<abstract xmlns="http://www.w3.org/1999/xhtml"> The novel hydrophilic back-extraction agent TS-BTPhen (3,3ʹ,3ʺ,3ʹʺ-[3-(1,10-phenanthroline-2,9-diyl)-1,2,4-triazine-5,5,6,6-tetrayl]tetrabenzenesulfonic acid) was tested for its selectivity towards Am(III) over Cm(III) and Eu(III) with a TODGA (N,N,Nʹ,Nʹ-tetraoctyldiglycolamide) based solvent. Batch experiments were carried out using TS-BTPhen dissolved in aqueous nitric acid solution with tracers of 152Eu, 241Am and 244Cm. A significant increase of the separation factor for Cm over Am from SFCm/Am = 1.6 up to SFCm/Am = 3.3 was observed compared to the use of a TODGA-nitric acid system alone. Furthermore, stripping was possible at high nitric acid concentrations (0.6-0.7 mol/L) resulting in a low sensitivity to acidity changes. The influence of the TS-BTPhen concentration was analyzed. A slope of -2 was expected taking into account literature stoichiometries of the lipophilic analogue CyMe4BTPhen. However, a slope of -1 was found. Batch stripping kinetics showed fast kinetics for the trivalent actinides. As an alternative organic ligand the methylated TODGA derivate Me-TODGA (2-methyl-N,N,Nʹ,Nʹ-tetraoctyldiglycolamide) was tested in combination with the hydrophilic TS-BTPhen. The Am(III) separation was achieved at even higher nitric acid concentrations compared to TODGA. </abstract>

The novel hydrophilic back-extraction agent TS-BTPhen (3,3ʹ,3ʺ,3ʹʺ-[3-(1,10-phenanthroline-2,9-diyl)-1,2,4-triazine-5,5,6,6-tetrayl]tetrabenzenesulfonic acid) was tested for its selectivity towards Am(III) over Cm(III) and Eu(III) with a TODGA (N,N,Nʹ,Nʹ-tetraoctyldiglycolamide) based solvent. Batch experiments were carried out using TS-BTPhen dissolved in aqueous nitric acid solution with tracers of 152Eu, 241Am and 244Cm. A significant increase of the separation factor for Cm over Am from SFCm/Am = 1.6 up to SFCm/Am = 3.3 was observed compared to the use of a TODGA-nitric acid system alone. Furthermore, stripping was possible at high nitric acid concentrations (0.6-0.7 mol/L) resulting in a low sensitivity to acidity changes. The influence of the TS-BTPhen concentration was analyzed. A slope of -2 was expected taking into account literature stoichiometries of the lipophilic analogue CyMe4BTPhen. However, a slope of -1 was found. Batch stripping kinetics showed fast kinetics for the trivalent actinides. As an alternative organic ligand the methylated TODGA derivate Me-TODGA (2-methyl-N,N,Nʹ,Nʹ-tetraoctyldiglycolamide) was tested in combination with the hydrophilic TS-BTPhen. The Am(III) separation was achieved at even higher nitric acid concentrations compared to TODGA.

TS-BTPhen as a promising hydrophilic complexing agent for selective Am(III) separation by solvent extraction

Institut für Energie- und Klimaforschung, Nukleare Entsorgung und Reaktorsicherheit (IEK-6),

Department of Applied Sciences, Faculty of Health and Life Sciences, Northumbria University, Newcastle upon Tyne NE1 8ST, United Kingdom

Department of Chemistry, University of Reading, Whiteknights, Reading RG6 6AD, United Kingdom

Nukleonika

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

The novel hydrophilic back-extraction agent TS-BTPhen (3,3ʹ,3ʺ,3ʹʺ-[3-(1,10-phenanthroline-2,9-diyl)-1,2,4-triazine-5,5,6,6-tetrayl]tetrabenzenesulfonic acid)...

TS-BTPhen as a promising hydrophilic complexing agent for selective Am(III) separation by solvent extraction

Publicado en línea: 30 dic 2015

Páginas: 815 - 820

Recibido: 19 jun 2015

Aceptado: 21 ago 2015

DOI: https://doi.org/10.1515/nuka-2015-0120

Palabras clave
Am-Cm separation, TODGA, TS-BTPhen, liquid-liquid extraction

© by Giuseppe Modolo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

TS-BTPhen as a promising hydrophilic complexing agent for selective Am(III) separation by solvent extraction

Publicado en línea: 30 dic 2015

Páginas: 815 - 820

Recibido: 19 jun 2015

Aceptado: 21 ago 2015

DOI: https://doi.org/10.1515/nuka-2015-0120

Palabras claveAm-Cm separation, TODGA, TS-BTPhen, liquid-liquid extraction

© by Giuseppe Modolo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Palabras clave
Am-Cm separation, TODGA, TS-BTPhen, liquid-liquid extraction