniques. The synthesized nanocomposite exhibits good performance for photodegradation of methylene blue (MB) dye and hydrolysis of ammonia–borane complex for hydrogen releasing experiment in a batch reactor under visible light. A mathematical model was developed to predict the photocatalytic activity of the produced nanocomposite with various parameters. The operational parameters include the effect of the initial concentration, catalyst dosage, light intensity, and reaction temperature, which are studied to validate the mathematical model. The reaction rate constant of MB photodegradation is found to be 0.0153 min−1 for an initial MB concentration of 5 mg·L−1 with a catalytic dosage of 200 mg·L−1 at a reaction temperature of 25°C under a light intensity of 25 W·m−2. Similarly, the H2 generation employing TiO2@CNFs and MnTiO3/TiO2@CNFs under visible light irradiation is observed to be 0.31 mol and 2.95 mol, respectively, corresponding to an exposure of 10 min. We also demonstrated that the yield of hydrogen employing MnTiO3/TiO2@CNFs under visible light increases to 2.95 mol compared with 1.51 mol in darkness. Finally, comparisons were made between the experimental and model-predicted values of the reaction rate constant and final concentrations. Theoretical and experimental data of photocatalytic activity are found to be in good agreement for MnTiO3/TiO2@CNFs.

Fabrication of heterojunction MnTiO3–TiO2-decorated carbon nanofibers via electrospinning as an effective multifunctional photocatalyst

Department of Chemical Engineering, College of Engineering

Department of Mechanical Engineering, College of Engineering

Department of Chemistry, College of Science

Department of Industrial Engineering, College of Engineering

Engineering Mathematics and Physics Department, Faculty of Engineering

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Fabrication of heterojunction MnTiO–TiO-decorated carbon nanofibers via electrospinning as an effective multifunctional photocatalyst

In this paper, we successfully synthesized heterojunction manganese titanate/titanate nanoparticles (MnTiO3–TiO2 NPs)-decorated carbon nanofibers (CNFs)...

Fabrication of heterojunction MnTiO₃–TiO₂-decorated carbon nanofibers via electrospinning as an effective multifunctional photocatalyst

Publicado en línea: 25 dic 2022

Páginas: 289 - 305

Recibido: 13 jun 2022

Aceptado: 24 oct 2022

DOI: https://doi.org/10.2478/msp-2022-0028

Palabras clave
manganese titanate nanoparticles, dye removal, ammonia–borane complex, hydrogen release, electrospinning, visible light

© 2022 Ayman Yousef, published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Fabrication of heterojunction MnTiO3–TiO2-decorated carbon nanofibers via electrospinning as an effective multifunctional photocatalyst

Publicado en línea: 25 dic 2022

Páginas: 289 - 305

Recibido: 13 jun 2022

Aceptado: 24 oct 2022

DOI: https://doi.org/10.2478/msp-2022-0028

Palabras clavemanganese titanate nanoparticles, dye removal, ammonia–borane complex, hydrogen release, electrospinning, visible light

© 2022 Ayman Yousef, published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Fabrication of heterojunction MnTiO₃–TiO₂-decorated carbon nanofibers via electrospinning as an effective multifunctional photocatalyst

Palabras clave
manganese titanate nanoparticles, dye removal, ammonia–borane complex, hydrogen release, electrospinning, visible light